24 research outputs found
Sterols sense swelling in lipid bilayers
In the mimetic membrane system of phosphatidylcholine bilayers, thickening
(pre-critical behavior, anomalous swelling) of the bilayers is observed, in the
vicinity of the main transition, which is non-linear with temperature. The
sterols cholesterol and androsten are used as sensors in a time-resolved
simultaneous small- and wide angle x-ray diffraction study to investigate the
cause of the thickening. We observe precritical behavior in the pure lipid
system, as well as with sterol concentrations less than 15%. To describe the
precritical behavior we introduce a theory of precritical phenomena.The good
temperature resolution of the data shows that a theory of the influence of
fluctuations needs modification. The main cause of the critical behavior
appears to be a changing hydration of the bilayer.Comment: 11 pages, 7 ps figures included, to appear in Phys.Rev.
Conformal mapping methods for interfacial dynamics
The article provides a pedagogical review aimed at graduate students in
materials science, physics, and applied mathematics, focusing on recent
developments in the subject. Following a brief summary of concepts from complex
analysis, the article begins with an overview of continuous conformal-map
dynamics. This includes problems of interfacial motion driven by harmonic
fields (such as viscous fingering and void electromigration), bi-harmonic
fields (such as viscous sintering and elastic pore evolution), and
non-harmonic, conformally invariant fields (such as growth by
advection-diffusion and electro-deposition). The second part of the article is
devoted to iterated conformal maps for analogous problems in stochastic
interfacial dynamics (such as diffusion-limited aggregation, dielectric
breakdown, brittle fracture, and advection-diffusion-limited aggregation). The
third part notes that all of these models can be extended to curved surfaces by
an auxilliary conformal mapping from the complex plane, such as stereographic
projection to a sphere. The article concludes with an outlook for further
research.Comment: 37 pages, 12 (mostly color) figure
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