349 research outputs found
Flexible control of the Peierls transition in metallic C polymers
The metal-semiconductor transition of peanut-shaped fullerene (C)
polymers is clarified by considering the electron-phonon coupling in the uneven
structure of the polymers. We established a theory that accounts for the
transition temperature reported in a recent experiment and also suggests
that is considerably lowered by electron doping or prolonged irradiation
during synthesis. The decrease in is an appealing phenomenon with regard
to realizing high-conductivity C-based nanowires even at low
temperatures.Comment: 3 pages, 3 figure
Propagating Knowledge Updates to LMs Through Distillation
Modern language models have the capacity to store and use immense amounts of
knowledge about real-world entities, but it remains unclear how to update such
knowledge stored in model parameters. While prior methods for updating
knowledge in LMs successfully inject atomic facts, updated LMs fail to make
inferences based on injected facts. In this work, we demonstrate that a context
distillation-based approach can both impart knowledge about entities and
propagate that knowledge to enable broader inferences. Our approach consists of
two stages: transfer set generation and distillation on the transfer set. We
first generate a transfer set by prompting a language model to generate
continuations from the entity definition. Then, we update the model parameters
so that the distribution of the LM (the student) matches the distribution of
the LM conditioned on the definition (the teacher) on the transfer set. Our
experiments demonstrate that this approach is more effective at propagating
knowledge updates than fine-tuning and other gradient-based knowledge-editing
methods. Moreover, it does not compromise performance in other contexts, even
when injecting the definitions of up to 150 entities at once.Comment: NeurIPS 2023 Camera Read
Phonon dispersion and electron-phonon interaction in peanut-shaped fullerene polymers
We reveal that the periodic radius modulation peculiar to one-dimensional
(1D) peanut-shaped fullerene (C) polymers exerts a strong influence on
their low-frequency phonon states and their interactions with mobile electrons.
The continuum approximation is employed to show the zone-folding of phonon
dispersion curves, which leads to fast relaxation of a radial breathing mode in
the 1D C polymers. We also formulate the electron-phonon interaction
along the deformation potential theory, demonstrating that only a few set of
electron and phonon modes yields a significant magnitude of the interaction
relevant to the low-temperature physics of the system. The latter finding gives
an important implication for the possible Peierls instability of the C
polymers suggested in the earlier experiment.Comment: 9 pages, 8 figure
Rough Surface Effect on Meissner Diamagnetism in Normal-layer of N-S Proximity-Contact System
Rough surface effect on the Meissner diamagnetic current in the normal layer
of proximity contact N-S bi-layer is investigated in the clean limit. The
diamagnetic current and the screening length are calculated by use of
quasi-classical Green's function. We show that the surface roughness has a
sizable effect, even when a normal layer width is large compared with the
coherence length . The effect is as large as that
of the impurity scattering and also as that of the finite reflection at the N-S
interface.Comment: 12 pages, 3 figures. To be published in J. Phys. Soc. Jpn. Vol.71-
Vibrational spectra of C60C8H8 and C70C8H8 in the rotor-stator and polymer phases
C60-C8H8 and C70-C8H8 are prototypes of rotor-stator cocrystals. We present
infrared and Raman spectra of these materials and show how the rotor-stator
nature is reflected in their vibrational properties. We measured the
vibrational spectra of the polymer phases poly(C60C8H8) and poly(C70C8H8)
resulting from a solid state reaction occurring on heating. Based on the
spectra we propose a connection pattern for the fullerene in poly(C60C8H8),
where the symmetry of the C60 is D2h. On illuminating the C60-C8H8 cocrystal
with green or blue light a photochemical reaction was observed leading to a
similar product to that of the thermal polymerization.Comment: 26 pages, 8 figures, to appear in Journal of Physical Chemistry B 2nd
version: minor changes in wording, accepted version by journa
Far-infrared vibrational properties of high-pressure-high-temperature C60 polymers and the C60 dimer
We report high-resolution far-infrared transmission measurements of the 2 + 2 cycloaddition C-60 dimer and two-dimensional rhombohedral and one-dimensional orthorhombic high-pressure high-temperature C60 polymers. In the spectral region investigated(20-650 cm(-1)), we see no low-energy interball modes, but symmetry breaking of the linked C-60 balls is evident in the complex spectrum of intramolecular modes. Experimental features suggest large splittings or frequency shifts of some IhC60-derived modes that are activated by symmetry reduction, implying that the balls are strongly distorted in these structures. We have calculated the vibrations of all three systems by first-principles quantum molecular dynamics and use them to assign the predominant IhC60 symmetries of observed modes. Pur calculations show unprecedentedly large downshifts of T-1u(2)-derived modes and extremely large splittings of other modes, both of which are consistent with the experimental spectra. For the rhombohedral and orthorhombic polymers, the T-1u(2)-derived mode that is polarized along the bonding direction is calculated to downshift below any T-1u(1)-derived modes. We also identify a previously unassigned feature near 610 cm(-1) in all three systems as a widely split or shifted mode derived from various silent IhC60 vibrations, confirming a strong perturbation model for these linked fullerene structures
Far-infrared study of the Jahn-Teller distorted C60 monoanion in C60 tetraphenylphosphoniumiodide
We report high-resolution far-infrared transmission measurements on C(60)-tetraphenylphosphoniumiodide as a function of temperature. In the spectral region investigated (20-650 cm(-1)), we assign intramolecular modes of the C(60) monoanion and identify low-frequency combination modes. The well-known F(1u)(1) and F(1u)(2) modes are split into doublers at room temperature, indicating a D(5d) or D(3d) distorted ball. This result is consistent with a dynamic Jahn-Teller effect in the strong-coupling limit or with a static distortion stabilized by low-symmetry perturbations. The appearance of silent odd modes is in keeping with symmetry reduction of the hall, while activation of even modes is attributed to interband electron-phonon coupling and orientational disorder in the fulleride salt. Temperature dependences reveal a weak transition in the region 125-150 K in both C(60)(-) and counterion modes, indicating a bulk, rather than solely molecular, effect. Anomalous softening (with decreasing temperature) in several modes may correlate with the radial character of those vibrations. [S0163-1829(98)03245-7]
Pfmrk, a MO15-related protein kinase from Plasmodium falciparum. Gene cloning, sequence, stage-specific expression and chromosome localization.
Cyclin-dependent kinases (Cdks) play a central role in the regulation of the eukaryotic cell cycle. A novel gene encoding a Cdk-like protein, Pfmrk, has been isolated from the human malaria parasite Plasmodium falciparum. The gene has no introns and comprises an open reading frame encoding a protein of 324 amino acids with a predicted molecular mass of 38 kDa. Database searches revealed a striking similarity to the Cdk subfamily with the highest similarity to human MO15 (Cdk7). The overall sequence of Pfmrk shares 62% similarity and 46% identity with human MO15, in comparison to the 49-58% similarity and 34-43% identity with other human Cdks. Pfmrk contains two unique inserts: one consisting of 5 amino acids just before the cyclin-binding motif and the other composed of 13 amino acids within the T-loop equivalent region. Southern blots of genomic DNA digests and chromosomal separations showed that Pfmrk is a single-copy gene conserved between several parasite strains and is located on chromosome 10. A 2500-nucleotide transcript of this gene is expressed predominantly in the sexual blood stages (gametocytes), suggesting that Pfmrk may be involved in sexual stage development
Lymphocytes and the Dap12 Adaptor Are Key Regulators of Osteoclast Activation Associated with Gonadal Failure
Bone resorption by osteoclasts is necessary to maintain bone homeostasis. Osteoclast differentiation from hematopoietic progenitors and their activation depend on M-CSF and RANKL, but also requires co-stimulatory signals acting through receptors associated with DAP12 and FcRγ adaptors. Dap12 mutant mice (KΔ75) are osteopetrotic due to inactive osteoclasts but, surprisingly, these mice are more sensitive than WT mice to bone loss following an ovariectomy. Because estrogen withdrawal is known to disturb bone mass, at least in part, through lymphocyte interaction, we looked at the role of mature lymphocytes on osteoclastogenesis and bone mass in the absence of functional DAP12. Lymphocytes were found to stimulate an early osteoclast differentiation response from Dap12-deficient progenitors in vitro. In vivo, Rag1-/- mice lacking mature lymphocytes did not exhibit any bone phenotype, but lost their bone mass after ovariectomy like KΔ75 mice. KΔ75;Rag1-/- double mutant female mice exhibited a more severe osteopetrosis than Dap12-deficient animals but lost their bone mass after ovariectomy, like single mutants. These results suggest that both DAP12 and mature lymphocytes act synergistically to maintain bone mass under physiological conditions, while playing similar but not synergistic co-stimulatory roles in protecting bone loss after gonadal failure. Thus, our data support a role for lymphocytes during osteoclast differentiation and suggest that they may function as accessory cells when regular osteoclast function is compromised
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