7 research outputs found

    Nanotribology: Nonlinear mechanisms of friction

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    Friction with its related nonlinear dynamics is a vast interdisciplinary field, involving complex physical processes over a wide range of length and time scales. The accelerated progress in experimental and computational techniques, often leading to complex detailed dynamical patterns, has vigorously stimulated the search and implementation of idealized experimental frameworks and simplermathematical models, capable of describing and interpreting, in amore immediateway, the essential physics involved in nonlinear sliding phenomena

    Microimaging of transient guest profiles to monitor mass transfer in nanoporous materials

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    The intense interactions of guest molecules with the pore walls of nanoporous materials is the subject of continued fundamental research. Stimulated by their thermal energy, the guest molecules in these materials are subject to a continuous, irregular motion, referred to as diffusion. Diffusion, which is omnipresent in nature, influences the efficacy of nanoporous materials in reaction and separation processes. The recently introduced techniques of microimaging by interference and infrared microscopy provide us with a wealth of information on diffusion, hitherto inaccessible from commonly used techniques. Examples include the determination of surface barriers and the sticking coefficient's analogue, namely the probability that, on colliding with the particle surface, a molecule may continue its diffusion path into the interior. Microimaging is further seen to open new vistas in multicomponent guest diffusion ( including the detection of a reversal in the preferred diffusion pathways), in guest-induced phase transitions in nanoporous materials and in matching the results of diffusion studies under equilibrium and nonequilibrium conditions

    Size effects on the fracture of microscale and nanoscale materials

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