Predicting Big Bang Deuterium

We present new upper and lower bounds to the primordial abundances of deuterium and helium-3 based on observational data from the solar system and the interstellar medium. Independent of any model for the primordial production of the elements we find (at the 95\% C.L.): $1.5 \times 10^{-5} \le (D/H)_P \le 10.0 \times 10^{-5}$ and $(^3He/H)_P \le 2.6\times 10^{-5}$. When combined with the predictions of standard big bang nucleosynthesis, these constraints lead to a 95\% C.L. bound on the primordial abundance of deuterium: $(D/H)_{best} = (3.5^{+2.7}_{-1.8})\times 10^{-5}$. Measurements of deuterium absorption in the spectra of high redshift QSOs will directly test this prediction. The implications of this prediction for the primordial abundances of helium-4 and lithium-7 are discussed, as well as those for the universal density of baryons.Comment: Revised version of paper to reflect comments of the referee and reply to suggestions of Copi, Schramm, and Turner regarding the overall analysis and treatment of chemical evolution of D and He-3. Best-fit D/H abundance changes from (2.3 + 3.0 - 1.0)x10^{-5} to (3.5 +2.7 - 1.8) x10^{-5}. See also hep-ph/950531

Neutrino degeneracy and cosmological nucleosynthesis, revisited

A reexamination of the effects of non-zero degeneracies on Big Bang Nucleosynthesis is made. As previously noted, non-trivial alterations of the standard model conclusions can be induced only if excess lepton numbers L sub i, comparable to photon number densities eta sub tau, are assumed (where eta sub tau is approx. 3 times 10(exp 9) eta sub b). Furthermore, the required lepton number densities (L sub i eta sub tau) must be different for upsilon sub e than for upsilon sub mu and epsilon sub tau. It is shown that this loophole in the standard model of nucleosynthesis is robust and will not vanish as abundance and reaction rate determinations improve. However, it is also argued that theoretically (L sub e) approx. (L sub mu) approx. (L sub tau) approx. eta sub b is much less than eta sub tau which would preclude this loophole in standard unified models

Big-bang nucleosynthesis revisited

The homogeneous big-bang nucleosynthesis yields of D, He-3, He-4, and Li-7 are computed taking into account recent measurements of the neutron mean-life as well as updates of several nuclear reaction rates which primarily affect the production of Li-7. The extraction of primordial abundances from observation and the likelihood that the primordial mass fraction of He-4, Y(sub p) is less than or equal to 0.24 are discussed. Using the primordial abundances of D + He-3 and Li-7 we limit the baryon-to-photon ratio (eta in units of 10 exp -10) 2.6 less than or equal to eta(sub 10) less than or equal to 4.3; which we use to argue that baryons contribute between 0.02 and 0.11 to the critical energy density of the universe. An upper limit to Y(sub p) of 0.24 constrains the number of light neutrinos to N(sub nu) less than or equal to 3.4, in excellent agreement with the LEP and SLC collider results. We turn this argument around to show that the collider limit of 3 neutrino species can be used to bound the primordial abundance of He-4: 0.235 less than or equal to Y(sub p) less than or equal to 0.245

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres

Powertrain dynamics and control of a two speed dual clutch transmission for electric vehicles

© 2016 Elsevier Ltd The purpose of this paper is to demonstrate the application of torque based powertrain control for multi-speed power shifting capable electric vehicles. To do so simulation and experimental studies of the shift transient behaviour of dual clutch transmission equipped electric vehicle powertrains is undertaken. To that end a series of power-on and power-off shift control strategies are then developed for both up and down gear shifts, taking note of the friction load requirements to maintain positive driving load for power-on shifting. A mathematical model of an electric vehicle powertrain is developed including a DC equivalent circuit model for the electric machine and multi-body dynamic model of the powertrain system is then developed and integrated with a hydraulic clutch control system model. Integral control of the powertrain is then performed through simulations on the develop powertrain system model for each of the four shift cases. These simulation results are then replicated on a full scale powertrain test rig. To evaluate the performance of results shift duration and vehicle jerk are used as metrics to demonstrate that the presented strategies are effective for shift control in electric vehicles. Qualitative comparison of both theoretical and experimental results demonstrates reasonable agreement between simulated and experimental outcomes