1,135 research outputs found

    Respiratory distress in a newborn

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    Modeling nitrous acid and its impact on ozone and hydroxyl radical during the Texas Air Quality Study 2006

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    Nitrous acid (HONO) mixing ratios for the Houston metropolitan area were simulated with the Community Multiscale Air Quality (CMAQ) Model for an episode during the Texas Air Quality Study (TexAQS) II in August/September 2006 and compared to in-situ MC/IC (mist-chamber/ion chromatograph) and long path DOAS (Differential Optical Absorption Spectroscopy) measurements at three different altitude ranges. Several HONO sources were accounted for in simulations, such as gas phase formation, direct emissions, nitrogen dioxide (NO<sub>2</sub>) hydrolysis, photo-induced formation from excited NO<sub>2</sub> and photo-induced conversion of NO<sub>2</sub> into HONO on surfaces covered with organic materials. Compared to the gas-phase HONO formation there was about a tenfold increase in HONO mixing ratios when additional HONO sources were taken into account, which improved the correlation between modeled and measured values. Concentrations of HONO simulated with only gas phase chemistry did not change with altitude, while measured HONO concentrations decrease with height. A trend of decreasing HONO concentration with altitude was well captured with CMAQ predicted concentrations when heterogeneous chemistry and photolytic sources of HONO were taken into account. Heterogeneous HONO production mainly accelerated morning ozone formation, albeit slightly. Also HONO formation from excited NO<sub>2</sub> only slightly affected HONO and ozone (O<sub>3</sub>) concentrations. Photo-induced conversion of NO<sub>2</sub> into HONO on surfaces covered with organic materials turned out to be a strong source of daytime HONO. Since HONO immediately photo-dissociates during daytime its ambient mixing ratios were only marginally altered (up to 0.5 ppbv), but significant increase in the hydroxyl radical (OH) and ozone concentration was obtained. In contrast to heterogeneous HONO formation that mainly accelerated morning ozone formation, inclusion of photo-induced surface chemistry influenced ozone throughout the day

    PREPARATION AND CHARACTERIZATION OF LOW RESISTIVITY CuS FILMS USING SPRAY PYROLYSIS

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    CuS films were prepared by spray pyrolysis from solutions of (NH 2 ) 2 CS and CuCl 2 .2H 2 O mixed at ratios of 3:1, 4:1 and 5:1 on glass substrates heated at 160 to 240 o C. The deposition temperatures and pulsed regime of spray were controlled with the help of electronic equipments. The resistivity, phase composition, morphology, band gap energy and type of conductivity of the films were characterized using volt-ampere, XRD, SEM, optical absorption and Hall effect measurements. It was found that for all ratios of precursors the low resistivity of the films was stably obtained at substrate temperatures from 170 to 220 o C. Among them the lowest sheet resistivity of the films reached value of 8 ohm/sqr. The influences of deposition temperature and material ratio on characteristics of the spray deposited CuS films were discussed

    Measurement of Cosmic-ray Muons and Muon-induced Neutrons in the Aberdeen Tunnel Underground Laboratory

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    We have measured the muon flux and production rate of muon-induced neutrons at a depth of 611 m water equivalent. Our apparatus comprises three layers of crossed plastic scintillator hodoscopes for tracking the incident cosmic-ray muons and 760 L of gadolinium-doped liquid scintillator for producing and detecting neutrons. The vertical muon intensity was measured to be Iμ=(5.7±0.6)×10−6I_{\mu} = (5.7 \pm 0.6) \times 10^{-6} cm−2^{-2}s−1^{-1}sr−1^{-1}. The yield of muon-induced neutrons in the liquid scintillator was determined to be Yn=(1.19±0.08(stat)±0.21(syst))×10−4Y_{n} = (1.19 \pm 0.08 (stat) \pm 0.21 (syst)) \times 10^{-4} neutrons/(μ⋅\mu\cdotg⋅\cdotcm−2^{-2}). A fit to the recently measured neutron yields at different depths gave a mean muon energy dependence of ⟨Eμ⟩0.76±0.03\left\langle E_{\mu} \right\rangle^{0.76 \pm 0.03} for liquid-scintillator targets.Comment: 14 pages, 17 figures, 3 table
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