Growth of ZnO nanostructures on Si by means of plasma immersion ion implantation and deposition

Crystalline zinc oxide (ZnO) nanostructures have been grown on Si substrates by means of Plasma Based Ion Implantation and Deposition (PIII&D) at temperature of about 300 0C and in the presence of an argon glow discharge. In the process a crucible filled with small pieces of metallic zinc plays the role of the anode of the discharge itself, being polarized by positive DC voltage of about 400V. Electrons produced by thermionic emission by an oxide cathode (Ba, Sr, Ca)O impact this crucible, causing its heating and vaporization of Zn. Partial ionization of Zn atoms takes place due to collisions with plasma particles. High negative voltage pulses (7 kv/40μs/250Hz) applied to the sample holder cause the implantation of metallic zinc into Si surface, while Zn deposition happens between pulses. After annealing at 700 0C, strong UV and various visible photoluminescence bands are observed at room temperature, as well as the presence of ZnO nanoparticles. The coated surface was characterized in detail using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), atomic force microscopy (AFM) and photoluminescence (PL) spectroscopy. XRD indicated the presence of only ZnO peaks after annealing. The composition analysis by EDS revealed distinct Zn/O stoichiometry relation depending on the conditions of the process. AFM images showed the formation of columns in the nanoscale range. Topography viewed by SEM showed the formation of structures similar to cactus with nanothorns. Depth analysis performed by XPS indicated an increase of concentration of metallic Zn with increasing depth and the exclusive presence of ZnO for outer regions. PIII&D allowed to growing nanostructures of ZnO on Si without the need of a buffer layer

The Unruh Quantum Otto Engine

We introduce a quantum heat engine performing an Otto cycle by using the thermal properties of the quantum vacuum. Since Hawking and Unruh, it has been established that the vacuum space, either near a black hole or for an accelerated observer, behaves as a bath of thermal radiation. In this work, we present a fully quantum Otto cycle, which relies on the Unruh effect for a single quantum bit (qubit) in contact with quantum vacuum fluctuations. By using the notions of quantum thermodynamics and perturbation theory we obtain that the quantum vacuum can exchange heat and produce work on the qubit. Moreover, we obtain the efficiency and derive the conditions to have both a thermodynamic and a kinematic cycle in terms of the initial populations of the excited state, which define a range of allowed accelerations for the Unruh engine.Comment: 31 pages, 11 figure

Nonviolation of Bell's Inequality in Translation Invariant Systems

The nature of quantum correlations in strongly correlated systems has been a subject of intense research. In particular, it has been realized that entanglement and quantum discord are present at quantum phase transitions and able to characterize it. Surprisingly, it has been shown for a number of different systems that qubit pairwise states, even when highly entangled, do not violate Bell's inequalities, being in this sense local. Here we show that such a local character of quantum correlations is in fact general for translation invariant systems and has its origins in the monogamy trade-off obeyed by tripartite Bell correlations. We illustrate this result in a quantum spin chain with a soft breaking of translation symmetry. In addition, we extend the monogamy inequality to the $N$-qubit scenario, showing that the bound increases with $N$ and providing examples of its saturation through uniformly generated random pure states.Comment: Published erratum added at the en

The fluctuation-dissipation theorem and the linear Glauber model

We obtain exact expressions for the two-time autocorrelation and response functions of the $d$-dimensional linear Glauber model. Although this linear model does not obey detailed balance in dimensions $d\geq 2$, we show that the usual form of the fluctuation-dissipation ratio still holds in the stationary regime. In the transient regime, we show the occurence of aging, with a special limit of the fluctuation-dissipation ratio, $X_{\infty}=1/2$, for a quench at the critical point.Comment: Accepted for publication (Physical Review E