From nanoscopic to macroscopic photo-driven motion in azobenzene-containing materials

AbstractThe illumination of azobenzene molecules with UV/visible light efficiently converts the molecules between trans and cis isomerization states. Isomerization is accompanied by a large photo-induced molecular motion, which is able to significantly affect the physical and chemical properties of the materials in which they are incorporated. In some material systems, the nanoscopic structural movement of the isomerizing azobenzene molecules can be even propagated at macroscopic spatial scales. Reversible large-scale superficial photo-patterning and mechanical photo-actuation are efficiently achieved in azobenzene-containing glassy materials and liquid crystalline elastomers, respectively. This review covers several aspects related to the phenomenology and the applications of the light-driven macroscopic effects observed in these two classes of azomaterials, highlighting many of the possibilities they offer in different fields of science, like photonics, biology, surface engineering and robotics

Polariton Nanophotonics using Phase Change Materials

Polaritons formed by the coupling of light and material excitations such as plasmons, phonons, or excitons enable light-matter interactions at the nanoscale beyond what is currently possible with conventional optics. Recently, significant interest has been attracted by polaritons in van der Waals materials, which could lead to applications in sensing, integrated photonic circuits and detectors. However, novel techniques are required to control the propagation of polaritons at the nanoscale and to implement the first practical devices. Here we report the experimental realization of polariton refractive and meta-optics in the mid-infrared by exploiting the properties of low-loss phonon polaritons in isotopically pure hexagonal boron nitride (hBN), which allow it to interact with the surrounding dielectric environment comprising the low-loss phase change material, Ge$_3$Sb$_2$Te$_6$ (GST). We demonstrate waveguides which confine polaritons in a 1D geometry, and refractive optical elements such as lenses and prisms for phonon polaritons in hBN, which we characterize using scanning near field optical microscopy. Furthermore, we demonstrate metalenses, which allow for polariton wavefront engineering and sub-wavelength focusing. Our method, due to its sub-diffraction and planar nature, will enable the realization of programmable miniaturized integrated optoelectronic devices, and will lay the foundation for on-demand biosensors.Comment: 15 pages, 4 figures, typos corrected in v

Wavelength-Dependent Shaping of Azopolymer Micropillars for Three-Dimensional Structure Control

: Surfaces endowed with three-dimensional (3D) mesostructures, showing features in the nanometer to micrometer range, are critical for applications in several fields of science and technology. Finding a fabrication method that is simultaneously inexpensive, simple, fast, versatile, highly scalable, and capable of producing complex 3D shapes is still a challenge. Herein, we characterize the photoreconfiguration of a micropillar array of an azobenzene-containing polymer at different light wavelengths and demonstrate the tailoring of the surface geometry and its related functionality only using light. By changing the irradiated light wavelength and its polarization, we demonstrate the fabrication of various complex isotropic and anisotropic 3D mesostructures from a single original pristine geometry. Quantitative morphological analyses revealed an interplay between the decay rate of absorbed light intensity, micropillar volume preservation, and the cohesive forces between the azopolymer chains as the origin of distinctive wavelength-dependent 3D structural remorphing. Finally, we show the potentialities of this method in surface engineering by photoreshaping a single original micropillar surface into two sets of different mesostructured surfaces exhibiting tunable hydrophobicity in a wide water contact angle range. Our study opens up a new paradigm for fabricating functional 3D mesostructures in a simple, low-cost, fast, and scalable manner

Shapeshifting Diffractive Optical Devices

In optical devices like diffraction gratings and Fresnel lenses, light wavefront is engineered through the structuring of device surface morphology, within thicknesses comparable to the light wavelength. Fabrication of such diffractive optical elements involves highly accurate multistep lithographic processes that in fact set into stone both the surface morphology and optical functionality, resulting in intrinsically static devices. In this work, this fundamental limitation is overcome by introducing shapeshifting diffractive optical elements directly written on an erasable photoresponsive material, whose morphology can be changed in real time to provide different on-demand optical functionalities. First a lithographic configuration that allows writing/erasing cycles of aligned optical elements directly in the light path is developed. Then, the realization of complex diffractive gratings with arbitrary combinations of grating vectors is shown. Finally, a shapeshifting diffractive lens that is reconfigured in the light-path in order to change the imaging parameters of an optical system is demonstrated. The approach leapfrogs the state-of-the-art realization of optical Fourier surfaces by adding on-demand reconfiguration to the potential use in emerging areas in photonics, like transformation and planar optics

Shapeshifting Diffractive Optical Devices

In optical devices like diffraction gratings and Fresnel lenses, light wavefront is engineered through the structuring of device surface morphology, within thicknesses comparable to the light wavelength. Fabrication of such diffractive optical elements involves highly accurate multistep lithographic processes that in fact set into stone both the surface morphology and optical functionality, resulting in intrinsically static devices. In this work, this fundamental limitation is overcome by introducing shapeshifting diffractive optical elements directly written on an erasable photoresponsive material, whose morphology can be changed in real time to provide different on-demand optical functionalities. First a lithographic configuration that allows writing/erasing cycles of aligned optical elements directly in the light path is developed. Then, the realization of complex diffractive gratings with arbitrary combinations of grating vectors is shown. Finally, a shapeshifting diffractive lens that is reconfigured in the light-path in order to change the imaging parameters of an optical system is demonstrated. The approach leapfrogs the state-of-the-art realization of optical Fourier surfaces by adding on-demand reconfiguration to the potential use in emerging areas in photonics, like transformation and planar optics

Laser surface texturing of copper and variation of the wetting response with the laser pulse fluence

We report an experimental investigation on laser surface texturing of copper targets by Ti:Sa femtosecond laser pulses addressing their wetting response to water droplets. In particular, fs laser surface processing is used to developed hierarchical surface structures by writing parallel micro-trenches with a period of 50 μm at different laser pulse fluences. The laser irradiation simultaneously induces both the formation of laser induced periodic surface structures (LIPSS), in form of periodic ripples, and the random decoration with nanoparticles, resulting in the formation of a multiscale surface morphology. The morphological features of the samples are investigated and correlated with their wetting response through static contact angle measurements. Our findings evidence a progressive increase of the contact angle with the laser pulse fluence. The combination of the microscale trenches, written by laser line scanning, with the ripples patterns and the random nanoparticles decoration, formed on the surface, allow developing highly hydrophobic copper samples with contact angles reaching values around 160°, presenting potential interest for wettability applications

Laser-induced periodic surface structuring for secondary electron yield reduction of copper: dependence on ambient gas and wavelength

One of the main limitations for future high-performance accelerators operating with positively charged particles is the formation of an electron-cloud inside the beam vacuum chamber, giving rise to instabilities. The Secondary Electron Yield (SEY) of the beam-facing surfaces gives a measure of the mechanism which drives this phenomenon. The laser-induced periodic structure formation on Cu surfaces has been demonstrated as a promising process to reduce SEY. In view of applications in beam chambers, we studied the laser process influence on SEY for 515 and 1030 nm wavelength femtosecond pulses on copper in different ambiences (air, nitrogen, vacuum). Depending on used process conditions, the surface composition differs, structures with varying aspect ratio are formed, i.e., periodic ripples and large-scale channels. Treatment in air at 515 nm is the most efficient for the formation of deeper structures allowing SEY maximum reduction first down to 1.6–1.7 and then below unity upon electron irradiation, thereby totally suppressing electron-cloud. Increasing the laser fluence, SEY will further reduce due to surface roughness enhancement via nanoparticle redeposition. This study reveals the fundamental role of LIPSS treatments to enable surface treatment in large-scale accelerator installations, where particle-free components are desired, and paves the way to potential future applications