129 research outputs found
Anionic effects observed in complexes of trivalent lanthanides with partitioning relevant N-donor ligands
Complexation of Cm(III) with the recombinant N-lobe of human serum transferrin studied by time-resolved laser fluorescence spectroscopy (TRLFS)
The complexation of Cm(III) with the recombinant N-lobe of human serum transferrin (hTf/2N) is investigated in the pH range from 4.0 to 11.0 using TRLFS. At pH [greater-than-or-equal] 7.4 a Cm(III) hTf/2N species is formed with Cm(III) bound at the Fe(III) binding site. The results are compared with Cm(III) transferrin interaction at the C-lobe and indicate the similarity of the coordination environment of the C- and N-terminal binding sites with four amino acid residues of the protein, two H2O molecules and three additional ligands (e.g. synergistic anions such as carbonate) in the first coordination sphere. Measurements at c(carbonate)tot = 0.23 mM (ambient carbonate concentration) and c(carbonate)tot = 25 mM (physiological carbonate concentration) show that an increase of the total carbonate concentration suppresses the formation of the Cm(III) hTf/2N species significantly. Additionally, the three Cm(III) carbonate species Cm(CO3)+, Cm(CO3)2- and Cm(CO3)33- are formed successively with increasing pH. In general, carbonate complexation is a competing reaction for both Cm(III) complexation with transferrin and hTf/2N but the effect is significantly higher for the half molecule. At c(carbonate)tot = 0.23 mM the complexation of Cm(III) with transferrin and hTf/2N starts at pH [greater-than-or-equal] 7.4. At physiological carbonate concentration the Cm(III) transferrin species II forms at pH [greater-than-or-equal] 7.0 whereas the Cm(III) hTf/2N species is not formed until pH > 10.0. Hence, our results reveal significant differences in the complexation behavior of the C-terminal site of transferrin and the recombinant N-lobe (hTf/2N) towards trivalent actinides
Combined time-resolved laser fluorescence spectroscopy nd extended X-ray absorption fine structure spectroscopy study on the complexatioin of trivalent actinides with chloride at T = 25-200⁰C
Water soluble BTBP ligand - a highly efficient ligand for the separation of Am(III) and Cm(III)
Microbial Transformations of Uranium Complexed with Organic and Inorganic Ligands
Biotransformation of various chemical forms of uranium present in wastes, contaminated soils and materials by microorganisms under different process conditions such as aerobic and anaerobic (denitrifying, iron-reducing, fermentative, and sulfate-reducing) conditions will affect the solubility, bioavailability, and mobility of uranium in the natural environment. Fundamental understanding of the mechanisms of microbial transformations of uranium under a variety of environmental conditions will be useful in developing appropriate remediation and waste management strategies as well as predicting the microbial impacts on the long-term stewardship of contaminated sites
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