Assessmanet of exposure and risk associated with trihalomethanes and other volatile organic compounds in drinking water

Thesis (Master)--Izmir Institute of Technology, Environmental Engineering, Izmir, 2005Includes bibliographical references (leaves: 64-70)Text in English; Abstract: Turkish and Englishx, 81 leavesConcentrations of 54 volatile organic compounds (VOCs) were measured in İzmir drinking water, and associated health risks due to ingestion of these compounds were investigated using a semi-probabilistic sampling design. 100 houses were visited in different districts of İzmir and drinking water samples were collected from consumer taps and bottled waters. Using questionnaires, demographics and drinking water consumption rates were determined. Individual and population based exposures and risks were estimated by employing deterministic and probabilistic approaches, respectively.Trihalomethanes (THMs) (i.e., chloroform, bromodichloromethane, dibromochloromethane, and bromoform), benzene, toluene, p-xylene, and naphthalene were the most frequently detected VOCs in İzmir drinking water with concentrations ranging from below detection limit to 35 .g/l. None of the samples exceeded the maximum contaminant levels stated in the Turkish, European, and American drinking water regulations. For all VOCs, the concentrations measured in metropolitan area were greater than those in other districts. All THM species were detected in higher concentrations in tap water.Noncarcinogenic risks attributable to ingestion of VOCs in İzmir drinking water were negligible whereas the mean carcinogenic risk estimates for bromodichloromethane and dibromochloromethane were above the acceptable level of one in a million (10-6). Deterministic approach revealed that 23%, 29%, and 2% of individuals had lifetime cancer risks greater than 10-6 associated with ingestion of bromodichloromethane, dibromochloromethane, and bromoform, respectively. The results of this study show that exposures to drinking water contaminants and associated risks may be higher than the acceptable level even if the concentrations fall below the drinking water standards

Olive tree, Olea europaea L., leaves as a bioindicator of atmospheric PCB contamination

Olive tree leaf samples were collected to investigate their possible use for biomonitoring of lipophilic toxic substances. The samples were analyzed for 28 polychlorinated biphenyls (PCB) congeners. Twelve congeners were detected in the samples. PCB-60, 77, 81, 89, 105, 114, and 153 were the most frequently detected congeners ranging from 32 % for PCB-52 to 97 % for PCB-81. Σ12PCBs concentration varied from below detection limit to 248 ng/g wet weight in the sampling area, while the mean congener concentrations ranged from 0.06 ng/g (PCB-128 + 167) to 64.2 ng/g wet weight (PCB-60). Constructed concentration maps showed that olive tree leaves can be employed for the estimation of spatial distrubution of these congener

Assessmanet of exposure and risk associated with trihalomethanes and other volatile organic compounds in drinking water

Thesis (Master)--Izmir Institute of Technology, Environmental Engineering, Izmir, 2005Includes bibliographical references (leaves: 64-70)Text in English; Abstract: Turkish and Englishx, 81 leavesConcentrations of 54 volatile organic compounds (VOCs) were measured in İzmir drinking water, and associated health risks due to ingestion of these compounds were investigated using a semi-probabilistic sampling design. 100 houses were visited in different districts of İzmir and drinking water samples were collected from consumer taps and bottled waters. Using questionnaires, demographics and drinking water consumption rates were determined. Individual and population based exposures and risks were estimated by employing deterministic and probabilistic approaches, respectively.Trihalomethanes (THMs) (i.e., chloroform, bromodichloromethane, dibromochloromethane, and bromoform), benzene, toluene, p-xylene, and naphthalene were the most frequently detected VOCs in İzmir drinking water with concentrations ranging from below detection limit to 35 .g/l. None of the samples exceeded the maximum contaminant levels stated in the Turkish, European, and American drinking water regulations. For all VOCs, the concentrations measured in metropolitan area were greater than those in other districts. All THM species were detected in higher concentrations in tap water.Noncarcinogenic risks attributable to ingestion of VOCs in İzmir drinking water were negligible whereas the mean carcinogenic risk estimates for bromodichloromethane and dibromochloromethane were above the acceptable level of one in a million (10-6). Deterministic approach revealed that 23%, 29%, and 2% of individuals had lifetime cancer risks greater than 10-6 associated with ingestion of bromodichloromethane, dibromochloromethane, and bromoform, respectively. The results of this study show that exposures to drinking water contaminants and associated risks may be higher than the acceptable level even if the concentrations fall below the drinking water standards

An exposure and risk assessment for fluoride and trace metals in black tea

Exposure and associated health risks for fluoride and trace metals in black tea were estimated. Fifty participants were randomly recruited to supply samples from the tea that they drink, and self-administer a questionnaire that inquired about personal characteristics and daily tea intake. Analyzed trace metals included aluminum, arsenic, barium, cadmium, cobalt, chromium, copper, manganese, nickel, strontium, and zinc. Fluoride and four metals (Al, Cr, Mn, Ni) were detected in all samples while barium was detected only in one sample. The remaining metals were detected in >60% of the samples. Fluoride and aluminum levels in instant tea bag samples were greater than in loose tea samples (p 1.0 × 10-6 even at the median level. According to sensitivity analysis, daily tea intake was the most influencing variable to the risk except for arsenic for which the concentration distribution was of more importance

A health risk assessment for exposure to trace metals via drinking water ingestion pathway

A health risk assessment was conducted for exposure to trace metals via drinking water ingestion pathway for Province of İzmir, Turkey. Concentrations of 11 trace metals were measured in drinking waters collected from 100 population weighted random sampling units (houses). The samples were analyzed in atomic absorption spectrometry for arsenic, and inductively coupled plasma-optical emission spectrometry for Be, Cd, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn. Questionnaires were administered to a participant from each sampling unit to determine drinking water consumption related information and demographics. Exposure and risks were estimated for each individual by direct calculation, and for İzmir population by Monte Carlo simulation. Six trace metals (As, Cr, Cu, Mn, Ni, and Zn) were detected in >50% of the samples. Concentrations of As and Ni exceeded the corresponding standards in 20% and 58% of the samples, respectively. As a result, arsenic noncarcinogenic risks were higher than the level of concern for 19% of the population, whereas carcinogenic risks were >10-4 for 46%, and >10-6 for 90% of the population

Polycyclic and nitro musks in indoor air: A primary school classroom and a women's sport center

Indoor air gas and particulate-phase samples (PM2.5) were collected from a primary school classroom and a women's sport center because children are one of the sensitive population subgroups and women are frequent users of personal care products in addition to the high level of activity in this specific microenvironment. PM2.5 was collected with a Harvard impactor, and polyurethane foam was used for the gas phase. Samples were ultrasonically extracted, concentrated, and analyzed with a GC-MS. The mean gas-phase concentrations in the classroom ranged from 0.12 ± 0.2 ng/m3 for MK to 267 ± 56 ng/m3 for HHCB, while it was from 0.08 ± 0.10 ng/m3 for AHMI to 144 ± 61 ng/m3 for HHCB in the sports center. Particulate-phase average concentrations in the sports center ranged from 0.22 ± 0.11 ng/m3 for ATII to 1.34 ± 071 ng/m3 for AHTN, while it ranged from 0.05 ± 0.02 ng/m3 (musk xylene) to 2.50 ± 0.94 ng/m3 (HHCB) in the classroom. Exposure-risk assessment showed that inhalation route is most probably far less significant than the dermal route; however, it should be noted that the exposure duration covered in this study was not the larger fraction of the da

Occurrence, oral exposure and risk assessment of volatile organic compounds in drinking water for İzmir

Concentrations of volatile organic compounds (VOCs) were measured in the drinking water in Province of İzmir, Turkey, and associated health risks due to ingestion of these compounds were investigated using population weighted random samples. A total of 100 houses were visited in different districts of İzmir and drinking water samples were collected from consumers' drinking water source. Questionnaires were administered to one participant in each house to determine demographics and drinking water consumption rates. Oral exposure and risks were estimated for each participant and İzmir population by deterministic and probabilistic approaches, respectively. The four trihalomethane (THM) species (i.e., chloroform, bromodichloromethane, dibromochloromethane, and bromoform), benzene, toluene, p-xylene, and naphthalene were the most frequently detected VOCs with concentrations ranging from below detection limit to 35 μg/l. The risk estimates were found to be less than the values reported in the literature with few exceptions. Noncarcinogenic risks attributable to ingestion of VOCs for İzmir population were negligible, whereas the mean carcinogenic risk estimates for bromodichloromethane and dibromochloromethane were above the de minimis level of one in a million (10-6). For all VOCs, the concentrations measured in metropolitan area were greater than those in other districts. All THM species were detected in higher concentrations in tap water, whereas nontap water contained more benzene, toluene, p-xylene, and naphthalene. Therefore, the concentrations of the latter four compounds and associated risks increased with increasing income and education level since bottled water was used in larger proportions within these subgroups. The results of this study showed that oral exposure to drinking water contaminants and associated risks may be higher than the acceptable levels even if the concentrations fall below the standards.TÜBİTA

Speciated arsenic concentrations, exposure, and associated health risks for rice and bulgur

Arsenic species were determined in rice and bulgur samples that were collected from 50 participants who also supplied exposure related information through a questionnaire survey. Speciation analysis was conducted using an HPLC-ICP-MS system. Ingestion exposure to arsenic and associated health risks were assessed by combining the concentration and questionnaire data both for individual participants and the subject population. Inorganic arsenic dominated both in rice and bulgur but concentrations were about an order of magnitude higher in rice (160. ±. 38. ng/g) than in bulgur. Because participants also consumed more rice than bulgur, exposures were significantly higher for rice resulting in carcinogenic risks above acceptable level for 53% and 93% of the participants when the in-effect and the proposed potencies were used, respectively, compared to 0% and 5% for bulgur. An inorganic arsenic standard for rice would be useful to lower the risks while public awareness about the relation between excessive rice consumption and health risks is built, and bulgur consumption is promoted

The use of olive tree (Olea europaea L.) leaves as a bioindicator for environmental pollution in the Province of Aydın, Turkey

Introduction: In this study, olive tree leaves, collected from 50 sampling sites throughout the Province of Aydi{dotless}n, Turkey, were used to estimate level of pollution by measuring Al, As, B, Ba, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, and Zn concentrations and calculating pollution factor (PF) values. Materials and methods: After sample preparation, collected leaves were microwave digested, and extracts were analyzed by an inductively coupled plasma-mass spectrometer. Results and discussion: The maximum PF values were ≥10 for a number of elements ranging from 11-13 (Al, As, Cr, Fe, Mn, Ni) to >100 for Cu, Li, and Na. Urban-rural and roadside-nonroadside concentration comparisons showed that some of the elements (As, Cu, and Pb) were at significantly higher levels on urban and/or roadside sampling sites. Summary and conclusion: Correlations and factor analysis showed that there may be common sources for some elements, which included several soil types and anthropogenic activities. Based on the results of the statistical source apportionment, possible sources were narrowed down with help of the constructed elemental concentration maps. In conclusion, utilization of olive tree leaves for biomonitoring and assessment of environmental pollution was shown to be possible in the Mediterranean region where they are indigenous and cultivated