Multilayered and Chemiresistive Thin and Thick Film Gas Sensors for Air Quality Monitoring

Selective detection of gases such as nitrogen dioxide (NO2), carbon monoxide (CO), carbon dioxide (CO2), and various volatile organic components (VOCs) is necessary for air quality monitoring. Detection of hydrogen (H2) is equally important as it is a flammable gas and poses serious threat of explosion when exposed to oxygen gas. We have studied the sensing characteristics of these gases using thin film deposited by chemical solution deposition as well as relatively thicker films deposited by atmospheric plasma spray (APS) process. The chapter starts with the sensing mechanism of chemiresistive sensors followed by the definition of gas sensing parameters. Subsequently, we have demonstrated selective NO2 sensing characteristics of zinc oxide-graphene (ZnO-G) multilayered thin film followed by CO and H2 sensing characteristics of ZnO thin film and SnO2 thick film. Cross-sensitivity among CO and H2 gases has been addressed through the analysis of conductance transients with the determination of activation energy, Ea, and heat of adsorption, Q. The concepts of reversible and irreversible sensing have also been discussed in relation to CO and H2 gases. CO2 sensing characteristics of LaFe0.8Co0.2O3 (LFCO)-ZnO thin film have been elucidated. Interference from CO has been addressed with principal component analyses and the ascertaining of Ea and Q values. Additionally, the variation of response with temperature for each gas was simulated to determine distinct parameters for the individual gases. Further, VOC sensing characteristics of copper oxide (CuO) thin film and WO3-SnO2 thick film were investigated. Principal component analysis was performed to discriminate the gases in CuO thin film. The interaction of WO3-SnO2 thick film with various VOCs was found to obey the Freundlich adsorption isotherm based on which Ea and Q values were determined

Variation in the number of ray- and disc-florets in four species of compositae

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Matrimonial distance, inbreeding coefficient and population size: dhangar data

Data on the distance between the birthplaces of spouses (matrimonial distance) were collected from 2260 married individuals belonging to 21 endogamous castes of the Dhangar (shepherd) caste-cluster of Maharashtra, India. The general form of the distribution of matrimonial distances is one which is extremely positively skewed and leptokurtic. The percentage of intra-village marriages generally decreases from the southern areas of Maharashtra to the northern areas of the state, as does the inbreeding coefficient. This situation is in conformity with the socio-cultural norms regulating matrimonial choice in south and north India. An attempt has been made to relate the degree of inbreeding to the mean matrimonial distance and population size. The mean matrimonial distance is more useful in predicting the degree of inbreeding than population size

Dragonflies and damselflies (Insecta: Odonata) of Tripura, northeastern India with a pictorial catalogue.

A survey of Odonata was conducted in four reserve forests, three wildlife sanctuaries and three unclassified natural areas of Tripura, northeastern India from 2008 to 2012, from May to August.  A total of 53 species belonging to 37 genera under nine families of Zygoptera (damselflies) and Anisoptera (dragonflies) were recorded in five years from 1370 points by direct search.  This included 25 species, 16 genera and five families reported as new records for the state.  A list of the species, number of specimens examined, their habitats, local and IUCN status, and worldwide distribution are provided.  A pictorial catalogue of adults of the recorded species is also provided.  </div

On hypertrichosis pinnae

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Determination of proton concentration at cardiolipin-containing membrane interfaces and its relation with the peroxidase activity of cytochrome c†

The activities of biomolecules are affected by the proton concentrations at biological membranes. Here, we succeeded in evaluating the interface proton concentration (−log[H+] defined as pH′) of cardiolipin (CL)-enriched membrane models of the inner mitochondrial membrane (IMM) using a spiro-rhodamine-glucose molecule (RHG). According to fluorescence microscopy and 1H-NMR studies, RHG interacted with the Stern layer of the membrane. The acid/base equilibrium of RHG between its protonated open form (o-RHG) and deprotonated closed spiro-form (c-RHG) at the membrane interface was monitored with UV-vis absorption and fluorescence spectra. The interface pH′ of 25% cardiolipin (CL)-containing large unilamellar vesicles (LUVs), which possess similar lipid properties to those of the IMM, was estimated to be ∼3.9, when the bulk pH was similar to the mitochondrial intermembrane space pH (6.8). However, for the membranes containing mono-anionic lipids, the interface pH′ was estimated to be ∼5.3 at bulk pH 6.8, indicating that the local negative charges of the lipid headgroups in the lipid membranes are responsible for the deviation of the interface pH′ from the bulk pH. The peroxidase activity of cyt c increased 5–7 fold upon lowering the pH to 3.9–4.3 or adding CL-containing (10–25% of total lipids) LUVs compared to that at bulk pH 6.8, indicating that the pH′ decrease at the IMM interface from the bulk pH enhances the peroxidase activity of cyt c. The peroxidase activity of cyt c at the membrane interface of tetraoleoyl CL (TOCL)-enriched (50% of total lipids) LUVs was higher than that estimated from the interface pH′, while the peroxidase activity was similar to that estimated from the interface pH′ for tetramyristoyl CL (TMCL)-enriched LUVs, supporting the hypothesis that when interacting with TOCL (not TMCL), cyt c opens the heme crevice to substrates. The present simple methodology allows us to estimate the interface proton concentrations of complex biological membranes