724 research outputs found
Hallmarks of mechanochemistry: From nanoparticles to technology
The aim of this review article on recent developments of mechanochemistry (nowadays established as a part of chemistry) is to provide a comprehensive overview of advances achieved in the field of atomistic processes, phase transformations, simple and multicomponent nanosystems and peculiarities of mechanochemical reactions. Industrial aspects with successful penetration into fields like materials engineering, heterogeneous catalysis and extractive metallurgy are also reviewed. The hallmarks of mechanochemistry include influencing reactivity of solids by the presence of solid-state defects, interphases and relaxation phenomena, enabling processes to take place under non-equilibrium conditions, creating a well-crystallized core of nanoparticles with disordered near-surface shell regions and performing simple dry time-convenient one-step syntheses. Underlying these hallmarks are technological consequences like preparing new nanomaterials with the desired properties or producing these materials in a reproducible way with high yield and under simple and easy operating conditions. The last but not least hallmark is enabling work under environmentally friendly and essentially waste-free conditions (822 references).Slovak Grant Agency VEGA 2/0009/11, 2/0043/11Slovak Agency for Science and Development APVV VV-0189-10, VV-0528-11Russian Foundation for Basic Research 10-03-00942a, 12-03-00651aMinistry of Science and Higher education in Poland CUT/c-1/DS/KWC/2008-2012, PB1T09B02330, NN209145136, NN20914893
Studies of unicellular micro-organisms Saccharomyces cerevisiae by means of Positron Annihilation Lifetime Spectroscopy
Results of Positron Annihilation Lifetime Spectroscopy (PALS) and microscopic
studies on simple microorganisms: brewing yeasts are presented. Lifetime of
ortho - positronium (o-Ps) were found to change from 2.4 to 2.9 ns (longer
lived component) for lyophilised and aqueous yeasts, respectively. Also
hygroscopicity of yeasts in time was examined, allowing to check how water -
the main component of the cell - affects PALS parameters, thus lifetime of o-Ps
were found to change from 1.2 to 1.4 ns (shorter lived component) for the dried
yeasts. The time sufficient to hydrate the cells was found below 10 hours. In
the presence of liquid water an indication of reorganization of yeast in the
molecular scale was observed.
Microscopic images of the lyophilised, dried and wet yeasts with best
possible resolution were obtained using Inverted Microscopy (IM) and
Environmental Scanning Electron Microscopy (ESEM) methods. As a result visible
changes to the surface of the cell membrane were observed in ESEM images.Comment: Nukleonika (2015
Compressive Sensing of Signals Generated in Plastic Scintillators in a Novel J-PET Instrument
The J-PET scanner, which allows for single bed imaging of the whole human
body, is currently under development at the Jagiellonian University. The dis-
cussed detector offers improvement of the Time of Flight (TOF) resolution due
to the use of fast plastic scintillators and dedicated electronics allowing for
sam- pling in the voltage domain of signals with durations of few nanoseconds.
In this paper we show that recovery of the whole signal, based on only a few
samples, is possible. In order to do that, we incorporate the training signals
into the Tikhonov regularization framework and we perform the Principal
Component Analysis decomposition, which is well known for its compaction
properties. The method yields a simple closed form analytical solution that
does not require iter- ative processing. Moreover, from the Bayes theory the
properties of regularized solution, especially its covariance matrix, may be
easily derived. This is the key to introduce and prove the formula for
calculations of the signal recovery error. In this paper we show that an
average recovery error is approximately inversely proportional to the number of
acquired samples
Beam profile investigation of the new collimator system for the J-PET detector
Jagiellonian Positron Emission Tomograph (J-PET) is a multi-purpose detector
which will be used for search for discrete symmetries violations in the decays
of positronium atoms and for investigations with positronium atoms in
life-sciences and medical diagnostics. In this article we present three methods
for determination of the beam profile of collimated annihilation gamma quanta.
Precise monitoring of this profile is essential for time and energy calibration
of the J-PET detector and for the determination of the library of model signals
used in the hit-time and hit-position reconstruction. We have we have shown
that usage of two lead bricks with dimensions of 5x10x20 cm^3 enables to form a
beam of annihilation quanta with Gaussian profile characterized by 1 mm FWHM.
Determination of this characteristic is essential for designing and
construction the collimator system for the 24-module J-PET prototype.
Simulations of the beam profile for different collimator dimensions were
performed. This allowed us to choose optimal collimation system in terms of the
beam profile parameters, dimensions and weight of the collimator taking into
account the design of the 24 module J-PET detector.Comment: 14 pages, 9 figure
Application of the Compress Sensing Theory for Improvement of the TOF Resolution in a Novel J-PET Instrument
Nowadays, in Positron Emission Tomography (PET) systems, a Time of Flight
information is used to improve the image reconstruction process. In Time of
Flight PET (TOF-PET), fast detectors are able to measure the difference in the
arrival time of the two gamma rays, with the precision enabling to shorten
significantly a range along the line-of-response (LOR) where the annihilation
occurred. In the new concept, called J-PET scanner, gamma rays are detected in
plastic scintillators. In a single strip of J-PET system, time values are
obtained by probing signals in the amplitude domain. Owing to Compress Sensing
theory, information about the shape and amplitude of the signals is recovered.
In this paper we demonstrate that based on the acquired signals parameters, a
better signal normalization may be provided in order to improve the TOF
resolution. The procedure was tested using large sample of data registered by a
dedicated detection setup enabling sampling of signals with 50 ps intervals.
Experimental setup provided irradiation of a chosen position in the plastic
scintillator strip with annihilation gamma quanta
Heralded generation of entangled photon pairs
Entangled photons are a crucial resource for quantum communication and linear
optical quantum computation. Unfortunately, the applicability of many
photon-based schemes is limited due to the stochastic character of the photon
sources. Therefore, a worldwide effort has focused in overcoming the limitation
of probabilistic emission by generating two-photon entangled states conditioned
on the detection of auxiliary photons. Here we present the first heralded
generation of photon states that are maximally entangled in polarization with
linear optics and standard photon detection from spontaneous parametric
down-conversion. We utilize the down-conversion state corresponding to the
generation of three photon pairs, where the coincident detection of four
auxiliary photons unambiguously heralds the successful preparation of the
entangled state. This controlled generation of entangled photon states is a
significant step towards the applicability of a linear optics quantum network,
in particular for entanglement swapping, quantum teleportation, quantum
cryptography and scalable approaches towards photonics-based quantum computing
Searches for discrete symmetries violation in ortho-positronium decay using the J-PET detector
In this paper we present prospects for using the J-PET detector to search for
discrete symmetries violations in a purely leptonic system of the positronium
atom. We discuss tests of CP and CPT symmetries by means of ortho-positronium
decays into three photons. No zero expectation values for chosen correlations
between ortho-positronium spin and momentum vectors of photons would imply the
existence of physics phenomena beyond the Standard Model. Previous measurements
resulted in violation amplitude parameters for CP and CPT symmetries consistent
with zero, with an uncertainty of about 10-3. The J-PET detector allows to
determine those values with better precision thanks to a unique time and
angular esolution combined with a high geometrical acceptance. Achieving the
aforementioned is possible due to application of polymer scintillators instead
of crystals as detectors of annihilation quanta.Comment: in Nukleonika 201
Test of a single module of the J-PET scanner based on plastic scintillators
Time of Flight Positron Emission Tomography scanner based on plastic
scintillators is being developed at the Jagiellonian University by the J-PET
collaboration. The main challenge of the conducted research lies in the
elaboration of a method allowing application of plastic scintillators for the
detection of low energy gamma quanta. In this article we report on tests of a
single detection module built out from BC-420 plastic scintillator strip (with
dimensions of 5x19x300mm^3) read out at two ends by Hamamatsu R5320
photomultipliers. The measurements were performed using collimated beam of
annihilation quanta from the 68Ge isotope and applying the Serial Data Analyzer
(Lecroy SDA6000A) which enabled sampling of signals with 50ps intervals. The
time resolution of the prototype module was established to be better than 80ps
(sigma) for a single level discrimination. The spatial resolution of the
determination of the hit position along the strip was determined to be about
0.93cm (sigma) for the annihilation quanta. The fractional energy resolution
for the energy E deposited by the annihilation quanta via the Compton
scattering amounts to sigma(E)/E = 0.044/sqrt(E[MeV]) and corresponds to the
sigma(E)/E of 7.5% at the Compton edge.Comment: 12 pages, 6 figures; Updated with editorial corrections related to
publication in NIM
Analysis framework for the J-PET scanner
J-PET analysis framework is a flexible, lightweight, ROOT-based software
package which provides the tools to develop reconstruction and calibration
procedures for PET tomography. In this article we present the implementation of
the full data-processing chain in the J-PET framework which is used for the
data analysis of the J-PET tomography scanner. The Framework incorporates
automated handling of PET setup parameters' database as well as high level
tools for building data reconstruction procedures. Each of these components is
briefly discussed.Comment: 6 pages, 1 figur
Potential of the J-PET detector for studies of discrete symmetries in decays of positronium atom - a purely leptonic system
The Jagiellonian Positron Emission Tomograph (J-PET) was constructed as a
prototype of the cost-effective scanner for the simultaneous metabolic imaging
of the whole human body. Being optimized for the detection of photons from the
electron-positron annihilation with high time- and high angular-resolution, it
constitutes a multi-purpose detector providing new opportunities for studying
the decays of positronium atoms. Positronium is the lightest purely leptonic
object decaying into photons. As an atom bound by a central potential it is a
parity eigenstate, and as an atom built out of an electron and an anti-electron
it is an eigenstate of the charge conjugation operator. Therefore, the
positronium is a unique laboratory to study discrete symmetries whose precision
is limited in principle by the effects due to the weak interactions expected at
the level of (~10) and photon-photon interactions expected at the level
of (~10). The J-PET detector enables to perform tests of discrete
symmetries in the leptonic sector via the determination of the expectation
values of the discrete-symmetries-odd operators, which may be constructed from
the spin of ortho-positronium atom and the momenta and polarization vectors of
photons originating from its annihilation. In this article we present the
potential of the J-PET detector to test the C, CP, T and CPT symmetries in the
decays of positronium atoms.Comment: 27 pages, 6 figure
- …