Rheological, processing, and 371 deg C mechanical properties of Celion 6000/N-phenylnadimide modified PMR composites

The rheology, processing, and chemistry of newly developed N-phenylnadimide modified PMR (PMR-PN) polyimide resins are reviewed. The 371 C performance of their composites reinforced with Celion 6000 graphite fibers is also reviewed, along with the state of the art Celion 6000/PMR-15 composite. The effects of the 371 C exposure in air for up to 300 hr on the composite glass transition temperature, weight loss characteristics, and dimensional stability are presented. The changes in the composite 371 C interlaminar shear and flexural properties are also presented. In addition, composite interfacial degradation at a function of exposure time at 371 C was followed by scanning electron microscopy. The results suggest that the composite materials can be used at 371 C for at least 100 hr

High temperature resistant polyimide from tetra ester, diamine, diester and N-arylnadimide

The invention described relates to improved polyimide resins which are noted for their high thermal and oxidative stability, high strength at elevated temperatures and which exhibit many other outstanding physical and chemical properties, especially useful in high temperature applications. The polyimides are prepared by the reaction, with application of heat of a mixture of monomers comprising: (1) a dialkyl or tetraalkyl ester of an aromatic tetracarboxylic acid, (2) and aromatic diamine, (3) a monoalkyl or dialky ester of a dicarboxylic acid, and (4) a N-arylnadimide such as N-phenylnadimide. Polyimides of monomers (1), (2) and (3) are known

Novel improved PMR polyimides

A series of N-phenylnadimide (PN) modified PMR polyimide composites reinforced with graphite fibers was investigated. The improved flow matrix resins consist of N-phenylnadimide (PN), monomenthyl ester of 5-norbornene-2, 3-dicarboxylic acid (NE), dimethyl ester of 3,3, 4,4-benzophenonetetracarboxylic acide (BTDE), and 4,4 methylenedianiline (MDA). Five modified PMR resin systems were formulated by the addition of 4 to 20 mole percent N-phenylnadimide to the standard PMR-15 composition. These formulations and the control PMR resin were evaluated for rheological characteristics. The initial thermal and mechanical properties of the PN modified PMR and the control PMR/Celion 6000 composites were determined. The results show that the addition of N-phenylnadimide to PMR-15 significantly improved the resin flow characteristics without sacrificing the composites properties. Concentrations of 4 and 9 mole percent PN appear to improve the thermoxidative stability of PMR composites

The 371 deg C(700 deg F) properties of celion 6000/n-phenylnadimide modified PMR polyimide composites

The 371 C (700 F) properties of Celion 6000/N-phenylnadimide modified PMR-15 polyimide composites were investigated to determine the feasibility of using these materials at a 371 C (700 F) service temperature. The processing characteristics and physical and mechanical properties of the composite systems are presented. The results of the 371 C (700 F) thermo-oxidation stability study suggest that the composite materials can be considered for short term (at least 100 hours) application at 371 C (700 F)

Dynamic Mechanical Properties of N-Phenylnadimide Modified PMR Polyimide Composites

The rheological behavior of newly developd Celion 6000/N-phenylnadimide modified PMR polyimide and PMR-15 composites was investigated. The dynamic mechanical properties were correlated with the structure of N-phenylnadimide modified PMR polyimides. The storage modulus (G'), loss modulus (G''), and loss tangent (tan delta) of four composite systems were measured over a temperature range from -150 to 400 C. Three well defined peaks were seen in the regions of 360, 100, and -120 C, corresponding to the alpha, beta, and gamma relaxations, respectively, of the matrix resins. The activation energies of the alpha, beta, and gamma relaxations were estimated to be 232, 60, and 14 kcal/mole, respectively, for PMR-15. Addition of N-phenylnadimide to the PMR-15 composition lowered the glass transition temperature and the activation energies of PMR-15 polyimide. The dynamic mechanical data appear to be consistent with the formation of a copolymer from N-phenylnadimide and a PMR-15 prepolymer

Imide modified epoxy matrix resins

High char yield epoxy using novel bisimide amines (BIA's) as curing agents with a state of the art epoxy resin was developed. Stoichiometric quantities of the epoxy resin and the BIA's were studied to determine the cure cycle required for preparation of resin specimens. The bisimide cured epoxies were designated IME's (imide modified epoxy). The physical, thermal and mechanical properties of these novel resins were determined. The levels of moisture absorption exhibited by the bisimide amine cured expoxies (IME's) were considerably lower than the state of the art epoxies. The strain-to-failure of the control resin system was improved 25% by replacement of DDS with 6F-DDS. Each BIA containing resin exhibited twice the char yield of the control resin MY 720/DDS. Graphite fiber reinforced control (C) and IME resins were fabricated and characterized. Two of the composite systems showed superior properties compared to the other Celion 6000/IME composite systems and state of the art graphite epoxy systems. The two systems exhibited excellent wet shear and flexural strengths and moduli at 300 and 350 F

THE VALUATION OF THE ENTERPRISES AND PRODUCTS COMPETITIVENESS

The increase of the enterprise competitiveness in the enlarged European Union imposes, firstly, a good knowledge of the competitiveness factors and a pragmatic rigorous valuation of the competitiveness at the micro level (cluster, firm, business, and product), in correlation with the competitiveness at the macro level (continent, country, and region) and the mezzo level (county, zone, and locality). New concepts, models and methods have been analysed and developed in this field: the competitiveness typology; the competitiveness metaperformances (flexibility, value, liquidity, efficiency) and factors at the micro level; the competitive capacity of enterprises; integrated valuations of the competitiveness (value in the market/segment/niche, competitiveness profile, score)

Simultaneous Observations of Comet C/2002 T7 (LINEAR) with the Berkeley-Illinois-Maryland Association and Owens Valley Radio Observatory Interferometers: HCN and CH_3OH

We present observations of HCN J = 1-0 and CH_3OH J(K_a, K_c) = 3(1, 3)-4(0, 4) A+ emission from comet C/2002 T7 (LINEAR) obtained simultaneously with the Owens Valley Radio Observatory (OVRO) and Berkeley-Illinois-Maryland Association (BIMA) millimeter interferometers. We combined the data from both arrays to increase the (u, v) sampling and signal to noise of the detected line emission. We also report the detection of CH_3OH J(K_a, K_c) = 8(0, 8)-7(1, 7) A^+ with OVRO data alone. Using a molecular excitation code that includes the effects of collisions with water and electrons, as well as pumping by the Solar infrared photons (for HCN alone), we find a production rate of HCN of 2.9 × 10^(26) s^(–1) and for CH_3OH of 2.2 × 10^(27) s^(–1). Compared to the adopted water production rate of 3 × 10^(29) s^(–1), this corresponds to an HCN/H_2O ratio of 0.1% and a CH_3OH/H_2O ratio of 0.7%. We critically assess the uncertainty of these values due to the noise (~10%), the uncertainties in the adopted comet model (~50%), and the uncertainties in the adopted collisional excitation rates (up to a factor of 2). Pumping by Solar infrared photons is found to be a minor effect for HCN, because our 15" synthesized beam is dominated by the region in the coma where collisions dominate. Since the uncertainties in the derived production rates are at least as large as one-third of the differences found between comets, we conclude that reliable collision rates and an accurate comet model are essential. Because the collisionally dominated region critically depends on the water production rate, using the same approximate method for different comets may introduce biases in the derived production rates. Multiline observations that directly constrain the molecular excitation provide much more reliable production rates

Superdiffusion of massive particles induced by multi-scale velocity fields

We study drag-induced diffusion of massive particles in scale-free velocity fields, where superdiffusive behavior emerges due to the scale-free size distribution of the vortices of the underlying velocity field. The results show qualitative resemblance to what is observed in fluid systems, namely the diffusive exponent for the mean square separation of pairs of particles and the preferential concentration of the particles, both as a function of the response time.Comment: 5 pages, 5 figures. Accepted for publication in EP

Morphology of Thermoset Polyimides by Positron Annihilation Spectroscopy

Thermoset polyimides have great potential for successfully meeting tough stress and temperature challenges in the advanced aircraft development program. However, studies of structure/property relationships in these materials have not been very successful so far. Positron annihilation spectroscopy has been used to investigate free volumes and associated parameters. It has been noted that the free volume correlates well with the molecular weight, cross-link density and thermal coefficient of expansion of these materials. Currently no other techniques are available for direct measurement of these parameters. Experimental results and their interpretations will be discussed