1,621 research outputs found
Spreading with evaporation and condensation in one-component fluids
We investigate the dynamics of spreading of a small liquid droplet in gas in
a one-component simple fluid, where the temperature is inhomogeneous around
0.9Tc and latent heat is released or generated at the interface upon
evaporation or condensation (with Tc being the critical temperature). In the
scheme of the dynamic van der Waals theory, the hydrodynamic equations
containing the gradient stress are solved in the axisymmetric geometry. We
assume that the substrate has a finite thickness and its temperature obeys the
thermal diffusion equation. A precursor film then spreads ahead of the bulk
droplet itself in the complete wetting condition. Cooling the substrate
enhances condensation of gas onto the advancing film, which mostly takes place
near the film edge and can be the dominant mechanism of the film growth in a
late stage. The generated latent heat produces a temperature peak or a hot spot
in the gas region near the film edge. On the other hand, heating the substrate
induces evaporation all over the interface. For weak heating, a steady-state
circular thin film can be formed on the substrate. For stronger heating,
evaporation dominates over condensation, leading to eventual disappearance of
the liquid region.Comment: 12 pages, 14 figure
Plastic flow in polycrystal states in a binary mixture
Using molecular dynamics simulation we examine dynamics in sheared
polycrystal states in a binary mixture containing 10% larger particles in two
dimensions. We find large stress fluctuations arising from sliding motions of
the particles at the grain boundaries, which occur cooperatively to release the
elastic energy stored. These dynamic processes are visualized with the aid of a
sixfold angle representing the local crystal orientation and a
disorder variable representing a deviation from the hexagonal order
for particle .Comment: 3 pages, 3 figure
Phase transition in compressible Ising systems at fixed volume
Using a Ginzburg-Landau model, we study the phase transition behavior of
compressible Ising systems at constant volume by varying the temperature
and the applied magnetic field . We show that two phases can coexist
macroscopically in equilibrium within a closed region in the - plane. It
occurence is favored near tricriticality. We find a field-induced critical
point, where the correlation length diverges, the difference of the coexisting
two phases and the surface tension vanish, but the isothermal magnetic
susceptibility does not diverge in the mean field theory. We also investigate
phase ordering numerically.Comment: 13 figure
Dynamics of Binary Mixtures with Ions: Dynamic Structure Factor and Mesophase Formation
Dynamic equations are presented for polar binary mixtures containing ions in
the presence of the preferential solvation. In one-phase states, we calculate
the dynamic structure factor of the composition accounting for the ion motions.
Microphase separation can take place for sufficiently large solvation asymmetry
of the cations and the anions. We show two-dimensional simulation results of
the mesophase formation with an antagonistic salt, where the cations are
hydrophilic and the anions are hydrophobic. The structure factor S(q) in the
resultant mesophase has a sharp peak at an intermediate wave number on the
order of the Debye-Huckel wave number. As the quench depth is increased, the
surface tension nearly vanishes in mesophases due to an electric double layer.Comment: 24 pages, 10 figures, to appear in Journal of Physics: Condensed
Matte
Thermoacoustic effects in supercritical fluids near the critical point: Resonance, piston effect, and acoustic emission and reflection
We present a general theory of thermoacoustic phenomena in supercritical
fluids near the critical point in a one-dimensional cell. We take into account
the effects of the heat conduction in the boundary walls and the bulk viscosity
near the critical point. We introduce a coefficient characterizing
reflection of sound with frequency at the boundary. As applications,
we examine the acoustic eigenmodes in the cell, the response to time-dependent
perturbations, sound emission and reflection at the boundary. Resonance and
rapid adiabatic changes are noteworthy. In these processes, the role of the
thermal diffusion layers is enhanced near the critical point because of the
strong critical divergence of the thermal expansion.Comment: 15 pages, 7 figure
Intermediate states at structural phase transition: Model with a one-component order parameter coupled to strains
We study a Ginzburg-Landau model of structural phase transition in two
dimensions, in which a single order parameter is coupled to the tetragonal and
dilational strains. Such elastic coupling terms in the free energy much affect
the phase transition behavior particularly near the tricriticality. A
characteristic feature is appearance of intermediate states, where the ordered
and disordered regions coexist on mesoscopic scales in nearly steady states in
a temperature window. The window width increases with increasing the strength
of the dilational coupling. It arises from freezing of phase ordering in
inhomogeneous strains. No impurity mechanism is involved. We present a simple
theory of the intermediate states to produce phase diagrams consistent with
simulation results.Comment: 16 pages, 14 figure
Dynamic van der Waals Theory of two-phase fluids in heat flow
We present a dynamic van der Waals theory. It is useful to study phase
separation when the temperature varies in space. We show that if heat flow is
applied to liquid suspending a gas droplet at zero gravity, a convective flow
occurs such that the temperature gradient within the droplet nearly vanishes.
As the heat flux is increased, the droplet becomes attached to the heated wall
that is wetted by liquid in equilibrium. In one case corresponding to partial
wetting by gas, an apparent contact angle can be defined. In the ther case with
larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure
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