46 research outputs found
Temperature dependent transport characteristics of graphene/n-Si diodes
Realizing an optimal Schottky interface of graphene on Si is challenging, as
the electrical transport strongly depends on the graphene quality and the
fabrication processes. Such interfaces are of increasing research interest for
integration in diverse electronic devices as they are thermally and chemically
stable in all environments, unlike standard metal/semiconductor interfaces. We
fabricate such interfaces with n-type Si at ambient conditions and find their
electrical characteristics to be highly rectifying, with minimal reverse
leakage current (10 A) and rectification of more than . We
extract Schottky barrier height of 0.69 eV for the exfoliated graphene and 0.83
eV for the CVD graphene devices at room temperature. The temperature dependent
electrical characteristics suggest the influence of inhomogeneities at the
graphene/n-Si interface. A quantitative analysis of the inhomogeneity in
Schottky barrier heights is presented using the potential fluctuation model
proposed by Werner and G\"{u}ttler.Comment: 5 pages, 5 figure
Deep Shape Matching
We cast shape matching as metric learning with convolutional networks. We
break the end-to-end process of image representation into two parts. Firstly,
well established efficient methods are chosen to turn the images into edge
maps. Secondly, the network is trained with edge maps of landmark images, which
are automatically obtained by a structure-from-motion pipeline. The learned
representation is evaluated on a range of different tasks, providing
improvements on challenging cases of domain generalization, generic
sketch-based image retrieval or its fine-grained counterpart. In contrast to
other methods that learn a different model per task, object category, or
domain, we use the same network throughout all our experiments, achieving
state-of-the-art results in multiple benchmarks.Comment: ECCV 201
High-Entropy Alloys as Catalysts for the CO2 and CO Reduction Reactions: Experimental Realization
Conversion of carbon dioxide into selective hydrocarbon using a stable catalyst remains a holy grail in the catalysis community. The high overpotential, stability, and selectivity in the use of a single-metal-based catalyst still remain a challenge. In current work, instead of using pure noble metals (Ag, Au, and Pt) as the catalyst, a nanocrystalline high-entropy alloy (HEA: AuAgPtPdCu) has been used for the conversion of CO2 into gaseous hydrocarbons. Utilizing an approach of multimetallic HEA, a faradic efficiency of about 100% toward gaseous products is obtained at a low applied potential (−0.3 V vs reversible hydrogen electrode). The reason behind the catalytic activity and selectivity of the high-entropy alloy (HEA) toward CO2 electroreduction was established through first-principles-based density functional theory (DFT) by comparing it with the pristine Cu(111) surface. This is attributed to the reversal in adsorption trends for two out of the total eight intermediates—*OCH3 and *O on Cu(111) and HEA surfaces
Synthesis of antiferroelectric (Bi0.534Na0.5)0.94Ba0.06TiO3 ceramics with high phase transition temperature and broad temperature range by a solid-state reaction method
Further Contribution on the Diptera (Insecta) Fauna of Andaman and Nicobar Islands
Volume: 99Start Page: 135End Page: 13
Low-cost high entropy alloy (HEA) for high-efficiency oxygen evolution reaction (OER)
Oxygen evolution reaction (OER) is the key step involved both in water splitting devices and rechargeable metal-air batteries, and hence, there is an urgent need for a stable and low-cost material for efficient OER. In the present investigation, Co-Fe-Ga-Ni-Zn (CFGNZ) high entropy alloy (HEA) has been utilized as a low-cost electrocatalyst for OER. Herein, after cyclic voltammetry activation, CFGNZ-nanoparticles (NPs) are covered with oxidized surface and form high entropy (oxy) hydroxides (HEOs), exhibiting a low overpotential of 370 mV to achieve a current density of 10 mA/cm2 with a small Tafel slope of 71 mV/dec. CFGNZ alloy has higher electrochemical stability in comparison to state-of-the art RuO2 electrocatalyst as no degradation has been
bserved up to 10 h of chronoamperometry. Transmission electron microscopy (TEM) studies after 10 h of long-term
chronoamperometry test showed no change in the crystal structure, which confirmed the high stability of CFGNZ. The density functional theory (DFT) based calculations show that the closeness of d(p)-band centers to the Fermi level (EF) plays a major role in determining active sites.This work highlights the tremendous potential of CFGNZ HEA for OER, which is the primary reaction involved in water splitting