Organosolv pretreatment of Sitka spruce wood: conversion of hemicelluloses to ethyl glycosides

A range of organosolv pretreatments, using ethanol:water mixtures with dilute sulphuric acid, were applied to Sitka spruce sawdust with the aim of generating useful co-products as well as improving saccharification yield. The most efficient of the pretreatment conditions, resulting in subsequent saccharification yields of up to 86%, converted a large part of the hemicellulose sugars to their ethyl glycosides as identified by GC/MS. These conditions also reduced conversion of pentoses to furfural, the ethyl glycosides being more stable to dehydration than the parent pentoses. Through comparison with the behaviour of model compounds under the same reaction conditions it was shown that the anomeric composition of the products was consistent with a predominant transglycosylation reaction mechanism, rather than hydrolysis followed by glycosylation. The ethyl glycosides have potential as intermediates in the sustainable production of high-value chemicals

Isolation of high quality lignin as a by-product from ammonia percolation pretreatment of poplar wood

A two-step process combining percolation-mode ammonia pretreatment of poplar sawdust with mild organosolv purification of the extracted lignin produced high quality, high purity lignin in up to 31% yield and 50% recovery. The uncondensed fraction of the isolated lignin was up to 34%, close to that the native lignin (40%). Less lignin was recovered after pretreatment in batch mode, apparently due to condensation during the longer residence time of the solubilised lignin at elevated temperature. The lignin recovery was directly correlated with its molecular weight and its nitrogen content. Low nitrogen incorporation, observed at high ammonia concentration, may be explained by limited homolytic cleavage of -O-4 bonds. Ammonia concentrations from 15% to 25% (w/w) gave similar results in terms of lignin structure, yield and recovery

Dark matter voids in the SDSS galaxy survey

What do we know about voids in the dark matter distribution given the Sloan Digital Sky Survey (SDSS) and assuming the $\Lambda\mathrm{CDM}$ model? Recent application of the Bayesian inference algorithm BORG to the SDSS Data Release 7 main galaxy sample has generated detailed Eulerian and Lagrangian representations of the large-scale structure as well as the possibility to accurately quantify corresponding uncertainties. Building upon these results, we present constrained catalogs of voids in the Sloan volume, aiming at a physical representation of dark matter underdensities and at the alleviation of the problems due to sparsity and biasing on galaxy void catalogs. To do so, we generate data-constrained reconstructions of the presently observed large-scale structure using a fully non-linear gravitational model. We then find and analyze void candidates using the VIDE toolkit. Our methodology therefore predicts the properties of voids based on fusing prior information from simulations and data constraints. For usual void statistics (number function, ellipticity distribution and radial density profile), all the results obtained are in agreement with dark matter simulations. Our dark matter void candidates probe a deeper void hierarchy than voids directly based on the observed galaxies alone. The use of our catalogs therefore opens the way to high-precision void cosmology at the level of the dark matter field. We will make the void catalogs used in this work available at http://www.cosmicvoids.net.Comment: 15 pages, 6 figures, matches JCAP published version, void catalogs publicly available at http://www.cosmicvoids.ne

Temperature and Disorder Chaos in Three-Dimensional Ising Spin Glasses

We study the effects of small temperature as well as disorder perturbations on the equilibrium state of three-dimensional Ising spin glasses via an alternate scaling ansatz. By using Monte Carlo simulations, we show that temperature and disorder perturbations yield chaotic changes in the equilibrium state and that temperature chaos is considerably harder to observe than disorder chaos.Comment: 4 pages, 3 figures, 1 tabl

Gravitating superconducting strings with timelike or spacelike currents

We construct gravitating superconducting string solutions of the U(1)_{local} x U(1)_{global} model solving the coupled system of Einstein and matter field equations numerically. We study the properties of these solutions in dependence on the ratio between the symmetry breaking scale and the Planck mass. Using the macroscopic stability conditions formulated by Carter, we observe that the coupling to gravity allows for a new stable region that is not present in the flat space-time limit. We match the asymptotic metric to the Kasner metric and show that the relations between the Kasner coefficients and the energy per unit length and tension suggested previously are well fulfilled for symmetry breaking scale much smaller than the Planck mass. We also study the solutions to the geodesic equation in this space-time. While geodesics in the exterior space-time of standard cosmic strings are just straight lines, test particles experience a force in a general Kasner space-time and as such bound orbits are possible.Comment: 16 pages including 14 figure

Abstract embeddability ranks

We describe several ordinal indices that are capable of detecting, according to various metric notions of faithfulness, the embeddability between pairs of Polish spaces. These embeddability ranks are of theoretical interest but seem difficult to estimate in practice. Embeddability ranks, which are easier to estimate in practice, are embeddability ranks generated by Schauder bases. These embeddability are inspired by the nonlinear indices \`a la Bourgain from \cite{BLMS_FM}. In particular, we resolve a problem \cite[Problem 3.10]{BLMS_FM} regarding the necessity of additional set-theoretic axioms regarding the main coarse universality result of \cite{BLMS_FM}.Comment: 10 page