Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids

To progress from the laboratory to commercial applications, it will be necessary to develop industrially scalable methods to produce large quantities of defect-free graphene. Here we show that high-shear mixing of graphite in suitable stabilizing liquids results in large-scale exfoliation to give dispersions of graphene nanosheets. X-ray photoelectron spectroscopy and Raman spectroscopy show the exfoliated flakes to be unoxidized and free of basal-plane defects. We have developed a simple model that shows exfoliation to occur once the local shear rate exceeds 10(4) s(-1). By fully characterizing the scaling behaviour of the graphene production rate, we show that exfoliation can be achieved in liquid volumes from hundreds of millilitres up to hundreds of litres and beyond. The graphene produced by this method performs well in applications from composites to conductive coatings. This method can be applied to exfoliate BN, MoS2 and a range of other layered crystals

Supplementary information files for An open-source platform for 3D-printed redox flow battery test cells

Supplementary files for article An open-source platform for 3D-printed redox flow battery test cells The development of new, large-scale stationary energy storage technologies, such as redox flow batteries, is vital to fully utilise renewable energy resources. However, test cells capable of assisting in this development can be prohibitively expensive and unreliable. Here, an open-source, low-cost, customisable 3D-printed test cell is presented as an alternative. These newly developed cells are designed to be printable using affordable desktop 3D-printers and readily available polymers. A simulation-led design optimisation yielded an improved internal manifold geometry that demonstrated improved real-world performance. The polymers used have been tested for chemical compatibility and through the use of advanced X-ray micro-CT, optimised parameters for 3D-printing have been identified. This framework provides a straightforward process enabling researchers to produce robust cells at an extremely low cost, helping to democratise research and widen accessibility to flow electrochemistry. </p

An open-source platform for 3D-printed redox flow battery test cells

The development of new, large-scale stationary energy storage technologies, such as redox flow batteries, is vital to fully utilise renewable energy resources. However, test cells capable of assisting in this development can be prohibitively expensive and unreliable. Here, an open-source, low-cost, customisable 3D-printed test cell is presented as an alternative. These newly developed cells are designed to be printable using affordable desktop 3D-printers and readily available polymers. A simulation-led design optimisation yielded an improved internal manifold geometry that demonstrated improved real-world performance. The polymers used have been tested for chemical compatibility and through the use of advanced X-ray micro-CT, optimised parameters for 3D-printing have been identified. This framework provides a straightforward process enabling researchers to produce robust cells at an extremely low cost, helping to democratise research and widen accessibility to flow electrochemistry.</p