Synthesis, Characterization and Kinetic Studies of Nickel (Ii) Complex of Dibenzoyl Methane and It’s Adduct

Nickel (II) Complex of dibenzoylmethane and the 1, 10 phenantroline adduct were synthesized using Nickel (II) acetate tetrahydrate in aqueous methanol. The resulting green Ni2+ compounds were characterized by elemental analysis, magnetic moments, IR and UV spectroscopy. The kinetics of the reaction for the formation of the complex   was conducted. The complex and adduct were identified by coupled vibrations of Ni-O + Ni-N which were conspicuously absent in the neat ligand .The elemental and metal analysis indicates 1:2 Metal-Ligand ratio in both complex and adduct. The electronic spectral and magnetic susceptibility studies are consistent with the adoption of an octahedral geometry for the adduct.  Results of the kinetic study showed that the formation of the nickel complex occurs at a rate of 1.7 x 103 – 9.2 x 103 moldm-3 in a 2nd order  reversible reaction, which involved both the metal and the ligand with equilibrium constant Keq ranging from 2.0 x 104 – 1.5 x 106. The observed rate is at variance with the rate of solvent exchange, this being typical of a tautomeric ligand. Keywords: 1, 10-phenantroline, Dibenzoylmethane, Kinetics, Solvent-exchange

Preparation and characterization of activated carbon from groundnut and egg shells as viable precursors for adsorption

This study was carried out to prepare groundnut shell (GS) and eggshell (ES) into activated carbon (AC) and characterize the AC using Association of Official Analytical Chemists (AOAC) and American Standard for Testing and Materials (ASTM) methods. The AC produced was characterized for: pH, moisture content, volatile matter, ash content, fixed carbon, bulk density and surface area. Surface functional groups and surface morphology were also determined using Fourier Transformed Infrared (FT-IR) and Scanning Electron Microscope (SEM) respectively. The ranges of the following results were achieved for the biomasses: Groundnut shell Activated Carbon (GSAC) and Eggshell Activated Carbon (ESAC) respectively: pH (6.80±0.101−7.80±0.011); moisture content (14.10±0.101−12.90±.110%); volatile matter (9.20±0.112−9.90±0.012%); ash content (8.98±0.111−5.80±0.111%); fixed carbon (67.70±0.010−71.40±110%); bulk density (370.00±0.000−380.00−0.000 g/L); surface area (880.00±0.100−800.00±0.000 m2/g). The agro-wastes have high carbon contents and low inorganic which make them viable adsorbents. FT-IR analysis revealed the presence of oxygen surface complexes such as carbonyls and OH groups on the surface of the ACs in addition to good pore structures from SEM studies revealed that the agro-wastes could be good precursors for ACs production. The overall results showed that the AC produced from the agro-wastes can be optimally used as good and effective adsorbents, thereby ensuring cheaper, readily available and affordable ACs for the treatment of effluent, waste water and used oils

Water Parameters and Floristic Composition of African Manatee (Trichechus senegalensis) Habitat in Pandam Wildlife Park, Nigeria

The study of the physicochemical characteristic and floristic composition of African manatee habitat in Pandam Lake was conducted between 2012 and 2013. The water parameters were tested using standard method while line intercept method was adopted for vegetation survey. Data obtained on the water parameters were analyzed using one-way ANOVA. Plant species diversity index was analyzed using PAST Software. The mean seasonal water surface area increase was 66.12±5.01. The mean water depth in the dry season was 2.28±1.14 while the wet season value was 4.3±1.15. Also the mean water transparency was for wet and dry seasons were 64.02±4.66 and 111.18±4.26 respectively. The mean pH value was 6.5±0.14. Water salinity ranges from 0.00mg/l to 0.01mg/l, mean DO was 6.24±1.13, nitrate was 0.08±0.02 and mean conductivity of 52.65 ±2.12. A total of 42 plant species from 23 families were recorded in Pandam Lake. The family Poaceae had the highest number of species (22) (30.56%). The grass species had the highest frequency of 13 while trees recorded the lowest (3). Also there are more perennial species (n=28; 66.67%) than annual species (n=14; 33.33%). The Shannon diversity index was 3.72. Thirteen species of plants recorded in Pandan Lake during this study were known to provide food for manatees across their range in Africa. All the water parameter values were within the range tolerable by manatee. The Lake have diverse species of plants that manatee can feed on both in the wet and dry seasons. The park management should maintain the integrity of the ecosystem by regulating fishing and other human activities to avoid pollution. The park should be taken over by the Federal government for effective protection of the resources most especially manatee.Keywords: Water quality, vegetation, African manatee, Pandam Lak

Assessment of Flexible Pavement on Some Selected Roads in Ola Oluwa Local Government, South Western Nigeria

The most used mode of transportation in Nigeria is road while flexible pavement is the most constructed on the roads. This project work is all about carefully assessing the condition of the flexible pavement on some selected roads, determine some causes of the failure on the selected roads in Ola Oluwa Local Government area of Osun State, South-western Nigeria. The visual assessments of the pavement were carried out through Pavement Condition Survey and the drainage condition of the selected roads. Disturbed soil samples were taken from the failed and unfailed portion of the roads and their geotechnical properties determined. After the thorough assessment of the pavements on selected roads it can be concluded that the failures on the roads are due to non-functioning drainage facilities, poor design, non-standard construction materials and poor maintenance culture. Keywords: Flexible pavement, Pavement Condition Survey, disturbed soil samples, geotechnical properties

Genotypic identification of coliforms isolated from cases of subclinical mastitis among pastoral herds in parts of Kaduna State, Nigeria

Background: Mastitis caused by Staphylococcus aureus was initially considered the major problem in dairy herds, but over the last few decades, the incidence of coliform mastitis has increased among the pastoral herds in Nigeria due to poor environmental and milking hygiene. Hence, this study was aimed at genotypic identification of coliform bacteria isolated from cases of bovine mastitis among pastoral herds in parts of Kaduna State, Nigeria.Methods: A cross-sectional survey of 30 herds of cows across 7 Local Government Areas of Kaduna State, Nigeria, was conducted. One hundred and forty seven cows were proportionately selected by purposive sampling technique. The milk samples were aseptically collected and bacteriologically screened for coliform bacteria following standard bacteriological techniques. Nine out of 12 coliforms identified phenotypically were selected for PCR amplification and sequencing of their 16S rRNA gene. The Basic Local Alignment Search Tool (BLAST) analysis of the sequences obtained was done on the National Centre for Biotechnology Information (NCBI) data base, and isolates confirmed based on similarity to 16S rDNA sequences in the Gen BankResults: Five of the 9 coliforms were confirmed to be Klebsiella pneumoniae (prevalence rate, 3.4%) and 4 were confirmed to be Escherichia coli (prevalence rate, 2.7%).Conclusion: This study shows that raw milk of mastitic cows can serve as a vehicle for the spread of pathogens such as K. pneumoniae and E. coli which, according to the Department of Health and Human Services of the United States Public Health Services, are potential threats to public health and safety of humans, animals and plant products.Keywords: pastoral herds, subclinical mastitis, cows, PCR, 16s rRNA, sequencin

Growth Performance, Haematological Indices and Cost Benefits of Growing Pigs Fed Cassava Peel Meal Diets Supplemented With Allzyme® SSF

Effect of replacing dietary maize with cassava peel meal (CPM) supplemented with Allzyme® SSF (SSF) on the growth performance, haematological indices and cost benefits of growing pigs was investigated. Chemical composition of CPM and diets used were determined using standard procedures. Twenty-four growing pigs with average weight of 14.0+0.25kg were allotted to 6 dietary treatments whereby CPM replaced maize at 0, 50 and 100% levels with SSF supplementation at 0g/100kg and 20g/100kg of diet. Each treatment was replicated 4 times while the experiment lasted 8 weeks. Data were collected on daily feed intake (DFI), daily weight gain (DWG) and feed conversion ratio (FCR); feed cost/weight gain and feed cost/day were calculated. Blood samples collected through jugular vein puncture were analyzed for haematological indices such as white blood cells (WBC), red blood cell and platelet count. The CPM diets with or without SSF gave comparable (P>0.05) pigs’ growth performance to what was obtained for pigs on the maize based diets in terms of DFI (1.26 – 1.33kg), DWG (0.32 – 0.40kg) and FCR (3.13 – 4.03). Values for WBC were within normal range, though they had significant (p<0.05) variations. Other haematological parameters were not influenced (p>0.05) by CPM inclusion. Feed cost/kg diet (N54.11 – N74.39) and feed cost/weight gain (N195.33 – N244.65) reduced insignificantly (P>0.05) with CPM inclusion in the diets of pigs. It was concluded that cassava peel meal can totally replace maize with or without enzyme supplementation in the diets of growing pigs for optimal performance at reduced cost

Comparative evaluation of the effects of organic and inorganic fertilizers on the vegetative growth of spleen amaranth (Amaranthus dubius L)

The application of organic and inorganic fertilizers to the soil is considered as good agricultural practice because they improve the fertility of the soil and plant quality. The overall objective of the study is to compare the effects of organic fertilizers (cow dung and chicken droppings) with inorganic fertilizer (urea) on the vegetativegrowth of Amaranthus dubius. The data obtained showed that, levels of all parameters measured for both the organic and inorganic fertilizers ranges; Stem length (7.5- 64.2) cm, Stem width (2.4- 8.1) cm, Leaf length (8.0- 19.3) cm, Leaf width (3.3- 14.2) cm and Number of leaves per plant (09- 34). The mean values for the stem length, stem width, leaf length, leaf width and number of leaves per plant were evaluated and found to be higher in plants grown with urea treatment compared to values obtained from the treatments with organic manures. Data were analyzed using One-way Analysis of Variance (ANOVA) and the results were expressed as percentage difference, the differences between the mean values were determined at 95% confidence. Inorganic fertilizer resulted in significant effects at (p<0.05) compared to values obtained from the organic manures.Keywords: Amaranthus dubius, Chicken droppings, Cow dung, Ure

Pediatric Blood Culture Isolates and Antibiotic Sensitivity Pattern in a Nigerian Tertiary Hospital

Introduction: There is a significant variation in the bacterial pathogens implicated in childhood septicemia and their antibiotic sensitivity patternfrom place to place. Sustained monitoring of this dynamics is therefore critical to rational antibiotic use. Materials and Methods: This study was thus conducted to determine the etiology of childhood septicemia and their antibiotic sensitivity pattern. Blood culture results (contaminants excluded), age, and sex of all pediatric patients with suspected septicemia between January 2013 and December 2014 were retrieved. Data were analyzed using SPSS version 20. Results: Over a 2‑year period, a total of 3680 blood samples were processed. Pathogenic bacteria were isolated in 701 samples (19%).    Staphylococcus aureus was the most common isolate (41.4%) and was most sensitive to ampicillin‑sulbactam (89%). Klebsiella species (21.7%),  coagulase‑negative Staphylococcus (14.7%), and Pseudomonas aeruginosa (11%) were other common organisms isolated. Virtually, all the isolates demonstrated a reliable susceptibility to ciprofloxacin except for S. aureus and Klebsiella species which were most sensitive to ampicillin‑sulbactam and imipenem, respectively. Conclusion: In conclusions, S. aureus is the leading cause of childhood septicemia in this locale. The significant rate of isolation of the supposedly less virulent organisms calls for an urgent review of potential risk factors and an appraisal of the hospital infection control policies and structures. Keywords: Antibiotics, isolates, paediatri

Carcass yield and intestinal morphology of male rabbits fed diets supplemented with turmeric (Curcuma Longa) powder

Thirty-two (7-8 weeks old) male rabbits that weighed between 700 and 800 g were used to determine the effect of inclusion of Turmeric powder on carcass yield and intestinal morphology of rabbits. The rabbits were randomly allotted to four diets containing varying levels of turmeric powder (0, 5, 10 and 15 g) in a complete randomized design. Data were collected on carcass yield, duodenum, jejunum, ileum, crypt depth, mucosal thickness and analyzed using ANOVA. Significant (p<0.05) differences were obtained on bled and eviscerated weights, forelimbs, hind limbs, neck, tail and loin. Highest (p<0.05) duodenum crypt depth (111.50 μm) was obtained with buck fed diet containing 15 g turmeric inclusion while buck fed with diet containing 0 g turmeric had the least value of (67.67 μm). This was similar (p>0.05) with values obtained for buck fed diets containing 5 g turmeric (73.83 μm) and those fed with 10 g turmeric inclusion (79.33 μm). There was significant difference (P<0.05) of rabbit fed with diets with turmeric on jejunum villi height. There was significant difference (P<0.05) in jejunum crypt depth and mucosal thickness. However, 10 g inclusion could be assumed as economic inclusion level for carcass yield and intestinal increase in rabbit production

Peak particle velocity data acquisition for monitoring blast induced earthquakes in quarry sites

The peak particle velocity datasets recorded during quarry blasts in the neighborhood villages and towns in Ibadan and Abeokuta were processed and analyzed in order to recommend a safe blast design for each of the quarries. The minimum peak particle velocity of 48.27 mm/s was recorded near the foundation of the nearest residence at the shot to monitored distance of 500m. The tendency of ground vibration emanating from the quarry sites to cause damage to the structures in the nearby dwelling areas is very high. The peak particle velocity datasets recorded were not within the safe limit. Therefore the peak particle velocity that will not exceed 35 mm/s is recommended for a safe blast design