Observation of photon-assisted tunneling in optical lattices

We have observed tunneling suppression and photon-assisted tunneling of Bose-Einstein condensates in an optical lattice subjected to a constant force plus a sinusoidal shaking. For a sufficiently large constant force, the ground energy levels of the lattice are shifted out of resonance and tunneling is suppressed; when the shaking is switched on, the levels are coupled by low-frequency photons and tunneling resumes. Our results agree well with theoretical predictions and demonstrate the usefulness of optical lattices for studying solid-state phenomena.Comment: 5 pages, 3 figure

Quantum scaling laws in the onset of dynamical delocalization

We study the destruction of dynamical localization, experimentally observed in an atomic realization of the kicked rotor, by a deterministic Hamiltonian perturbation, with a temporal periodicity incommensurate with the principal driving. We show that the destruction is gradual, with well defined scaling laws for the various classical and quantum parameters, in sharp contrast with predictions based on the analogy with Anderson localization.Comment: 3 pages, revtex

Quantum simulation of frustrated magnetism in triangular optical lattices

Magnetism plays a key role in modern technology as essential building block of many devices used in daily life. Rich future prospects connected to spintronics, next generation storage devices or superconductivity make it a highly dynamical field of research. Despite those ongoing efforts, the many-body dynamics of complex magnetism is far from being well understood on a fundamental level. Especially the study of geometrically frustrated configurations is challenging both theoretically and experimentally. Here we present the first realization of a large scale quantum simulator for magnetism including frustration. We use the motional degrees of freedom of atoms to comprehensively simulate a magnetic system in a triangular lattice. Via a specific modulation of the optical lattice, we can tune the couplings in different directions independently, even from ferromagnetic to antiferromagnetic. A major advantage of our approach is that standard Bose-Einstein-condensate temperatures are sufficient to observe magnetic phenomena like N\'eel order and spin frustration. We are able to study a very rich phase diagram and even to observe spontaneous symmetry breaking caused by frustration. In addition, the quantum states realized in our spin simulator are yet unobserved superfluid phases with non-trivial long-range order and staggered circulating plaquette currents, which break time reversal symmetry. These findings open the route towards highly debated phases like spin-liquids and the study of the dynamics of quantum phase transitions.Comment: 5 pages, 4 figure

An unusual occurrence of Nautilus macromphalus in a cenote in the Loyalty Islands (New Caledonia)

Exploration of a landlocked cenote on Lifou (Loyalty Islands) revealed 37 shells of the cephalopod Nautilus macromphalus Sowerby, 1849, in saltwater on the cenote floor, approximately 40 m below the water surface. The occurrence of these shells is unusual because N. macromphalus is restricted to the open marine waters surrounding the island. All of the shells are mature, and nearly all of them are unbroken, with faded red-brown color stripes. We analyzed seven shells to determine their age. Radiocarbon dating yielded ages of 6380¡30 to 7095¡30 y BP. The 238U-series radionuclides 210Pb (half-life 522.3 y) and 226Ra (half-life 51600 y) also were measured. Two of the samples showed radioactive equilibrium between the nuclides, consistent with the old radiocarbon dates, but the other five samples showed excess 210Pb. When corrected for radioactive decay, the 226Ra activities were much greater than those found in living Nautilus. We conclude that exposure to high activities of 222Rn and 226Ra in the salty groundwater of the cenote altered the activities originally incorporated into the shells. Human placement of the shells in the cavity is rejected based on their radiocarbon age and the geometry of the cenote. The most probable explanation is that the animals entered the flooded karstic system through a connection on the seaward side at approximately 7,000 y BP, during an interval of slowly rising sea level. Unable to find an exit and/or due to anoxic bottom waters, the animals were trapped and died inside. The open connection with the sea persisted for ,700 y, but after ,6400 y BP, the connection was lost, probably due to a roof collapse. This is a rare example of Nautilus in a karstic coastal basin and provides a minimum age for the appearance of N. macromphalus in the Loyalty Islands

AC-induced superfluidity

We argue that a system of ultracold bosonic atoms in a tilted optical lattice can become superfluid in response to resonant AC forcing. Among others, this allows one to prepare a Bose-Einstein condensate in a state associated with a negative effective mass. Our reasoning is backed by both exact numerical simulations for systems consisting of few particles, and by a theoretical approach based on Floquet-Fock states.Comment: Accepted for publication in Europhysics letters, 6 pages, 4 figures, Changes in v2: reference 7 replaced by a more recent on

Wave Function Renormalization Effects in Resonantly Enhanced Tunneling

We study the time evolution of ultra-cold atoms in an accelerated optical lattice. For a Bose- Einstein condensate with a narrow quasi-momentum distribution in a shallow optical lattice the decay of the survival probability in the ground band has a step-like structure. In this regime we establish a connection between the wave function renormalization parameter Z introduced in [Phys. Rev. Lett. 86, 2699 (2001)] to characterize non-exponential decay and the phenomenon of resonantly enhanced tunneling, where the decay rate is peaked for particular values of the lattice depth and the accelerating force.Comment: 12 page

Preparation and Instability of Nanocrystalline Cuprous Nitride

Low-dimensional cuprous nitride (Cu3N) was synthesized by nitridation (ammonolysis) of cuprous oxide (Cu2O) nanocrystals using either ammonia (NH3) or urea (H2NCONH2) as the nitrogen source. The resulting nanocrystalline Cu3N spontaneously decomposes to nanocrystalline CuO in the presence of both water and oxygen from air at room temperature. Ammonia was produced in 60% chemical yield during Cu3N decomposition, as measured using the colorimetric indophenol method. Because Cu3N decomposition requires H2O and produces substoichiometric amounts of NH3\u3e, we conclude that this reaction proceeds through a complex stoichiometry that involves the concomitant release of both N2 and NH3. This is a thermodynamically unfavorable outcome, strongly indicating that H2O (and thus NH3 production) facilitate the kinetics of the reaction by lowering the energy barrier for Cu3N decomposition. The three different Cu2O, Cu3N, and CuO nanocrystalline phases were characterized by a combination of optical absorption, powder X-ray diffraction, transmission electron microscopy, and electronic density of states obtained from electronic structure calculations on the bulk solids. The relative ease of interconversion between these interesting and inexpensive materials bears possible implications for catalytic and optoelectronic applications

Synthesis of Well-Defined, Surfactant-Free Co₃O₄ Nanoparticles:The Impact of Size and Manganese Promotion on Co₃O₄ Reduction and Water Oxidation Activity

Abstract: A surfactant-free synthetic route has been developed to produce size-controlled, cube-like cobalt oxide nanoparticles of three different sizes in high yields. It was found that by using sodium nitrite as salt-mediating agent, near-quantitative yields could be obtained. The size of the nanoparticles could be altered from 11 to 22 nm by changing the cobalt concentration and reaction time. These surfactant-free nanoparticles form ideal substrates for facile deposition of further elements such as manganese. The effect of size of the cobalt oxide nanoparticles and the presence of manganese on the reducibility of cobalt oxide to metallic cobalt was investigated. Similarly, the effect of these parameters was investigated with a visible light promoted water oxidation system with cobalt oxide as catalyst, together with [Ru(bpy) 3] 2+ light harvester dye and an electron acceptor. Graphical Abstract: A novel surfactant-free synthetic route has been developed to produce size-controlled, cube shaped cobalt oxide nanoparticles in high yields. [Figure not available: see fulltext.]. </p