Upgrading biogas with novel composite carbon molecular sieve (CCMS) membranes: Experimental and techno-economic assessment

The use of biogas as feedstock for hydrogen production was widely proposed in the literature in the last years as a strategy to reduce anthropogenic carbon emissions. However, its lower heating value compared to natural gas hampers the revamping of existing reforming plants. The use of composite carbon molecular sieve membranes for biogas upgrading (CO2 removal from biogas) was investigated experimentally in this work. In particular, ideal perm-selectivities and permeabilities above the Robeson plot for CO2/CH4 mixtures have been obtained. These membranes show better performances compared to polymeric membranes, which are nowadays commercialized for CO2 separation in natural gas streams. Compared to polymeric membranes, carbon membranes do not show deactivation by plasticization when exposed to CO2, and thus can find industrial application. This work was extended with a techno-economic analysis where carbon membranes are installed in a steam methane reforming plant. Results have been first validated with data from literature and show that the use of biogas increases the costs of hydrogen production to a value of 0.25 €/Nm3 compared to the benchmark technology (0.21 €/Nm3). On the other hand, the use of biogas leads to a decrease in carbon emissions up to 95%, thus the use of biogas for hydrogen production is foreseen as a very interesting alternative to conventional technologies in view of the reduction in the carbon footprint in the novel technologies that are to be installed in the near future

Three-dimensional Dirac oscillator in a thermal bath

The thermal properties of the three-dimensional Dirac oscillator are considered. The canonical partition function is determined, and the high-temperature limit is assessed. The degeneracy of energy levels and their physical implications on the main thermodynamic functions are analyzed, revealing that these functions assume values greater than the one-dimensional case. So that at high temperatures, the limit value of the specific heat is three times bigger.Comment: 9 pages, 4 figures. Text improved, references added. Revised to match accepted version in Europhysics Letters

Relation Discovery from Web Data for Competency Management

This paper describes a technique for automatically discovering associations between people and expertise from an analysis of very large data sources (including web pages, blogs and emails), using a family of algorithms that perform accurate named-entity recognition, assign different weights to terms according to an analysis of document structure, and access distances between terms in a document. My contribution is to add a social networking approach called BuddyFinder which relies on associations within a large enterprise-wide "buddy list" to help delimit the search space and also to provide a form of 'social triangulation' whereby the system can discover documents from your colleagues that contain pertinent information about you. This work has been influential in the information retrieval community generally, as it is the basis of a landmark system that achieved overall first place in every category in the Enterprise Search Track of TREC2006

Aging in coherent noise models and natural time

Event correlation between aftershocks in the coherent noise model is studied by making use of natural time, which has recently been introduced in complex time-series analysis. It is found that the aging phenomenon and the associated scaling property discovered in the observed seismic data are well reproduced by the model. It is also found that the scaling function is given by the $q$-exponential function appearing in nonextensive statistical mechanics, showing power-law decay of event correlation in natural time.Comment: 4 pages and 5 figure