Direct extreme UV-lithographic conversion of metal xanthates into nanostructured metal sulfide layers for hybrid photovoltaics

We present a versatile strategy toward the preparation of nanostructured metal sulfide layers, which exploits the photosensitivity of metal xanthates as a powerful tool for lithographic structuring. Using extreme ultraviolet interference lithography (EUV-IL), we successfully realized well-defined column and comb nanostructures. This approach provides new pathways to fabricate highly ordered structured metal sulfide layers with periodicities far below 100 nm for potential application in hybrid solar cells. © 2013 The Royal Society of Chemistry

ON/OFF switching of silicon wafer electrochemistry by pH-responsive polymer brushes

pH-Switchable electrochemical properties are demonstrated for the first time for native oxide-coated silicon wafer electrodes. Ultrathin and ultrathick pH-responsive poly(methacrylic acid) (PMAA) brushes, obtained by surface-initiated atom transfer radical polymerization, were used to achieve redox gating. PMAA brushes are reversibly switched between their protonated and deprotonated states by alternating acidic and basic pH, which corresponds to a swelling/collapsing behavior. As a result, the electrochemical properties of the PMAA brush-modified silicon electrode are switched "ON" and "OFF" simply by changing pH. The electrochemical properties of the modified electrode were examined by means of cyclic voltammetry and electrochemical impedance spectroscopy both in the absence and presence of ruthenium(iii) hexamine, a well-known cationic redox probe

Towards Amperometric Immunosensor Devices

In contrast to optical immunosensors, the electrochemical detection of an immunoanalytical reaction does require a labeling, but allows an easier discrimination of specific and non-specific binding. We present a concept and first results for a multivalent amperometric immunosensor system which is based on silicon technology. The capture molecule streptavidin, covalently immobilized on silica, allows the immobilization of biotinylated antigens at a defined density. A nanostructured gold electrode serving as a stable network of nanowires is expected to be beneficial for the electrochemical detection of bound ferrocene-labeled antibody molecules. The results presented focus on site-specific immobilization of streptavidin on silica and reduction of non-specific binding of proteins. | In contrast to optical immunosensors, the electrochemical detection of an immunoanalytical reaction does require a labeling, but allows an easier discrimination of specific and non-specific binding. We present a concept and first results for a multivalent amperometric immunosensor system which is based on silicon technology. The capture molecule streptavidin, covalently immobilized on silica, allows the immobilization of biotinylated antigens at a defined density. A nanostructured gold electrode serving as a stable network of nanowires is expected to be beneficial for the electrochemical detection of bound ferrocene-labeled antibody molecules. The results presented focus on site-specific immobilization of streptavidin on silica and reduction of non-specific binding of proteins

Chemical nanopatterns via Nanoimprint Lithography for simultaneous control over azimuthal and polar alignment of liquid crystals

The use of chemical nanopatterns through nanoimprint lithography ato align a nematic liquid crystal (LC) in LC cells was described. It was found that the ratio of areas with different surface-aligning helped in the polar orientation of LC, while the azimuthal orientation was determined by the direction of the chemical patterns. The deviation was found to occur along the lines, demonstrating the average azimuthal orientation of the LC over the cell thickness along the boundary lines. The results show that the chemical patterns with different chemistry and more complex structures can be applied to control all other LC properties, including anchoring conditions and switching behaviors

Beyond 100 nm resolution in 3D laser lithography — Post processing solutions

© 2018 Elsevier B.V. Laser polymerization has emerged as a direct writing technique allowing the fabrication of complex 3D structures with microscale resolution. The technique provides rapid prototyping capabilities for a broad range of applications, but to meet the growing interest in 3D nanoscale structures the resolution limits need to be pushed beyond the 100 nm benchmark, which is challenging in practical implementations. As a possible path towards this goal, a post processing of laser polymerized structures is presented. Precise control of the cross-sectional dimensions of structural elements as well as tuning of an overall size of the entire 3D structure was achieved by combining isotropic plasma etching and pyrolysis. The smallest obtainable feature sizes are mostly limited by the mechanical properties of the polymerized resist and the geometry of the 3D structure. Thus, the demonstrated post processing steps open new avenues to explore free form 3D structures at the nanoscale