Global Climate Cycles

Level M (Master of Science) module: powerpoint lectures and a number of practical

Stable isotope and calcareous nannofossil assemblage record of the late Paleocene and early Eocene (Cicogna section)

We present records of stable carbon and oxygen isotopes, CaCO3 content, and changes in calcareous nannofossil assemblages across an 81 m thick section of upper Paleocene lower Eocene marine sedimentary rocks now exposed along the Cicogna Stream in northeast Italy. The studied stratigraphic section represents sediment accumulation in a bathyal hemipelagic setting from approximately 57.5 to 52.2 Ma, a multi-million-year time interval characterized by perturbations in the global carbon cycle and changes in calcareous nannofossil assemblages. The bulk carbonate delta C-13 profile for the Cicogna section, once placed on a common timescale, resembles that at several other locations across the world, and includes both a long-term drop in delta C-13 and multiple short-term carbon isotope excursions (CIEs). This precise correlation of widely separated delta C-13 records in marine sequences results from temporal changes in the carbon composition of the exogenic carbon cycle. However, diagenesis has likely modified the delta C-13 record at Cicogna, an interpretation supported by variations in bulk carbonate 8180, which do not conform to expectations for a primary signal. The record of CaCO3 content reflects a combination of carbonate dilution and dissolution, as also inferred at other sites. Our detailed documentation and statistical analysis of calcareous nannofossil assemblages show major differences before, during and after the Paleocene Eocene Thermal Maximum. Other CIEs in our lower Paleogene section do not exhibit such a distinctive change;instead, these events are sometimes characterized by variations restricted to a limited number of taxa and transient shifts in the relative abundance of primary assemblage components. Both long-lasting and short-lived modifications to calcareous nannofossil assemblages preferentially affected nannoliths or holococcoliths such as Discoaster,, Fasciculithus, Rhomboaster/Tribrachiatus, Sphenolithus and Zygrhablithus, which underwent distinct variations in abundance as well as permanent evolutionary changes in terms of appearances and disappearances. By contrast, placoliths such as Coccolithus and Tow eius, which represent the main component of the assemblages, were characterized by a gradual decline in abundance over time. Comparisons of detailed nannofossil assemblage records at the Cicogna section and at ODP Site 1262 support the idea that variations in the relative and absolute abundances, even some minor changes, were globally synchronous. An obvious link is through climate forcing and carbon cycling, although the linkages between variations in calcareous nannoplankton, changes in delta C-13 records and oceanography will need additional work

Assessing orbital vs. volcanic control on carbon cycle during the Early Cretaceous

The interval from the Valanginian to the Barremian stages (137?121 Ma; Early Cretaceous) ispunctuated by several episodes of environmental changes, accompanied by shifts in weatheringintensity on the continents and changes in the Tethyan neritic carbonate production. Wesynthetize here the astrochronology of two recent studies performed in the Neuquén basin,Vocontian Basin and Subbetic Domain (Aguirre-Urreta et al., 2019; Martinez et al., 2020), anchoredto CA-ID-TIMS U-Pb ages, which conclusions have been included in the Geologic Time Scale 2020(Gale et al, in press). We applied this time scale to a compilation of carbon-isotope ratio frombelemnites and proxies of detrital supply in the Tethyan area (Vocontian Basin and SubbeticDomain). From this compilation, we show that the episodes of environmental changes are pacedby a 2.4-Myr cycle and, with a lower amplitude, a 1.2-Myr cycle. In addition, the new time scaleshows the synchronicity between the Weissert Event and the Parana-Etendeka Large IgneousProvince. In the series of carbon-isotope ratios measured on belemnite rostra, the amplitude ofthe 2.4-Myr cycle is twice higher during the Valanginian than in the Late Barremian and threetimes higher than in the Hauterivian and Early Barremian, suggesting that the activity of theParana-Etendeka Large Igneous Province amplified the initial orbital forcing to trigger theenvironmental changes observed during the Mid-Valanginian.Fil: Martinez, M.. Géosciences Rennes; FranciaFil: Aguirre Urreta, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Lescano, Marina Aurora. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Dera, G.. Université Paul Sabatier; FranciaFil: Omarini, Julieta. Universidad Nacional de Río Negro. Sede Alto Valle. Instituto de Investigaciones en Paleobiología y Geología; ArgentinaFil: Tunik, Maisa Andrea. Universidad Nacional de Río Negro. Sede Alto Valle. Instituto de Investigaciones en Paleobiología y Geología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Frederichs, Tomas. Universitat Bremen; AlemaniaFil: Palike, Heiko. Université Paul Sabatier; FranciaFil: O'Dogherty, Luis. Universidad de Cádiz; EspañaFil: Aguado, Roque. Universidad de Jaén; EspañaFil: Company, Miguel. Universidad de Granada; EspañaFil: Sandoval, Jose. Universidad de Granada; EspañaEGU General Assembly 2021AlemaniaEuropean Geosciences Unio

Remanence acquisition efficiency in biogenic and detrital magnetite and recording of geomagnetic paleointensity

Relative paleointensity (RPI) variations of Earth's magnetic field are widely used to understand geomagnetic field behavior and to develop age models for sedimentary sequences. RPI estimation is based on a series of assumptions. One key assumption that is rarely considered is that all magnetic particles in the sediment acquired a magnetization in an identical manner. In this paper, we test this assumption for sediments from the eastern equatorial Pacific Ocean that record well-documented global RPI variations over the last ∼780 kyr. The magnetization is carried by two stable single domain magnetic components, which we identify as magnetite magnetofossils and titanomagnetite nanoparticle inclusions within larger silicate particles. By analyzing signals carried by the two components separately, we determine for the first time that magnetic nanoparticle inclusions can cause their host particles to record reliable but inefficient sedimentary paleomagnetic signals. The magnetization carried by biogenic magnetite is acquired more efficiently than that carried by the nanoparticle inclusions. Variations in the concentration of both components are modulated climatically so that they record nearly identical RPI signals. In many sediment types, there is no correlation between the concentrations of different magnetic components so that variable remanence acquisition efficiency will complicate RPI recording. Our work demonstrates that detailed assessment of paleomagnetic recording by each constituent magnetic component needs to become a routine part of sedimentary RPI analysis.The authors acknowledge funding support from: L.C.: China Scholarship Council; A.P.R. and D.H.: Australian Research Council (ARC) through grants DP120103952, DP140104544, and LE120100218; H.V.M.: ARC Future Fellowship FT140100286; E.J.R.: ARC Australian Laureate Fellowship FL120100050; and H.P.: European Research Council grant 617462. We thank Joe Stoner, Marine Geology Repository (MGR), Oregon State University (OSU), for facilitating sampling of the studied sediment core (MGR is supported by NSF grant OCE1558679), Maziet Cheseby (MGR, OSU) for technical support, and Suzanne MacLachlan and Guy Rothwell, BOSCORF, National Oceanography Centre Southampton, for performing the XRF analyses. Data presented in this paper will be uploaded into the MagIC database (https://www2. earthref.org/MagIC)

Cyclostratigraphy and eccentricity tuning of the early Oligocene through early Miocene (30.1–17.1 Ma): Cibicides mundulus stable oxygen and carbon isotope records from Walvis Ridge Site 1264

Few astronomically calibrated high-resolution (≤5 kyr) climate records exist that span the Oligocene–Miocene time interval. Notably, available proxy records show responses varying in amplitude at frequencies related to astronomical forcing, and the main pacemakers of global change on astronomical time-scales remain debated. Here we present newly generated X-ray fluorescence core scanning and benthic foraminiferal stable oxygen and carbon isotope records from Ocean Drilling Program Site 1264 (Walvis Ridge, southeastern Atlantic Ocean). Complemented by data from nearby Site 1265, the Site 1264 benthic stable isotope records span a continuous ∼13-Myr interval of the Oligo-Miocene (30.1–17.1 Ma) at high resolution (∼3.0 kyr). Spectral analyses in the stratigraphic depth domain indicate that the largest amplitude variability of all proxy records is associated with periods of ∼3.4 m and ∼0.9 m, which correspond to 405- and ∼110-kyr eccentricity, using a magnetobiostratigraphic age model. Maxima in CaCO3 content, δ18O and δ13C are interpreted to coincide with ∼110 kyr eccentricity minima. The strong expression of these cycles in combination with the weakness of the precession- and obliquity-related signals allow construction of an astronomical age model that is solely based on tuning the CaCO3 content to the nominal (La2011_ecc3L) eccentricity solution. Very long-period eccentricity maxima (∼2.4-Myr) are marked by recurrent episodes of high-amplitude ∼110-kyr δ18O cycles at Walvis Ridge, indicating greater sensitivity of the climate/cryosphere system to short eccentricity modulation of climatic precession. In contrast, the responses of the global (high-latitude) climate system, cryosphere, and carbon cycle to the 405-kyr cycle, as expressed in benthic δ18O and especially δ13C signals, are more pronounced during ∼2.4-Myr minima. The relationship between the recurrent episodes of high-amplitude ∼110-kyr δ18O cycles and the ∼1.2-Myr amplitude modulation of obliquity is not consistent through the Oligo-Miocene. Identification of these recurrent episodes at Walvis Ridge, and their pacing by the ∼2.4-Myr eccentricity cycle, revises the current understanding of the main climate events of the Oligo-Miocene

Extended orbitally forced palaeoclimatic records from the equatorial Atlantic Ceara Rise

We extend existing high-resolution Oligocene–Miocene proxy records from Ocean Drilling Program (ODP) Leg 154. The extended record spans the time interval from ~17:86 to 26.5 Ma. The data are age calibrated against a new astronomical solution that affords a reevaluation of the intricate interaction between orbital (‘‘Milankovitch’’) forcing of the climate and ocean system, and the fidelity with which this forcing is recorded in oxygen and carbon stable isotope measurements from benthic foraminifera, and associated lithological proxy records of magnetic susceptibility, colour reflectance, and the measured sand fraction. Our records show a very strong continual imprint of the Earth’s obliquity cycle, modulate in amplitude every ~41 ka, a very strong eccentricity signal in the carbon isotope records, and a strong, but probably local, imprint of climatic precession on the coarse fraction and magnetic susceptibility records. Our data allowed us to evaluate how the interaction of long, multi-million year beats in the Earth’s eccentricity and obliquity are implicated in the waxing and waning of ice-sheets, presumably on Antarctica. Our refined age model confirms the revised age of the Oligocene–Miocene boundary, previously established by analysis of the lithological data, and allows a strong correlation with the geomagnetic time scale by comparison with data from ODP Site 1090, Southern Ocean

Should unit-stratotypes and astrochronozones be formally defined? A dual proposal (including postscriptum)

The Global Stratotype Section and Point (GSSP) approach to define stage boundaries leaves the unit or body of the stage undefined. At the same time, previous arguments against the use of unit-stratotypes have been invalidated for the younger Cenozoic part of the geological record through the revolutionary advance in integrated high-resolution stratigraphy and astronomical dating. Combined, these provide unprecedented age control and ensure continuity of sedimentary successions, at least within the time scales of the calibrated astronomical-forced climate oscillations, and offer the possibility to introduce amended unit-stratotypes for global stages. Here we propose that such unit-stratotypes should comprise the entire stage in an astronomically age calibrated deep-marine succession, preferably but not necessarily containing the GSSP. Furthermore, cycles used for the tuning can be formally defined as chronozones, i. e. chronostratigraphic units of either unspecified rank or of a smaller scale than the stage, and independent of the standard hierarchy in global chronostratigraphy. In this way, the standard Geological Time Scale and Global Chronostratigraphic Scale can be brought in line with the progress in integrated high-resolution stratigraphy and astronomical dating. However, the more fundamental formal definition of unit-stratotypes does not depend on the formalization of astrochonozones, and both issues should be separately considered and voted upon