Quasar 3C 298: a test-case for meteoritic nanodiamond 3.5 µm emission

Aims. We calculate the dust emission expected at 3.43 and 3.53 µm if meteoritic (i.e. hydrogenated) nanodiamonds are responsible for most of the far-UV break observed in quasars. Methods. We integrate the UV flux that hydrogenated nanodiamonds must absorb to reproduce the far-UV break. Based on laboratory spectra of H-terminated diamond surfaces, we analyse the radiative energy budget and derive theoretically the IR emission profiles expected for possible C-H surface stretch modes of the diamonds. Results. Using as test case a spectrum of 3C 298 provided by the Spitzer Observatory, we do not find evidence of these emission bands. Conclusions. While diamonds without surface adsorbates remain a viable candidate for explaining the far-UV break observed in quasars, hydrogenated nanodiamonds appear to be ruled out, as they would give rise to IR emission bands, which have not been observed so far

Nitrous oxide emissions from 2008 to 2012 for agricultural lands in the conterminous United States

The soil N2O emissions data for the conterminous United States were generated by the DayCent ecosystem model using the crop and land-use histories for survey locations in the USDA-NRCS National Resources Inventory (NRI). The model also requires weather and soils data. Daily maximum/minimum temperature and precipitation data are based on gridded weather data from the PRISM Climate Data product. Soils data are obtained from Soil Survey Geographic Database (SSURGO). See Del Grosso et al. (2022) and US-EPA (2020) for more details about the simulations. Atmospheric inversions were conducted using the CarbonTracker Langrage framework (Nevison et al. 2018). These results provide total N2O fluxes for the domain using atmospheric observations and an inverse modeling, and are compared to the DayCent emissions to confirm seasonal patterns, particularly the role of freeze-thaw events in driving pulses of N2O emissions from agricultural lands.Nitrous oxide (N2O) is an important greenhouse gas (GHG) that also contributes to depletion of ozone in the stratosphere. Agricultural soils account for about 60% of anthropogenic N2O emissions. Most national GHG reporting to the UN Framework Convention on Climate Change assumes nitrogen (N) additions drive emissions during the growing season, but soil freezing and thawing during spring is also an important driver in cold climates. We show that both atmospheric inversions and newly implemented bottom-up modeling approaches exhibit large N2O pulses in the northcentral region of the United States during early spring and this increases annual N2O emissions from croplands and grasslands reported in the national GHG inventory by 11%. Considering this, emission accounting in cold climate regions is very likely under-estimated in most national reporting frameworks. Current commitments related to the Paris Agreement and COP 26 emphasize reductions of carbon compounds. Assuming these targets are met, the importance of accurately accounting and mitigating N2O increases once CO2 and CH4 are phased out. Hence, the N2O emission under-estimate introduces additional risks into meeting long term climate goals.US Forest Service 18-CR-11242305-109, US Department of Agriculture (USDA) UV-B Monitoring and Research Program, Colorado State University, under USDA National Institute of Food and Agriculture Grant 2016-34263-25763, and the USDA GHG and DayCent modeling NACA agreements (58-3012-9-012 and 58-3012-1-015

Polarization of Broad Absorption Line QSOs I. A Spectropolarimetric Atlas

We present a spectropolarimetric survey of 36 broad absorption line quasi-stellar objects (BAL QSOs). The continuum, absorption trough, and emission line polarization of BAL QSOs yield clues about their structure. We confirm that BAL QSOs are in general more highly polarized than non-BAL QSOs, consistent with a more equatorial viewing direction for the former than the latter. We have identified two new highly-polarized QSOs in our sample (1232+1325 and 1333+2840). The polarization rises weakly to the blue in most objects, perhaps due to scattering and absorption by dust particles. We find that a polarization increase in the BAL troughs is a general property of polarized BAL QSOs, indicating an excess of scattered light relative to direct light, and consistent with the unification of BAL QSOs and non-BAL QSOs. We have also discovered evidence of resonantly scattered photons in the red wing of the C IV broad emission lines of a few objects. In most cases, the broad emission lines have lower polarization and a different position angle than the continuum. The polarization characteristics of low-ionization BAL QSOs are similar to those of high-ionization BAL QSOs, suggesting a similar BAL wind geometry.Comment: 39 pages, 6 figures (20 .gif files), accepted for publication in The Astrophysical Journal Supplement

Shocked Molecular Hydrogen in the 3C 326 Radio Galaxy System

The Spitzer spectrum of the giant FR II radio galaxy 3C 326 is dominated by very strong molecular hydrogen emission lines on a faint IR continuum. The H2 emission originates in the northern component of a double-galaxy system associated with 3C 326. The integrated luminosity in H2 pure-rotational lines is 8.0E41 erg/s, which corresponds to 17% of the 8-70 micron luminosity of the galaxy. A wide range of temperatures (125-1000 K) is measured from the H2 0-0 S(0)-S(7) transitions, leading to a warm H2 mass of 1.1E9 Msun. Low-excitation ionic forbidden emission lines are consistent with an optical LINER classification for the active nucleus, which is not luminous enough to power the observed H2 emission. The H2 could be shock-heated by the radio jets, but there is no direct indication of this. More likely, the H2 is shock-heated in a tidal accretion flow induced by interaction with the southern companion galaxy. The latter scenario is supported by an irregular morphology, tidal bridge, and possible tidal tail imaged with IRAC at 3-9 micron. Unlike ULIRGs, which in some cases exhibit H2 line luminosities of comparable strength, 3C 326 shows little star-formation activity (~0.1 Msun/yr). This may represent an important stage in galaxy evolution. Starburst activity and efficient accretion onto the central supermassive black hole may be delayed until the shock-heated H2 can kinematically settle and coolComment: 27 pages, 7 figures, accepted for publication in the Astrophysical Journa

PPE – Can you have too much of a good thing?

PresentationSpecifying Personal Protective Equipment (PPE) after a hazard has been identified is a critical aspect of a facility’s ability to protect their workers. In a chemical manufacturing facility, manual operations and maintenance activities have the potential to expose workers to hazardous chemicals and flammable atmospheres. Even though it is generally recognized to be one of the least effective safeguards in the hierarchy of controls, PPE is often the last line of defense, and sometimes the only feasible defense, that isolates workers from potential hazards. As a result, companies may lean toward putting workers in higher levels of PPE to provide additional protection. However, in many cases higher levels of PPE may introduce new hazards associated with limited worker mobility, fatigue, unreliable job performance, or limited egress. Therefore, PPE specification should focus not only on what is necessary to protect the worker, but also what is appropriate for a given job task. In this paper, a risk-based approach to PPE selection, specification, and use will be presented. Discussion will focus on potential hazards that can be inadvertently introduced because of PPE over-specification. Studies related to the impact of PPE on worker performance will be presented to help demonstrate the potential negative impacts of over specifying PPE. Lastly, a case study will be presented where a PPE specification was questioned, and the impact of increasing the PPE specification for a job task was evaluated

Structure of the X-ray Emission from the Jet of 3C 273

We present images from five observations of the quasar 3C 273 with the Chandra X-ray Observatory. The jet has at least four distinct features which are not resolved in previous observations. The first knot in the jet (A1) is very bright in X-rays. Its X-ray spectrum is well fitted with a power law with alpha = 0.60 +/- 0.05. Combining this measurement with lower frequency data shows that a pure synchrotron model can fit the spectrum of this knot from 1.647 GHz to 5 keV (over nine decades in energy) with alpha = 0.76 +/- 0.02, similar to the X-ray spectral slope. Thus, we place a lower limit on the total power radiated by this knot of 1.5e43 erg/s; substantially more power may be emitted in the hard X-ray and gamma-ray bands. Knot A2 is also detected and is somewhat blended with knot B1. Synchrotron emission may also explain the X-ray emission but a spectral bend is required near the optical band. For knots A1 and B1, the X-ray flux dominates the emitted energy. For the remaining optical knots (C through H), localized X-ray enhancements that might correspond to the optical features are not clearly resolved. The position angle of the jet ridge line follows the optical shape with distinct, aperiodic excursions of +/-1 deg from a median value of -138.0deg. Finally, we find X-ray emission from the ``inner jet'' between 5 and 10" from the core.Comment: 10 pages, 5 figures; accepted for publication in the Astrophysical Journal Letters. For the color image, see fig1.ps or http://space.mit.edu/~hermanm/papers/3c273/fig1.jp