Improving Monolithic Perovskite Silicon Tandem Solar Cells From an Optical Viewpoint

Perovskite silicon tandem solar cells are the most promising concept for a future photovoltaic technology. We report on recent progress from an optical viewpoint and disucss how we achieved more than 25 device efficienc

Thermoelectric Processes and Materials

Contains reports on three research projects.United States Navy, Office of Naval Research (Contract Nonr-1841(51)

EXPLORING SIMILARITIES AND VARIATIONS OF HUMAN MOBILITY PATTERNS IN THE CITY OF LONDON

The availability of new spatial data represents an unprecedented opportunity to better understand and plan cities. In particular, extensive data sets of human mobility data supply new information that can empower urbanism research to unveil how people use and visit urban places over time, overcoming traditional limitations related to the lack of large, detailed data sets. In this work, we explore patterns of similarities and spatial differences in human mobility flows in London, analysing their temporal variations in relation to the liveliness measured in a number of places. Using data sourced from the Oyster smart card and Twitter, we perform a time-series cluster analysis, exploring the similarity of temporal trends amongst places assigned to each cluster. Results suggest that differences in patterns appear to be related to the central and peripheral location of places, which present two or more temporal trends over the week. The type of transport network connecting the places (Tube, Railways, etc.) also appears to be a factor in determining significant differences. This work contributes to current urbanism research investigating the daily rhythms in cities. It also explores how to use mobility data to classify places according to their temporal features, with the aim of enhancing conventional analysis tools and integrating them with new quantitative information and methods

Comparing Extraction Methods for Biomarker Steroid Characterisation from Soil and Slurry

Clean water is a precious resource, and policies/programmes are implemented worldwide to protect and/or improve water quality. Faecal pollution can be a key contributor to water quality decline causing eutrophication through nutrient enrichment and pathogenic contamination. The robust sourcing of faecal pollutants is important to be able to target the appropriate sector and to engage managers. Biomarker technology has the potential for source confirmation, by using, for example the biomarker suite of steroids. Steroids have been used in the differentiation of human and animal faeces; however, there is no unequivocal extraction technique. Some of the methods used include (i) Soxhlet extraction, (ii) Bligh and Dyer (BD) extraction, and (iii) accelerated solvent extraction (ASE). The less costly and time intensive technique of ASE is particularly attractive, but a current research gap concerns further comparisons regarding ASE lipid extraction from soils/slurries compared with the more traditional Soxhlet and BD extractions. Accordingly, a randomised complete block experiment was implemented to assess differences between the three extraction methods, differences between the different sample types, and the interactions between these two factors. Following GC-MS, it was found that there was no significant difference between the results of the steroid extraction methods, regardless of the type of sample used, for the quantity of each steroid extracted. It was concluded that ASE could be used confidently instead of the more established steroid extraction methods, thereby delivering time and cost savings

Coupled steroid and phosphorus leaching from cattle slurry at lysimeter scale

Water quality degradation can be caused by excessive agricultural nutrient transfers from fertilised soils exposed to wet weather. Mitigation measures within the EU Nitrates Directive aim to reduce this pressure by including ‘closed’ fertiliser spreading periods during wet months. For organic fertilisers such as slurry and manure, this closed period requires sufficient on-farm winter storage and good weather conditions to relieve storage at the end of the period. Therefore, robust scientific evidence is needed to support the measure. Incidental nutrient transfers of recently applied organic fertilisers in wet weather can also be complicated by synchronous transfers from residual soil stores and tracing is required for risk assessments. The combination of nutrient monitoring and biomarker analyses may aid this and one such biomarker suite is faecal steroids. Accordingly, this study investigated the persistence of steroids and their association with phosphorus during leaching episodes. The focus was on the coupled behaviour of steroids and total phosphorus (TP) concentrations in sub-surface hydrological pathways. Cattle slurry was applied to monolith lysimeters either side of a closed period and concentrations of both steroids and TP were monitored in the leachate. The study showed no significant effect of the treatment (average p = 0.17), though tracer concentrations did significantly change over time (average p = 0.001). While the steroidal concentration ratio was validated for herbivorous faecal pollution in the leachate, there was a weak positive correlation between the steroids and TP. Further investigation at more natural scales (hillslope/catchment) is required to confirm tracer behaviours/correlations and to compliment this sub-surface pathway study

Length scale dependence of dynamical heterogeneity in a colloidal fractal gel

We use time-resolved dynamic light scattering to investigate the slow dynamics of a colloidal gel. The final decay of the average intensity autocorrelation function is well described by $g\_2(q,\tau)-1 \sim \exp[-(\tau/\tau\_\mathrm{f})^p]$, with $\tau\_\mathrm{f} \sim q^{-1}$ and $p$ decreasing from 1.5 to 1 with increasing $q$. We show that the dynamics is not due to a continuous ballistic process, as proposed in previous works, but rather to rare, intermittent rearrangements. We quantify the dynamical fluctuations resulting from intermittency by means of the variance $\chi(\tau,q)$ of the instantaneous autocorrelation function, the analogous of the dynamical susceptibility $\chi\_4$ studied in glass formers. The amplitude of $\chi$ is found to grow linearly with $q$. We propose a simple --yet general-- model of intermittent dynamics that accounts for the $q$ dependence of both the average correlation functions and $\chi$.Comment: Revised and improved, to appear in Europhys. Let

Mobility Data as a Proxy for Urban Vitality

In this paper, we propose an innovative approach to Jane Jacobs’s concept of diversity and vitality, analysing spatial big data to obtain quantitative measurements of urban qualities frequently employed to evaluate places. We use mobility data collected from public transport to calculate a diversity value for each research unit. Diversity is composed by three dynamic attributes: intensity, variability and consistency, each measuring different temporal variations of mobility flows. Using various datasets as proxy for activity density to validate results, we then use a regression model to establish the relation between diversity and vitality and unveil which are the most lively areas in London