Gaussian ellipsoid model for confined polymer systems

Polymer systems in slab geometries are studied on the basis of the recently presented Gaussian Ellipsoid Model [J. Chem. Phys. 114, 7655 (2001)].The potential of the confining walls has an exponential shape. For homogeneous systems in thermodynamic equilibrium we discuss density, orientation and deformation profiles of the polymers close to the walls. For strongly segregated mixtures of polymer components A and B equilibrium profiles are studied near a planar interface separating A and B rich regions. Spinodal decomposition processes of the mixtures in the presence of neutral walls show upon strong confinement an increase of the lateral size of A and B rich domains and a slowing down of the demixing kinetics. These findings are in agreement with predictions from time dependent Ginzburg--Landau theory. In the case, where one wall periodically favors one of the two mixture components over the other, different equilibrium structures emerge and lead to different kinetic pathways of spinodal decomposition processes in such systems.Comment: 18 pages, 16 figures, submitted to J. Chem. Phy

Active fault tolerant control for nonlinear systems with simultaneous actuator and sensor faults

The goal of this paper is to describe a novel fault tolerant tracking control (FTTC) strategy based on robust fault estimation and compensation of simultaneous actuator and sensor faults. Within the framework of fault tolerant control (FTC) the challenge is to develop an FTTC design strategy for nonlinear systems to tolerate simultaneous actuator and sensor faults that have bounded first time derivatives. The main contribution of this paper is the proposal of a new architecture based on a combination of actuator and sensor Takagi-Sugeno (T-S) proportional state estimators augmented with proportional and integral feedback (PPI) fault estimators together with a T-S dynamic output feedback control (TSDOFC) capable of time-varying reference tracking. Within this architecture the design freedom for each of the T-S estimators and the control system are available separately with an important consequence on robust L₂ norm fault estimation and robust L₂ norm closed-loop tracking performance. The FTTC strategy is illustrated using a nonlinear inverted pendulum example with time-varying tracking of a moving linear position reference. Keyword

Fault estimation and active fault tolerant control for linear parameter varying descriptor systems

Starting with the baseline controller design, this paper proposes an integrated approach of active fault tolerant control based on proportional derivative extended state observer (PDESO) for linear parameter varying descriptor systems. The PDESO can simultaneously provide the estimates of the system states, sensor faults, and actuator faults. The L₂ robust performance of the closed-loop system to bounded exogenous disturbance and bounded uncertainty is achieved by a two-step design procedure adapted from the traditional observer-based controller design. Furthermore, an LMI pole-placement region and the L₂ robustness performance are combined into a multiobjective formulation by suitably combing the appropriate LMI descriptions. A parameter-varying system example is given to illustrate the design procedure and the validity of the proposed integrated design approach

Shear Flows of Rapidly Flowing Granular Materials

Shear flows of granular materials are studied in an open channel. The wall shear is calculated from an open channel momentum equation which includes the density variations in the flow. An experimental technique was developed that allowed the measurement of the average density of the flow at different longitudinal locations in the channel. Two sizes of glass beads are examined and results show the variations in the wall shear as a function of various dimensionless parameters

Testable implications of forecast optimality

Evaluation of forecast optimality in economics and finance has almost exclusively been conducted on the assumption of mean squared error loss under which forecasts should be unbiased and forecast errors serially uncorrelated at the single period horizon with increasing variance as the forecast horizon grows. This paper considers properties of optimal forecasts under general loss functions and establishes new testable implications of forecast optimality. These hold when the forecaster’s loss function is unknown but testable restrictions can be imposed on the data generating process, trading off conditions on the data generating process against conditions on the loss function. Finally, we propose flexible parametric estimation of the forecaster’s loss function, and obtain a test of forecast optimality via a test of over-identifying restrictions

Active sensor fault tolerant output feedback tracking control for wind turbine systems via T-S model

This paper presents a new approach to active sensor fault tolerant tracking control (FTTC) for offshore wind turbine (OWT) described via Takagi–Sugeno (T–S) multiple models. The FTTC strategy is designed in such way that aims to maintain nominal wind turbine controller without any change in both fault and fault-free cases. This is achieved by inserting T–S proportional state estimators augmented with proportional and integral feedback (PPI) fault estimators to be capable to estimate different generators and rotor speed sensors fault for compensation purposes. Due to the dependency of the FTTC strategy on the fault estimation the designed observer has the capability to estimate a wide range of time varying fault signals. Moreover, the robustness of the observer against the difference between the anemometer wind speed measurement and the immeasurable effective wind speed signal has been taken into account. The corrected measurements fed to a T–S fuzzy dynamic output feedback controller (TSDOFC) designed to track the desired trajectory. The stability proof with H∞ performance and D-stability constraints is formulated as a Linear Matrix Inequality (LMI) problem. The strategy is illustrated using a non-linear benchmark system model of a wind turbine offered within a competition led by the companies Mathworks and KK-Electronic

Neutrinos from beta processes in a presupernova: probing the isotopic evolution of a massive star

We present a new calculation of the neutrino flux received at Earth from a massive star in the $\sim 24$ hours of evolution prior to its explosion as a supernova (presupernova). Using the stellar evolution code MESA, the neutrino emissivity in each flavor is calculated at many radial zones and time steps. In addition to thermal processes, neutrino production via beta processes is modeled in detail, using a network of 204 isotopes. We find that the total produced $\nu_{e}$ flux has a high energy spectrum tail, at $E \gtrsim 3 - 4$ MeV, which is mostly due to decay and electron capture on isotopes with $A = 50 - 60$. In a tentative window of observability of $E \gtrsim 0.5$ MeV and $t < 2$ hours pre-collapse, the contribution of beta processes to the $\nu_{e}$ flux is at the level of $\sim90\%$ . For a star at $D=1$ kpc distance, a 17 kt liquid scintillator detector would typically observe several tens of events from a presupernova, of which up to $\sim 30\%$ due to beta processes. These processes dominate the signal at a liquid argon detector, thus greatly enhancing its sensitivity to a presupernova.Comment: 14 pages, 5 figure

Synthesis of perfluorinated polyethers

A series of highly fluorinated acetylenes was prepared and their cyclization reactions were studied. A series of perfluoropolytriazines with -CF2I pendent groups were prepared. These materials can be cured thermally or photochemically to an elastomeric gum. Perfluoropolytriazines with -CN pendent groups were prepared. These materials can be crosslinked by reaction with terephthalonitrile oxide

Ocean services user needs assessment. Volume 1: Survey results, conclusions and recommendations

An interpretation of environmental information needs of marine users, derived from a direct contact survey of eight important sectors of the marine user community is presented. Findings of the survey and results and recommendations are reported. The findings consist of specific and quantized measurement and derived product needs for each sector and comparisons of these needs with current and planned NOAA data and services. The following supportive and reference material are examined: direct contact interviews with industry members, analyses of current NOAA data gathering and derived product capabilities, evaluations of new and emerging domestic and foreign satellite data gathering capabilities, and a special commercial fishing survey conducted by the Jet Propulsion Laboratory (JPL)