Bose-enhanced chemistry: Amplification of selectivity in the dissociation of molecular Bose-Einstein condensates

We study the photodissociation chemistry of a quantum degenerate gas of bosonic triatomic $ABC$ molecules, assuming two open rearrangement channels ($AB+C$ or $A+BC$). The equations of motion are equivalent to those of a parametric multimode laser, resulting in an exponential buildup of macroscopic mode populations. By exponentially amplifying a small differential in the single-particle rate-coefficients, Bose stimulation leads to a nearly complete selectivity of the collective $N$-body process, indicating a novel type of ultra-selective quantum degenerate chemistry.Comment: 5 pages, 3 figure

Electromagnetic Fields of Slowly Rotating Magnetized Gravastars

We study the dipolar magnetic field configuration and present solutions of Maxwell equations in the internal background spacetime of a a slowly rotating gravastar. The shell of gravastar where magnetic field penetrated is modeled as sphere consisting of perfect highly magnetized fluid with infinite conductivity. Dipolar magnetic field of the gravastar is produced by a circular current loop symmetrically placed at radius $a$ at the equatorial plane.Comment: 5 pages, 2 figures, accepted for publication to Mod. Phys. Lett.

Dark-Energy Dynamics Required to Solve the Cosmic Coincidence

Dynamic dark energy (DDE) models are often designed to solve the cosmic coincidence (why, just now, is the dark energy density $\rho_{de}$, the same order of magnitude as the matter density $\rho_m$?) by guaranteeing $\rho_{de} \sim \rho_m$ for significant fractions of the age of the universe. This typically entails ad-hoc tracking or oscillatory behaviour in the model. However, such behaviour is neither sufficient nor necessary to solve the coincidence problem. What must be shown is that a significant fraction of observers see $\rho_{de} \sim \rho_m$. Precisely when, and for how long, must a DDE model have $\rho_{de} \sim \rho_{m}$ in order to solve the coincidence? We explore the coincidence problem in dynamic dark energy models using the temporal distribution of terrestrial-planet-bound observers. We find that any dark energy model fitting current observational constraints on $\rho_{de}$ and the equation of state parameters $w_0$ and $w_a$, does have $\rho_{de} \sim \rho_m$ for a large fraction of observers in the universe. This demotivates DDE models specifically designed to solve the coincidence using long or repeated periods of $\rho_{de} \sim \rho_m$.Comment: 16 pages, 8 figures, Submitted to Phys. Rev.

The Virgo Alignment Puzzle in Propagation of Radiation on Cosmological Scales

We reconsider analysis of data on the cosmic microwave background on the largest angular scales. Temperature multipoles of any order factor naturally into a direct product of axial quantities and cosets. Striking coincidences exist among the axes associated with the dipole, quadrupole, and octupole CMB moments. These axes also coincide well with two other axes independently determined from polarizations at radio and optical frequencies propagating on cosmological scales. The five coincident axes indicate physical correlation and anisotropic properties of the cosmic medium not predicted by the conventional Big Bang scenario. We consider various mechanisms, including foreground corrections, as candidates for the observed correlations. We also consider whether the propagation anomalies may be a signal of ``dark energy'' in the form of a condensed background field. Perhaps {\it light propagation} will prove to be an effective way to look for the effects of {\it dark energy}.Comment: 24 pages, 4 figures, minor changes, no change in result or conclusions. to appear in IJMP

Dark Matter and Dark Radiation

We explore the feasibility and astrophysical consequences of a new long-range U(1) gauge field ("dark electromagnetism") that couples only to dark matter, not to the Standard Model. The dark matter consists of an equal number of positive and negative charges under the new force, but annihilations are suppressed if the dark matter mass is sufficiently high and the dark fine-structure constant $\hat\alpha$ is sufficiently small. The correct relic abundance can be obtained if the dark matter also couples to the conventional weak interactions, and we verify that this is consistent with particle-physics constraints. The primary limit on $\hat\alpha$ comes from the demand that the dark matter be effectively collisionless in galactic dynamics, which implies $\hat\alpha \lesssim 10^{-4}$ for TeV-scale dark matter. These values are easily compatible with constraints from structure formation and primordial nucleosynthesis. We raise the prospect of interesting new plasma effects in dark matter dynamics, which remain to be explored.Comment: 14 pages, 6 figures Updated equations and figure

Synthesis And Characterization Of (pyNO−)2GaCl: A Redox-Active Gallium Complex

We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffraction, and theory. UV–Vis absorption spectroscopy and electrochemistry were used to access the optical and electrochemical properties of the complex, respectively. Our discussion focuses primarily on a comparison of the gallium complex to the corresponding aluminum derivative and shows that although the complexes are very similar, small differences in the electronic structure of the complexes can be correlated to the identity of the metal

Entropy of gravitationally collapsing matter in FRW universe models

We look at a gas of dust and investigate how its entropy evolves with time under a spherically symmetric gravitational collapse. We treat the problem perturbatively and find that the classical thermodynamic entropy does actually increase to first order when one allows for gravitational potential energy to be transferred to thermal energy during the collapse. Thus, in this situation there is no need to resort to the introduction of an intrinsic gravitational entropy in order to satisfy the second law of thermodynamics.Comment: 9 pages, 4 figures. Major changes from previous version. We consider only thermodynamic entropy in this version. Published in PR

Using bacterial biomarkers to identify early indicators of cystic fibrosis pulmonary exacerbation onset

Acute periods of pulmonary exacerbation are the single most important cause of morbidity in cystic fibrosis patients, and may be associated with a loss of lung function. Intervening prior to the onset of a substantially increased inflammatory response may limit the associated damage to the airways. While a number of biomarker assays based on inflammatory markers have been developed, providing useful and important measures of disease during these periods, such factors are typically only elevated once the process of exacerbation has been initiated. Identifying biomarkers that can predict the onset of pulmonary exacerbation at an early stage would provide an opportunity to intervene before the establishment of a substantial immune response, with major implications for the advancement of cystic fibrosis care. The precise triggers of pulmonary exacerbation remain to be determined; however, the majority of models relate to the activity of microbes present in the patient's lower airways of cystic fibrosis. Advances in diagnostic microbiology now allow for the examination of these complex systems at a level likely to identify factors on which biomarker assays can be based. In this article, we discuss key considerations in the design and testing of assays that could predict pulmonary exacerbations

Solutions for real dispersionless Veselov-Novikov hierarchy

We investigate the dispersionless Veselov-Novikov (dVN) equation based on the framework of dispersionless two-component BKP hierarchy. Symmetry constraints for real dVN system are considered. It is shown that under symmetry reductions, the conserved densities are therefore related to the associated Faber polynomials and can be solved recursively. Moreover, the method of hodograph transformation as well as the expressions of Faber polynomials are used to find exact real solutions of the dVN hierarchy.Comment: 14 page