Non-equilibrium chemistry and dust formation in AGB stars as probed by SiO line emission

We have performed high spatial resolution observations of SiO line emission for a sample of 11 AGB stars using the ATCA, VLA and SMA interferometers. Detailed radiative transfer modelling suggests that there are steep chemical gradients of SiO in their circumstellar envelopes. The emerging picture is one where the radial SiO abundance distribution starts at an initial high abundance, in the case of M-stars consistent with LTE chemistry, that drastically decreases at a radius of ~1E15 cm. This is consistent with a scenario where SiO freezes out onto dust grains. The region of the wind with low abundance is much more extended, typically ~1E16 cm, and limited by photodissociation. The surpisingly high SiO abundances found in carbon stars requires non-equilibrium chemical processes.Comment: 2 pages, 1 figure. To be published in the proceedings of the conference "Why Galaxies Care about AGB Stars", held in Vienna, August 7-11, 2006; F. Kerschbaum, C. Charbonnel, B. Wing eds, ASP Conf.Ser. in pres

The surface accessibility of α-bungarotoxin monitored by a novel paramagnetic probe

The surface accessibility of {alpha}-bungarotoxin has been investigated by using Gd2L7, a newly designed paramagnetic NMR probe. Signal attenuations induced by Gd2L7 on {alpha}-bungarotoxin C{alpha}H peaks of 1H-13C HSQC spectra have been analyzed and compared with the ones previously obtained in the presence of GdDTPA-BMA. In spite of the different molecular size and shape, for the two probes a common pathway of approach to the {alpha}-bungarotoxin surface can be observed with an equally enhanced access of both GdDTPA-BMA and Gd2L7 towards the protein surface side where the binding site is located. Molecular dynamics simulations suggest that protein backbone flexibility and surface hydration contribute to the observed preferential approach of both gadolinium complexes specifically to the part of the {alpha}-bungarotoxin surface which is involved in the interaction with its physiological target, the nicotinic acetylcholine receptor

Health effects of gasoline exposure. I. Exposure assessment for U.S. distribution workers.

Personal exposures were estimated for a large cohort of workers in the U.S. domestic system for distributing gasoline by trucks and marine vessels. This assessment included development of a rationale and methodology for extrapolating vapor exposures prior to the availability of measurement data, analysis of existing measurement data to estimate task and job exposures during 1975-1985, and extrapolation of truck and marine job exposures before 1975. A worker's vapor exposure was extrapolated from three sets of factors: the tasks in his or her job associated with vapor sources, the characteristics of vapor sources (equipment and other facilities) at the work site, and the composition of petroleum products producing vapors. Historical data were collected on the tasks in job definitions, on work-site facilities, and on product composition. These data were used in a model to estimate the overall time-weighted-average vapor exposure for jobs based on estimates of task exposures and their duration. Task exposures were highest during tank filling in trucks and marine vessels. Measured average annual, full-shift exposures during 1975-1985 ranged from 9 to 14 ppm of total hydrocarbon vapor for truck drivers and 2 to 35 ppm for marine workers on inland waterways. Extrapolated past average exposures in truck operations were highest for truck drivers before 1965 (range 140-220 ppm). Other jobs in truck operations resulted in much lower exposures. Because there were few changes in marine operations before 1979, exposures were assumed to be the same as those measured during 1975-1985. Well-defined exposure gradients were found across jobs within time periods, which were suitable for epidemiologic analyses

Heavy Quarkonia and Quark Drip Lines in Quark-Gluon Plasma

Using the potential model and thermodynamical quantities obtained in lattice gauge calculations, we determine the spontaneous dissociation temperatures of color-singlet quarkonia and the `quark drip lines' which separate the region of bound $Q\bar Q$ states from the unbound region. The dissociation temperatures of $J/\psi$ and $\chi_b$ in quenched QCD are found to be 1.62$T_c$ and $1.18T_c$ respectively, in good agreement with spectral function analyses. The dissociation temperature of $J/\psi$ in full QCD with 2 flavors is found to be 1.42$T_c$. For possible bound quarkonium states with light quarks, the characteristics of the quark drip lines severely limit the stable region close to the phase transition temperature. Bound color-singlet quarkonia with light quarks may exist very near the phase transition temperature if their effective quark mass is of the order of 300-400 MeV and higher.Comment: 8 pages, 2 figures, in LaTex, invited talk presented at the International Conference on Strangeness in Quark Matter, UCLA, March 26-31, 200