Factors Influencing Changes of the Initial Stable Water Isotopes Composition in the Seasonal Snowpack of the South of Western Siberia, Russia

Stable water isotopes in snowpack and snowfalls are widely used for understanding hydrological processes occurring in the seasonally snow-covered territories. The present study examines the main factors influencing changes of the initial stable water isotopes composition in the seasonal snow cover of the south of Western Siberia. Studies of the isotopic composition of snow precipitation and snow cover, as well as experiments with them, were carried out during two cold seasons of 2019–2021, and laser spectroscopy PICARRO L2130-i (WS-CRDS) was used for the determination of water isotope composition (δ18O and δD). The main changes in the isotopic composition of the snow cover layers in the studied region are associated with the existence of a vertical temperature gradient between the layers and with the penetration of soil moisture into the bottom layers in the absence of soil freezing. During the winter period, the sublimation from the top layer of snow is observed only at the moments of a sharp increase in the daily air temperature. At the end of winter, the contrast between day and night air temperatures determines the direction of the shift in the isotopic composition of the top layer of snow relative to the initial snow precipitation

Mercury in Hair of Mammoth and Other Prehistorical Mammals as a Proxy of Hg Level in the Environment Associated with Climate Changes

The paper presents the first results of Hg determination in the hair of prehistorical animals (woolly mammoth, steppe bison, and woolly rhino). Hair of prehistorical mammals can be used as an archive that preserves changes of environmental pollution at the paleoscale. The aim of our study was to assess the levels of Hg exposure of ancient animals and to understand whether Hg concentration in hair could be used as a proxy indicating changes of mercury levels in the environment following global climate changes. We assessed changes of Hg exposure recorded in hairs of seven specimens of mammoth fauna mammals that inhabited the Yakutia region in the period from 45 to 10 ka yr BP. Hg concentrations in hair varied from 0.017 to 0.177 µg/g; the lowest Hg concentration were determined in older specimens (45–33 kyr yr BP). The two highest concentrations belonged sample from the Last Glacial Maximum and the Karginian interstadial (57–24 kyr BP) periods. Our hypothesis is the increase of Hg concentrations in hair reflecting environmental Hg level might be forced by high dust load in cold periods and thawing permafrost in warm climatic periods. Long-term variations of Hg level recovered from Ice Age animals’ hair correlate with Hg profiles of concentration and deposition reconstructed from the Antarctica ice core

Ice records provide new insights into climatic vulnerability of Central Asian forest and steppe communities

Forest and steppe communities in the Altai region of Central Asia are threatened by changing climate and anthropogenic pressure. Specifically, increasing drought and grazing pressure may cause collapses of moisture-demanding plant communities, particularly forests. Knowledge about past vegetation and fire responses to climate and land use changes may help anticipating future ecosystem risks, given that it has the potential to disclose mechanisms and processes that govern ecosystem vulnerability. We present a unique paleoecological record from the high-alpine Tsambagarav glacier in the Mongolian Altai that provides novel large-scale information on vegetation, fire and pollution with an exceptional temporal resolution and precision. Our palynological record identifies several late-Holocene boreal forest expansions, contractions and subsequent recoveries. Maximum forest expansions occurred at 3000–2800 BC, 2400–2100 BC, and 1900–1800 BC. After 1800 BC mixed boreal forest communities irrecoverably declined. Fires reached a maximum at 1600 BC, 200 years after the final forest collapse. Our multiproxy data suggest that burning peaked in response to dead biomass accumulation resulting from forest diebacks. Vegetation and fire regimes partly decoupled from climate after 1700 AD, when atmospheric industrial pollution began, and land use intensified. We conclude that moisture availability was more important than temperature for past vegetation dynamics, in particular for forest loss and steppe expansion. The past Mongolian Altai evidence implies that in the future forests of the Russian Altai may collapse in response to reduced moisture availability

Ice-Core Based Assessment of Historical Anthropogenic Heavy Metal (Cd, Cu, Sb, Zn) Emissions in the Soviet Union

The development of strategies and policies aiming at the reduction of environmental exposure to air pollution requires the assessment of historical emissions. Although anthropogenic emissions from the extended territory of the Soviet Union (SU) considerably influenced concentrations of heavy metals in the Northern Hemisphere, Pb is the only metal with long-term historical emission estimates for this region available, whereas for selected other metals only single values exist. Here we present the first study assessing long-term Cd, Cu, Sb, and Zn emissions in the SU during the period 1935–1991 based on ice-core concentration records from Belukha glacier in the Siberian Altai and emission data from 12 regions in the SU for the year 1980. We show that Zn primarily emitted from the Zn production in Ust-Kamenogorsk (East Kazakhstan) dominated the SU heavy metal emission. Cd, Sb, Zn (Cu) emissions increased between 1935 and the 1970s (1980s) due to expanded non-ferrous metal production. Emissions of the four metals in the beginning of the 1990s were as low as in the 1950s, which we attribute to the economic downturn in industry, changes in technology for an increasing metal recovery from ores, the replacement of coal and oil by gas, and air pollution control

An ice-core based history of Siberian forest fires since AD 1250

Forest fires play a key role in the global carbon cycle and thus, can affect regional and global climate. Although fires in extended areas of Russian boreal forests have a considerable influence on atmospheric greenhouse gas and soot concentrations, estimates of their impact on climate are hampered by a lack of data on the history of forest fires. Especially regions with strong continental climate are of high importance due to an intensified development of wildfires. In this study we reconstruct the fire history of Southern Siberia during the past 750 years using ice-core based nitrate, potassium, and charcoal concentration records from Belukha glacier in the continental Siberian Altai. A period of exceptionally high forest-fire activity was observed between AD 1600 and 1680, following an extremely dry period AD 1540-1600. Ice-core pollen data suggest distinct forest diebacks and the expansion of steppe in response to dry climatic conditions. Coherence with a paleoenvironmental record from the 200 km distant Siberian lake Teletskoye shows that the vegetational shift AD 1540-1680, the increase in fire activity AD 1600-1680, and the subsequent recovery of forests AD 1700 were of regional significance. Dead biomass accumulation in response to drought and high temperatures around AD 1600 probably triggered maximum forest-fire activity AD 1600-1680. The extreme dry period in the 16th century was also observed at other sites in Central Asia and is possibly associated with a persistent positive mode of the Pacific Decadal Oscillation (PDO). No significant increase in biomass burning occurred in the Altai region during the last 300 years, despite strongly increasing temperatures and human activities. Our results imply that precipitation changes controlled fire-regime and vegetation shifts in the Altai region during the past 750 years. We conclude that high sensitivity of ecosystems to occasional decadal-scale drought events may trigger unprecedented environmental reorganizations under global-warming conditions