Measuring in-situ X-ray scattering of natural rubber biaxial deformation: A new equipment for polymer studies

This research is supported by national funds through the FCT (Portuguese Foundation for Science and Technology)/MCTES (PIDDAC) under the projects UIDB/04044/2020, UIDP/04044/2020, Associate Laboratory ARISE LA/P/0112/2020 and PAMI—ROTEIRO/0328/2013 (Nº 022158) and UID/Multi/04044/2013.Understanding biaxial deformation is essential for a more realistic evaluation of rubber elasticity compared to the more usual uniaxial deformation. To study crystallisation occurring during biaxial deformation of natural rubber films, a new simple equipment has been designed and assembled. The equipment, mounted in the beamline of ALBA synchrotron light source facility, allowed the in-situ measurement of X-ray scattering of natural rubber during biaxial deformation. This work provides, for the first time, quantitative information on crystallisation during biaxial extension.info:eu-repo/semantics/publishedVersio

Microcellular natural rubber using supercritical CO2 technology

International audienc

Improvement of mechanical and dynamic properties of high silica filled epoxide functionalized natural rubber

In this research, 3 different low degrees (4, 8, and 14 mol%) of epoxide functionalized natural rubber were prepared via chemical modification of natural rubber, which was then vulcanized. Each of them was mixed with silica (50 parts per hundred of rubber) without a silane coupling agent and investigated their properties. It was found that the tensile and tear properties, as well as abrasion resistance of the silica filled epoxide functionalized natural rubber vulcanizates were higher than the silica filled natural rubber vulcanizate. These properties improvements could be attributed to the interaction of the silanol groups of the silica with the epoxide groups of the modified rubber chains via chemical and physical interactions. This could be supported by the occurrence of tear parts from the morphology investigation of the tensile fractured surface of the modified rubber vulcanizates using a scanning electron microscope. The presence of silicon elements in the rubber matrix was evidenced by scanning electron microscopy and energy dispersive X-Ray spectrometer. Moreover, the silica filled epoxide functionalized natural rubber having 14 mol% epoxide content without a silane coupling agent exhibited low abrasion loss, low heat build-up and enhancement in loss tangent at 0 °C, hence improved wet skid resistance, compared to the silica filled natural rubber without a silane coupling agent. This work demonstrated that the prepared low degree of epoxide functionalized natural rubber could be potentially applied to the tire tread rubber application without the use of a silane coupling agent

A new type of natural rubber as a potential replacement for ethylene propylene diene monomer (EPDM) rubber

International audienc

A new type of natural rubber as a potential replacement for ethylene propylene diene monomer (EPDM) rubber

International audienc

A new type of natural rubber as a potential replacement for ethylene propylene diene monomer (EPDM) rubber

International audienc