56 research outputs found
Fabrication of functionally graded 3A/5A zeolites by electrophoretic deposition
Functionally graded zeolites of molecular sieve type 3A and 5A are deposited by electrophoretic deposition (EPD) from acetone suspension with 8% volume concentration of n-butylamine as particle charging agent. The EPD characteristics of both 3A and 5A suspensions are studied. Functionally graded zeolite 3A/5A deposits are obtained at 200 V DC. Energy dispersive X-ray dispersion (EDX) analysis results confirm the graded structure. The deposited zeolites are also analysed by scanning electron microscopy (SEM). The factors influencing the deposition process are discussed
Equivalence problem for the orthogonal webs on the sphere
We solve the equivalence problem for the orthogonally separable webs on the
three-sphere under the action of the isometry group. This continues a classical
project initiated by Olevsky in which he solved the corresponding canonical
forms problem. The solution to the equivalence problem together with the
results by Olevsky forms a complete solution to the problem of orthogonal
separation of variables to the Hamilton-Jacobi equation defined on the
three-sphere via orthogonal separation of variables. It is based on invariant
properties of the characteristic Killing two-tensors in addition to properties
of the corresponding algebraic curvature tensor and the associated Ricci
tensor. The result is illustrated by a non-trivial application to a natural
Hamiltonian defined on the three-sphere.Comment: 32 page
Maxwell Equations in Complex Form of Majorana - Oppenheimer, Solutions with Cylindric Symmetry in Riemann S_{3} and Lobachevsky H_{3} Spaces
Complex formalism of Riemann - Silberstein - Majorana - Oppenheimer in
Maxwell electrodynamics is extended to the case of arbitrary pseudo-Riemannian
space - time in accordance with the tetrad recipe of Tetrode - Weyl - Fock -
Ivanenko. In this approach, the Maxwell equations are solved exactly on the
background of static cosmological Einstein model, parameterized by special
cylindrical coordinates and realized as a Riemann space of constant positive
curvature. A discrete frequency spectrum for electromagnetic modes depending on
the curvature radius of space and three parameters is found, and corresponding
basis electromagnetic solutions have been constructed explicitly. In the case
of elliptical model a part of the constructed solutions should be rejected by
continuity considerations. Similar treatment is given for Maxwell equations in
hyperbolic Lobachevsky model, the complete basis of electromagnetic solutions
in corresponding cylindrical coordinates has been constructed as well, no
quantization of frequencies of electromagnetic modes arises.Comment: 39 page
Iron oxide-based nanostructured ceramics with tailored magnetic and mechanical properties: Development of mechanically robust, bulk superparamagnetic materials
Nanostructured iron-oxide based materials with tailored mechanical and magnetic behavior are produced in bulk form. By applying ultra-fast heating routines via spark plasma sintering (SPS) to supercrystalline pellets, materials with an enhanced combination of elastic modulus, hardness and saturation magnetization are achieved. Supercrystallinity-namely the arrangement of the constituent nanoparticles into periodic structures-is achieved through self-assembly of the organically-functionalized iron oxide nanoparticles. The optimization of the following SPS regime allows the control of organics' removal, necking, iron oxide phase transformations and nano-grain size retention, and thus the fine-tuning of both mechanical properties and magnetic response, up until the production of bulk mm-size superparamagnetic materials.Deusche Forschungsgemeinschaft (DFG
Simulations of dislocation dynamics in aluminum interconnects
A discrete dislocation simulation of plastic deformation in metallic interconnects caused by thermal stress is carried out. The calculations are carried out using a two dimensional plane strain formulation with only edge dislocations. A boundary value problem is formulated and solved for the evolution of the thermal stress field and the evolution of the dislocation structure in the cross-section of the line as cooling proceeds. For lines with a small cross section (height or width less than 1 mum), the local concentration of stresses due to dislocation patterning strongly affects the overall stress build up and relaxation. The results show a clear dependence of the transverse stress development on the line aspect ratio
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