Multi-photon ionisation spectroscopy for rotational state preparation of N+2

In this paper we investigate the 2 + 1′ resonance enhanced multi-photon ionisation (REMPI) of molecular nitrogen via the a1Πg(v = 6) intermediate state and analyse its feasibility to generate molecular nitrogen ions in a well defined ro-vibrational state. This is an important tool for high precision experiments based on trapped molecular ions, and is crucial for studying the time variation of the fundamental constant mp/me using N+2. The transition is not reported in the literature and detailed spectral analysis has been conducted to extract the molecular constants of the intermediate state. By carefully choosing the intermediate ro-vibrational state, the ionisation laser wavelength and controlling the excitation laser pulse energy, unwanted formation of rotationally excited molecular ions can be suppressed and ro-vibrational ground state ions can be generated with high purity

Molecular physics: very cool molecular ions

Achieving full control over all internal and external degrees of freedom of a molecule has been a long-standing goal in molecular physics. Newly developed methods to prepare translationally, vibrationally and rotationally cold molecular ions have brought this target one step closer

Toward a Molecular Ion Qubit

We discuss the application of a novel spectroscopy protocol to study the Zeeman structure of single molecular ions. From molecular structure calculations for 14N+2 and 16O+2 we deduce their Zeeman spectra and discuss their potential to be used as a resource to encode quantum information