Orthogonal Solution-Processable Electron Transport Layers Based on Phenylpyridine Side-Chain Polystyrenes

This article reports the synthesis and characterization of a series of polystyrenes containing phenylpyridine moieties as side chains. Methanol solubility of these polymers is induced if the relative pyridine content of the overall aromatic units of the side chains is larger than 0.5. This allows for orthogonal processing of multilayered organic light emitting diode (OLED) stacks fabricated from solutions. The polymers show high thermal stability due to their glass-transition temperatures ranging from 136 up to 247 °C. High triplet energies of up to 2.8 eV are obtained by combination of the side-chain aromatic rings in the meta position. The use of the methanol soluble side-chain polymers as an electron transport layer (ETL) is demonstrated in an orthogonally processed three-layer green-emitting OLED stack. When depositing the ETL from methanol, redissolution of the underlying emission layer does not occur

Correlation between the Open Circuit Voltage and the Energetics of Organic Bulk Heterojunction Solar Cells

A detailed investigation of the open circuit voltage (<i>V</i>_OC) of organic bulk heterojunction solar cells comprising three different donor polymers and two different fullerene-based acceptors is presented. Bias amplified charge extraction (BACE) is combined with Kelvin Probe measurements to derive information on the relevant energetics in the blend. On the example of P3HT:PC₇₀BM the influence of composition and preparation conditions on the relevant transport levels will be shown. Moderate upward shifts of the P3HT HOMO depending on crystallinity are observed, but contrarily to common believe, the dependence of <i>V</i>_OC on blend composition and thermal history is found to be largely determined by the change in the PCBM LUMO energy. Following this approach, we quantified the energetic contribution to the <i>V</i>_OC in blends with fluorinated polymers or higher adduct fullerenes

Charge-Transfer Localization in Molecularly Doped Thiophene-Based Donor Polymers

We provide evidence for highly localized charge-transfer complex formation between a series of thiophenetetrafluorobenzene donor copolymers and the molecular acceptor tetrafluorotetracyanoquinodimethane (F₄TCNQ). Infrared absorption spectra of diagnostic vibrational bands in conjunction with theoretical modeling show that one acceptor molecule undergoes charge transfer with a quaterthiophene segment of the polymers, irrespective of the macroscopic polymer ionization energy and acceptor concentration in thin films. The interaction is thus determined by the “local ionization potential” of quaterthiophene. Consequently, using materials parameters determined on a macroscopic length scale as a guideline for making new charge-transfer complex materials for high electrical conductivity turns out to be oversimplified, and a reliable material design must take into account property variations on the nm scale as well

Fluorinated Copolymer PCPDTBT with Enhanced Open-Circuit Voltage and Reduced Recombination for Highly Efficient Polymer Solar Cells

A novel fluorinated copolymer (F-PCPDTBT) is introduced and shown to exhibit significantly higher power conversion efficiency in bulk heterojunction solar cells with PC₇₀BM compared to the well-known low-band-gap polymer PCPDTBT. Fluorination lowers the polymer HOMO level, resulting in high open-circuit voltages well exceeding 0.7 V. Optical spectroscopy and morphological studies with energy-resolved transmission electron microscopy reveal that the fluorinated polymer aggregates more strongly in pristine and blended layers, with a smaller amount of additives needed to achieve optimum device performance. Time-delayed collection field and charge extraction by linearly increasing voltage are used to gain insight into the effect of fluorination on the field dependence of free charge-carrier generation and recombination. F-PCPDTBT is shown to exhibit a significantly weaker field dependence of free charge-carrier generation combined with an overall larger amount of free charges, meaning that geminate recombination is greatly reduced. Additionally, a 3-fold reduction in non-geminate recombination is measured compared to optimized PCPDTBT blends. As a consequence of reduced non-geminate recombination, the performance of optimized blends of fluorinated PCPDTBT with PC₇₀BM is largely determined by the field dependence of free-carrier generation, and this field dependence is considerably weaker compared to that of blends comprising the non-fluorinated polymer. For these optimized blends, a short-circuit current of 14 mA/cm², an open-circuit voltage of 0.74 V, and a fill factor of 58% are achieved, giving a highest energy conversion efficiency of 6.16%. The superior device performance and the low band-gap render this new polymer highly promising for the construction of efficient polymer-based tandem solar cells