Statistical mechanics of permanent random atomic and molecular networks: Structure and heterogeneity of the amorphous solid state

Under sufficient permanent random covalent bonding, a fluid of atoms or small molecules is transformed into an amorphous solid network. Being amorphous, local structural properties in such networks vary across the sample. A natural order parameter, resulting from a statistical-mechanical approach, captures information concerning this heterogeneity via a certain joint probability distribution. This joint probability distribution describes the variations in the positional and orientational localization of the particles, reflecting the random environments experienced by them, as well as further information characterizing the thermal motion of particles. A complete solution, valid in the vicinity of the amorphous solidification transition, is constructed essentially analytically for the amorphous solid order parameter, in the context of the random network model and approach introduced by Goldbart and Zippelius [Europhys. Lett. 27, 599 (1994)]. Knowledge of this order parameter allows us to draw certain conclusions about the stucture and heterogeneity of randomly covalently bonded atomic or molecular network solids in the vicinity of the amorphous solidification transition. Inter alia, the positional aspects of particle localization are established to have precisely the structure obtained perviously in the context of vulcanized media, and results are found for the analogue of the spin glass order parameter describing the orientational freezing of the bonds between particles.Comment: 31 pages, 5 figure

Density-correlator signatures of the vulcanization transition

Certain density correlators, measurable via various experimental techniques, are studied in the context of the vulcanization transition. It is shown that these correlators contain essential information about both the vulcanization transition and the emergent amorphous solid state. Contact is made with various physical ingredients that have featured in experimental studies of amorphous colloidal and gel systems and in theoretical studies of the glassy state.Comment: 7 pages, 1 figur

Density-correlator signatures of the vulcanization transition

Certain density correlators, measurable via various experimental techniques, are studied in the context of the vulcanization transition. It is shown that these correlators contain essential information about both the vulcanization transition and the emergent amorphous solid state. Contact is made with various physical ingredients that have featured in experimental studies of amorphous colloidal and gel systems and in theoretical studies of the glassy state.Comment: 7 pages, 1 figur

Connecting the vulcanization transition to percolation

The vulcanization transition is addressed via a minimal replica-field-theoretic model. The appropriate long-wave-length behavior of the two- and three-point vertex functions is considered diagrammatically, to all orders in perturbation theory, and identified with the corresponding quantities in the Houghton-Reeve-Wallace field-theoretic approach to the percolation critical phenomenon. Hence, it is shown that percolation theory correctly captures the critical phenomenology of the vulcanization transition associated with the liquid and critical states.Comment: 9 pages, 5 figure

Vortex lattice stability in the SO(5) model

We study the energetics of superconducting vortices in the SO(5) model for high-$T_c$ materials proposed by Zhang. We show that for a wide range of parameters normally corresponding to type II superconductivity, the free energy per unit flux \FF(m) of a vortex with $m$ flux quanta is a decreasing function of $m$, provided the doping is close to its critical value. This implies that the Abrikosov lattice is unstable, a behaviour typical of type I superconductors. For dopings far from the critical value, \FF(m) can become very flat, indicating a less rigid vortex lattice, which would melt at a lower temperature than expected for a BCS superconductor.Comment: 4 pp, revtex, 5 figure

Flocking from a quantum analogy: spin–orbit coupling in an active fluid

Theoretical Physic

Competing orders in a magnetic field: spin and charge order in the cuprate superconductors

We describe two-dimensional quantum spin fluctuations in a superconducting Abrikosov flux lattice induced by a magnetic field applied to a doped Mott insulator. Complete numerical solutions of a self-consistent large N theory provide detailed information on the phase diagram and on the spatial structure of the dynamic spin spectrum. Our results apply to phases with and without long-range spin density wave order and to the magnetic quantum critical point separating these phases. We discuss the relationship of our results to a number of recent neutron scattering measurements on the cuprate superconductors in the presence of an applied field. We compute the pinning of static charge order by the vortex cores in the `spin gap' phase where the spin order remains dynamically fluctuating, and argue that these results apply to recent scanning tunnelling microscopy (STM) measurements. We show that with a single typical set of values for the coupling constants, our model describes the field dependence of the elastic neutron scattering intensities, the absence of satellite Bragg peaks associated with the vortex lattice in existing neutron scattering observations, and the spatial extent of charge order in STM observations. We mention implications of our theory for NMR experiments. We also present a theoretical discussion of more exotic states that can be built out of the spin and charge order parameters, including spin nematics and phases with `exciton fractionalization'.Comment: 36 pages, 33 figures; for a popular introduction, see http://onsager.physics.yale.edu/superflow.html; (v2) Added reference to new work of Chen and Ting; (v3) reorganized presentation for improved clarity, and added new appendix on microscopic origin; (v4) final published version with minor change

Connections between relative entropy of entanglement and geometric measure of entanglement

As two of the most important entanglement measures---the entanglement of formation and the entanglement of distillation---have so far been limited to bipartite settings, the study of other entanglement measures for multipartite systems appears necessary. Here, connections between two other entanglement measures---the relative entropy of entanglement and the geometric measure of entanglement---are investigated. It is found that for arbitrary pure states the latter gives rise to a lower bound on the former. For certain pure states, some bipartite and some multipartite, this lower bound is saturated, and thus their relative entropy of entanglement can be found analytically in terms of their known geometric measure of entanglement. For certain mixed states, upper bounds on the relative entropy of entanglement are also established. Numerical evidence strongly suggests that these upper bounds are tight, i.e., they are actually the relative entropy of entanglement.</jats:p