Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement

Efficient, one-pot preparation of synthetically challenging, high molecular weight (MW), narrowly dispersed brush block copolymers and random copolymers in high conversions was achieved by ring-opening metathesis (co)polymerization (ROMP) of various macromonomers (MMs) using the highly active, fast-initiating ruthenium olefin metathesis catalyst (H_2IMes)(pyr)_2(Cl)_2RuCHPh. A series of random and block copolymers were prepared from a pair of MMs containing polylactide (PLA) and poly(n-butyl acrylate) (PnBA) side chains at similar MWs. Their self-assembly in the melt state was studied by small-angle X-ray scattering (SAXS) and atomic force microscopy (AFM). In brush random copolymers containing approximately equal volume fractions of PLA and PnBA, the side chains segregate into lamellae with domain spacing of 14 nm as measured by SAXS, which was in good agreement with the lamellar thickness measured by AFM. The domain spacings and order−disorder transition temperatures of brush random copolymers were insensitive to the backbone length. In contrast, brush block copolymers containing approximately equal volume fractions of these MMs self-assembled into highly ordered lamellae with domain spacing over 100 nm. Their assemblies suggested that the brush block copolymer backbone adopted an extended conformation in the ordered state

The Mass of the Convective Zone in FGK Main Sequence Stars and the Effect of Accreted Planetary Material on Apparent Metallicity Determinations

The mass of the outer convective zone in FGK main sequence stars decreases dramatically with stellar mass. Therefore, any contamination of a star's atmosphere by accreted planetary material should affect hotter stars much more than cool stars. If recent suggestions that high metal abundances in stars with planets are caused by planetesimal accretion are correct, then metallicity enhancements in earlier-type stars with planets should be very pronounced. No such trend is seen, however.Comment: Submitted ApJ Letters March 26th; accepted April 30th. 12 pages, 2 figure

Development of a second generation prototype reflectometer for reflectance measurement in space Final technical report

Prototype reflectometer development for reflection measurements in spac

vbyCaHbeta CCD Photometry of Clusters. VI. The Metal-Deficient Open Cluster NGC 2420

CCD photometry on the intermediate-band vbyCaHbeta system is presented for the metal-deficient open cluster, NGC 2420. Restricting the data to probable single members of the cluster using the CMD and the photometric indices alone generates a sample of 106 stars at the cluster turnoff. The average E(b-y) = 0.03 +/- 0.003 (s.e.m.) or E(B-V) = 0.050 +/- 0.004 (s.e.m.), where the errors refer to internal errors alone. With this reddening, [Fe/H] is derived from both m1 and hk, using b-y and Hbeta as the temperature index. The agreement among the four approaches is reasonable, leading to a final weighted average of [Fe/H] = -0.37 +/- 0.05 (s.e.m.) for the cluster, on a scale where the Hyades has [Fe/H] = +0.12. When combined with the abundances from DDO photometry and from recalibrated low-resolution spectroscopy, the mean metallicity becomes [Fe/H] = -0.32 +/- 0.03. It is also demonstrated that the average cluster abundances based upon either DDO data or low-resolution spectroscopy are consistently reliable to 0.05 dex or better, contrary to published attempts to establish an open cluster metallicity scale using simplistic offset corrections among different surveys.Comment: scheduled for Jan. 2006 AJ; 33 pages, latex, includes 7 figures and 2 table

vbyCaHbeta CCD Photometry of Clusters. VIII. The Super-Metal Rich, Old Open Cluster NGC 6791

CCD photometry on the intermediate-band vbyCaHbeta system is presented for the metal-rich, old open cluster, NGC 6791. Preliminary analysis led to [Fe/H] above +0.4 with an anomalously high reddening and an age below 5 Gyr. A revised calibration between (b-y)_0 and [Fe/H] at a given temperature shows that the traditional color-metallicity relations underestimate the color of the turnoff stars at high metallicity. With the revised relation, the metallicity from hk and the reddening for NGC 6791 become [Fe/H] = +0.45 +/- 0.04 and E(b-y) = 0.113 +/- 0.012 or E(B-V) = 0.155 +/- 0.016. Using the same technique, reanalysis of the photometry for NGC 6253 produces [Fe/H] = +0.58 +/-0.04 and E(b-y) = 0.120 +/- 0.018 or E(B-V) = 0.160 +/- 0.025. The errors quoted include both the internal and external errors. For NGC 6791, the metallicity from m_1 is a factor of two below that from hk, a result that may be coupled to the consistently low metal abundance from DDO photometry of the cluster and the C-deficiency found from high dispersion spectroscopy. E(B-V) is the same value predicted from Galactic reddening maps. With E(B-V) = 0.15 and [Fe/H] = +0.45, the available isochrones predict an age of 7.0 +/- 1.0 Gyr and an apparent modulus of (m-M) = 13.60 +/- 0.15, with the dominant source of the uncertainty arising from inconsistencies among the isochrones. The reanalysis of NGC 6253 with the revised lower reddening confirms that on both the hk and m_1 metallicity scales, NGC 6253, while less than half the age of NGC 6791, remains at least as metal-rich as NGC 6791, if not richer.Comment: Accepted for Astronomical Journal. 42 p. latex file includes 11 figures and 3 tables, one of which is a short version of a data table to appear in online AJ in its entiret

Einstein-Podolsky-Rosen correlations via dissociation of a molecular Bose-Einstein condensate

Recent experimental measurements of atomic intensity correlations through atom shot noise suggest that atomic quadrature phase correlations may soon be measured with a similar precision. We propose a test of local realism with mesoscopic numbers of massive particles based on such measurements. Using dissociation of a Bose-Einstein condensate of diatomic molecules into bosonic atoms, we demonstrate that strongly entangled atomic beams may be produced which possess Einstein-Podolsky-Rosen (EPR) correlations in field quadratures, in direct analogy to the position and momentum correlations originally considered by EPR.Comment: Final published version (corrections in Ref. [32], updated references

Caby Photometry of the Hyades: Comparisons to the Field Stars

Intermediate-band photometry of the Hyades cluster on the Caby system is presented for dwarf stars ranging from spectral type A through late K. A mean hk, b-y relation is constructed using only single stars without anomalous atmospheres and compared to the field stars of the solar neighborhood. For the F dwarfs, the Hyades relation defines an approximate LOWER bound in the two-color diagram, consistent with an [Fe/H] between +0.10 and +0.15. These index-color diagrams follow the common convention of presenting stars with highest abundance at the bottom of the plot although the index values for the metal-rich stars are numerically larger. For field F dwarfs in the range [Fe/H] between +0.4 and -1.0, [Fe/H] = -5.6 delta-hk + 0.125, with no evidence for a color dependence in the slope. For the G and K dwarfs, the Hyades mean relation crosses the field star distribution in the two-color diagram, defining an approximate UPPER bound for the local disk stars. Stars found above the Hyades stars fall in at least one of three categories: [Fe/H] below -0.7, [Fe/H] above that of the Hyades, or chromospherically active. It is concluded that, contrary to the predictions of model atmospheres, the hk index for cool dwarfs at a given color hits a maximum value for stars below solar composition and, with increasing [Fe/H] above some critical value, declines. This trend is consistent, however, with the predictions from synthetic indices based upon much narrower Ca filters where the crossover is caused by the metallicity sensitivity of b-y.Comment: 13 pages, 9 eps figures, 1 tex table, 1 ascii tabl

Frequency Dependent Specific Heat from Thermal Effusion in Spherical Geometry

We present a novel method of measuring the frequency dependent specific heat at the glass transition applied to 5-polyphenyl-4-ether. The method employs thermal waves effusing radially out from the surface of a spherical thermistor that acts as both a heat generator and thermometer. It is a merit of the method compared to planar effusion methods that the influence of the mechanical boundary conditions are analytically known. This implies that it is the longitudinal rather than the isobaric specific heat that is measured. As another merit the thermal conductivity and specific heat can be found independently. The method has highest sensitivity at a frequency where the thermal diffusion length is comparable to the radius of the heat generator. This limits in practise the frequency range to 2-3 decades. An account of the 3omega-technique used including higher order terms in the temperature dependency of the thermistor and in the power generated is furthermore given.Comment: 17 pages, 15 figures, Substantially revised versio

A method to polarise antiprotons in storage rings and create polarised antineutrons

An intense circularely polarised photon beam interacts with a cooled antiproton beam in a storage ring. Due to spin dependent absorption cross sections for the reaction gamma+antiproton > pi- + antineutron a built-up of polarisation of the stored antiprotons takes place. Figures-of-merit around 0.1 can be reached in principle over a wide range of antiproton energies. In this process antineutrons with Polarisation > 70% emerge. The method is presented for the case of 300 MeV/c cooled antiproton beam

Single vortices observed as they enter NbSe2_2

We observe single vortices as they penetrate the edge of a superconductor using a high-sensitivity magneto-optical microscope. The vortices leap across a gap near the edge, a distance that decreases with increasing applied field and sample thickness. This behaviour can be explained by the combined effect of the geometrical barrier and bulk pinning.Comment: 2 pages, 1 figure, M2S-Rio proceeding