55,507 research outputs found

    Eden

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    'Young adult offender volunteer mentoring': project evaluation

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    Working girls: abuse or choice in street-level sex work? A study of homeless women in Nottingham

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    This paper aims to explore how abused homeless women understand their choice to sex work. In particular, there is a discussion of the motivations given by women as to why they sex worked, and it is suggested that abused homeless women can experience coercion from abusive partners in deciding to sex work. There is a challenge to the notion of 'victim' within the government's 'Prostitution Strategy' (Home Office, 2006) in specifying responses to the complex needs of sex working women. Recommendations are also made for practice in the context of the 'Strategy' when working with abused and coerced homeless women who choose to sex work. Twenty-six homeless women were interviewed - nine of whom had sex worked - and a structured, qualitative questionnaire was used in a case study design from which information was gathered about the relationship between a woman's experience of abuse and her decision to sex work

    On the origin of the Trojan asteroids: Effects of Jupiter's mass accretion and radial migration

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    We present analytic and numerical results which illustrate the effects of Jupiter's accretion of nebular gas and the planet's radial migration on its Trojan companions. Initially, we approximate the system by the planar circular restricted three-body problem and assume small Trojan libration amplitudes. Employing an adiabatic invariant calculation, we show that Jupiter's thirty-fold growth from a 10M10 M_\oplus core to its present mass causes the libration amplitudes of Trojan asteroids to shrink by a factor of about 2.5 to 40\sim 40% of their original size. The calculation also shows that Jupiter's radial migration has comparatively little effect on the Trojans; inward migration from 6.2 to 5.2 AU causes an increase in Trojan libration amplitudes of 4\sim4%. In each case, the area enclosed by small tadpole orbits, if made dimensionless by using Jupiter's semimajor axis, is approximately conserved. Similar adiabatic invariant calculations for inclined and eccentric Trojans show that Jupiter's mass growth leaves the asteroid's eccentricities and inclinations essentially unchanged, while one AU of inward migration causes an increase in both of these quantities by 4\sim 4%. Numerical integrations confirm and extend these analytic results. We demonstrate that our predictions remain valid for Trojans with small libration amplitudes even when the asteroids have low, butComment: Submitted to Icarus - 13 Fig

    Spot sampling of nutrient concentrations in the Puarenga catchment, Rotorua

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    The Centre for Biodiversity and Ecology Research was approached by Tūhourangi Tribal Authority for assistance with measuring water quality in streams in the Puarenga Stream catchment. Water sampling was subsequently undertaken on 18 July 2011 and samples were analysed to determine concentrations of total and dissolved fractions of nitrogen and phosphorus. Nitrogen and phosphorus are both essential plant nutrients which, when present in excess, can cause eutrophication and associated water quality decline of freshwaters. High concentrations of dissolved forms of nitrogen can also be toxic to aquatic organisms. Excessive nitrogen and phosphorus concentrations are typically the result of pollution due to human activities, although groundwater in the Central Volcanic Plateau region can have elevated concentrations of phosphorus arising from natural geological sources. This report summarises the methods used, presents the results and places measured concentrations in context by drawing comparisons with both guideline and regional mean values

    Mechanisms for the Oxonolysis of Ethene and Propene: Reliability of Quantum Chemical Predictions

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    Reactions of ozone with ethene and propene leading to primary ozonide (concerted and stepwise ozonolysis) or epoxide and singlet molecular oxygen (partial ozonolysis) are studied theoretically. The mechanism of concerted ozonolysis proceeds via a single transition structure which is a partial diradical. The transition structures and intermediates in the stepwise ozonolysis and partial ozonolysis mechanisms are singlet diradicals. Spin-restricted and unrestricted density functional methods are employed to calculate the structures of the closed-shell and diradical species. Although the partial diradicals exhibit moderate to pronounced instability in their RDFT and RHF solutions, RDFT is required to locate the transition structure for concerted ozonolysis. Spin projected fourth-order Møller–Plesset theory (PMP4) was used to correct the DFT energies. The calculated pre-exponential factors and activation energies for the concerted ozonolysis of ethene and propene are in good agreement with experimental values. However, the PMP4//DFT procedure incorrectly predicts the stepwise mechanism as the favored channel. UCCSD(T) predicts the concerted mechanism as the favored channel but significantly overestimates the activation energies. RCCSD(T) is found to be more accurate than UCCSD(T) for the calculation of the concerted mechanism but is not applicable to the diradical intermediates. The major difficulty in accurate prediction of the rate constant data for these reactions is the wide range of spin contamination for the reference UHF wave functions and UDFT solutions across the potential energy surface. The possibility of the partial ozonolysis mechanism being the source of epoxide observed in some experiments is discussed

    Presence and Absence

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    The river model of black holes

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    This paper presents an under-appreciated way to conceptualize stationary black holes, which we call the river model. The river model is mathematically sound, yet simple enough that the basic picture can be understood by non-experts. %that can by understood by non-experts. In the river model, space itself flows like a river through a flat background, while objects move through the river according to the rules of special relativity. In a spherical black hole, the river of space falls into the black hole at the Newtonian escape velocity, hitting the speed of light at the horizon. Inside the horizon, the river flows inward faster than light, carrying everything with it. We show that the river model works also for rotating (Kerr-Newman) black holes, though with a surprising twist. As in the spherical case, the river of space can be regarded as moving through a flat background. However, the river does not spiral inward, as one might have anticipated, but rather falls inward with no azimuthal swirl at all. Instead, the river has at each point not only a velocity but also a rotation, or twist. That is, the river has a Lorentz structure, characterized by six numbers (velocity and rotation), not just three (velocity). As an object moves through the river, it changes its velocity and rotation in response to tidal changes in the velocity and twist of the river along its path. An explicit expression is given for the river field, a six-component bivector field that encodes the velocity and twist of the river at each point, and that encapsulates all the properties of a stationary rotating black hole.Comment: 16 pages, 4 figures. The introduction now refers to the paper of Unruh (1981) and the extensive work on analog black holes that it spawned. Thanks to many readers for feedback that called attention to our omissions. Submitted to the American Journal of Physic
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