6 research outputs found
The Use of Anhydrous Barium Hydroxide for Selective Alkylation of Dialkyloxy-tert-butyl-calix[4]arenes
A practical method of selective alkylation of the third hydroxyl group of disubstituted tert-butyl-calix[4]arenes using anhydrous barium hydroxide as a base was developed in this study. The use of this method in the synthesis of inherently chiral derivatives is shown herein
The Use of Anhydrous Barium Hydroxide for Selective Alkylation of Dialkyloxy-<i>tert</i>-butyl-calix[4]arenes
A practical method of selective alkylation of the third hydroxyl group of disubstituted tert-butyl-calix[4]arenes using anhydrous barium hydroxide as a base was developed in this study. The use of this method in the synthesis of inherently chiral derivatives is shown herein
Chiral phosphorus-containing calixarenes
International audiencePhosphorus-containing inherently chiral calix[4]arenes as well as calix[4]arenes substituted with phosphinoferrocene chiral groups at the lower rim are described. Stereoselective synthesis, structure, and catalytic properties of the chiral calixarenes are discussed
Synthesis of an Enantiomerically Pure Inherently Chiral Calix[4]Arene Phosphonic Acid and Its Evaluation as an Organocatalyst
A facile
method for the preparation of enantiomerically pure inherently
chiral calix[4]Âarene phosphonic acid (<i>cR</i>,<i>pR</i>)-<b>7</b> in four steps starting from the readily
available and previously synthesized (<i>cS</i>)-enantiomer
of calix[4]Âarene acetic acid <b>1</b> or its methyl ester <b>2</b> was developed. The first tests of this unique calixarene
BroÌnsted acid with inherent chirality in organocatalysis of
the aza-DielsâAlder reaction of imines with Danishefskyâs
diene and epoxide ring opening by benzoic acid were performed. The
calixarene phosphonic acid (<i>cR</i>,<i>pR</i>)-<b>7</b> shows good catalytic activities but with low enantioselectivities
in these reactions