8,946 research outputs found
Photocatalytic production of organic compounds from CO and H2O in a simulated Martian atmosphere
[14C]CO2 and [14C]organic compounds are formed when a mixture of [14C]CO and water vapor diluted in [12C]CO2 or N2 is irradiated with ultraviolet light in the presence of soil or pulverized vycor substratum. The [14C]CO2 is recoverable from the gas phase, the [14C]organic products from the substratum. Three organic products have been tentatively identified as formaldehyde, acetaldehyde, and glycolic acid. The relative yields of [14C]CO2 and [14C]organics are wavelength- and surface-dependent. Conversion of CO to CO2 occurs primarily at wavelengths shorter than 2000 angstrom, apparently involves the photolysis of water, and is inhibited by increasing amounts of vycor substratum. Organic formation occurs over a broad spectral range below 3000 angstrom and increases with increasing amounts of substratum. It is suggested that organic synthesis results from adsorption of CO and H2O on surfaces, with excitation of one or both molecules occurring at wavelengths longer than those absorbed by the free gases. This process may occur on Mars and may have been important on the primitive earth
Exact Solution of a Electron System Combining Two Different t-J Models
A new strongly correlated electron model is presented. This is formed by two
types of sites: one where double occupancy is forbidden, as in the t-J model,
and the other where double occupancy is allowed but vacancy is not allowed, as
an inverse t-J model. The Hamiltonian shows nearest and next-to-nearest
neighbour interactions and it is solved by means of a modified algebraic nested
Bethe Ansatz. The number of sites where vacancy is not allowed, may be treated
as a new parameter if the model is looked at as a t-J model with impurities.
The ground and excited states are described in the thermodynamic limit.Comment: Some corrections and references added. To be published in J. Phys.
Cumulant expansion of the periodic Anderson model in infinite dimension
The diagrammatic cumulant expansion for the periodic Anderson model with
infinite Coulomb repulsion () is considered here for an hypercubic
lattice of infinite dimension (). The same type of simplifications
obtained by Metzner for the cumulant expansion of the Hubbard model in the
limit of , are shown to be also valid for the periodic Anderson
model.Comment: 13 pages, 7 figures.ps. To be published in J. Phys. A: Mathematical
and General (1997
Mineral Processing by Short Circuits in Protoplanetary Disks
Meteoritic chondrules were formed in the early solar system by brief heating
of silicate dust to melting temperatures. Some highly refractory grains (Type B
calcium-aluminum-rich inclusions, CAIs) also show signs of transient heating. A
similar process may occur in other protoplanetary disks, as evidenced by
observations of spectra characteristic of crystalline silicates. One possible
environment for this process is the turbulent magnetohydrodynamic flow thought
to drive accretion in these disks. Such flows generally form thin current
sheets, which are sites of magnetic reconnection, and dissipate the magnetic
fields amplified by a disk dynamo. We suggest that it is possible to heat
precursor grains for chondrules and other high-temperature minerals in current
sheets that have been concentrated by our recently described short-circuit
instability. We extend our work on this process by including the effects of
radiative cooling, taking into account the temperature dependence of the
opacity; and by examining current sheet geometry in three-dimensional, global
models of magnetorotational instability. We find that temperatures above 1600 K
can be reached for favorable parameters that match the ideal global models.
This mechanism could provide an efficient means of tapping the gravitational
potential energy of the protoplanetary disk to heat grains strongly enough to
form high-temperature minerals. The volume-filling nature of turbulent magnetic
reconnection is compatible with constraints from chondrule-matrix
complementarity, chondrule-chondrule complementarity, the occurrence of igneous
rims, and compound chondrules. The same short-circuit mechanism may perform
other high-temperature mineral processing in protoplanetary disks such as the
production of crystalline silicates and CAIs.Comment: 6 pages, 3 figures, ApJL published versio
Temperature Fluctuations driven by Magnetorotational Instability in Protoplanetary Disks
The magnetorotational instability (MRI) drives magnetized turbulence in
sufficiently ionized regions of protoplanetary disks, leading to mass
accretion. The dissipation of the potential energy associated with this
accretion determines the thermal structure of accreting regions. Until
recently, the heating from the turbulence has only been treated in an
azimuthally averaged sense, neglecting local fluctuations. However, magnetized
turbulence dissipates its energy intermittently in current sheet structures. We
study this intermittent energy dissipation using high resolution numerical
models including a treatment of radiative thermal diffusion in an optically
thick regime. Our models predict that these turbulent current sheets drive
order unity temperature variations even where the MRI is damped strongly by
Ohmic resistivity. This implies that the current sheet structures where energy
dissipation occurs must be well resolved to correctly capture the flow
structure in numerical models. Higher resolutions are required to resolve
energy dissipation than to resolve the magnetic field strength or accretion
stresses. The temperature variations are large enough to have major
consequences for mineral formation in disks, including melting chondrules,
remelting calcium-aluminum rich inclusions, and annealing silicates; and may
drive hysteresis: current sheets in MRI active regions could be significantly
more conductive than the remainder of the disk.Comment: 16 pages, 13 figures, ApJ In Press, updated to match proof
Many-body approach to the nonlinear interaction of charged particles with an interacting free electron gas
We report various many-body theoretical approaches to the nonlinear decay
rate and energy loss of charged particles moving in an interacting free
electron gas. These include perturbative formulations of the scattering matrix,
the self-energy, and the induced electron density. Explicit expressions for
these quantities are obtained, with inclusion of exchange and correlation
effects.Comment: 11 pages, 5 figures. To appear in Journal of Physics
Quantum Lifshitz point in the infinite dimensional Hubbard model
We show that the Gutzwiller variational wave function is surprisingly
accurate for the computation of magnetic phase boundaries in the infinite
dimensional Hubbard model. This allows us to substantially extend known phase
diagrams. For both the half-hypercubic and the hypercubic lattice a large part
of the phase diagram is occupied by an incommensurate phase, intermediate
between the ferromagnetic and the paramagnetic phase. In case of the hypercubic
lattice the three phases join at a new quantum Lifshitz point at which the
order parameter is critical and the stiffness vanishes.Comment: 4 pages, 3 figure
Ferromagnetism in the Periodic Anderson Model - a Modified Alloy Analogy
We introduce a new aproximation scheme for the periodic Anderson model (PAM).
The modified alloy approximation represents an optimum alloy approximation for
the strong coupling limit, which can be solved within the CPA-formalism.
Zero-temperature and finite-temperature phase diagrams are presented for the
PAM in the intermediate-valence regime. The diversity of magnetic properties
accessible by variation of the system parameters can be studied by means of
quasiparticle densities of states: The conduction band couples either ferro- or
antiferromagneticaly to the f-levels. A finite hybridization is a necessary
precondition for ferromagnetism. However, too strong hybridization generally
suppresses ferromagnetism, but can for certain system parameters also lead to a
semi-metallic state with unusual magnetic properties. By comparing with the
spectral density approximation, the influence of quasiparticle damping can be
examined.Comment: 20 pages, 13 figure
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