Nonlocal communication with photoinduced structures at the surface of a polymer film

Nonlocal communication between two laser light beams is experimented in a photochromic polymer thin films. Information exchange between the beams is mediated by the self-induction of a surface relief pattern. The exchanged information is related to the pitch and orientation of the grating. Both are determined by the incident beam. The process can be applied to experiment on a new kind of logic gates.Comment: 7 pages, 4 figures, 2 table

Multistate polarization addressing using one single beam in an azo polymer film

Peculiar light-matter interactions can break the rule that a single beam polarization can address only two states in an optical memory device. Multistate storage of a single beam polarization is achieved using self-induced surface diffraction gratings in a photo-active polymer material. The grating orientation follows the incident light beam polarization direction. The permanent self-induced surface relief grating can be readout in real time using the same laser beam.Comment: 11 pages,3 figure

Mastering Nano-Objects with Photoswitchable Molecules for Nanotechnology Applications

Advance in the fabrication of nano-objects becomes more important for the development of new nanodevices with local properties leading to new functional devices. In this direction, the assembly of nanometer-scaled building objects into device configurations and functionalization is a promising investigated research field in nanotechnology. Optical recording and photofabrication techniques that exploit changes in material properties have gained importance, and there is a requirement for a decrease of the dimensions of the recording and processing surfaces. Photochromic materials leading to submicron structures responding to stimuli and in particular light are the best materials that exhibit multifunctional behaviors. Photomechanical properties of azopolymers show the perfect performance in photoinduced nanopatterning and reshaping by tailored light fields. Azopolymer nanostructures are then recognized as an excellent choice for a broad range of fundamental and applied research in modern nanotechnology. This chapter shows how polymer nanofilms, nanotubes, nanospheres, or nanowires containing azobenzene can be controlled by light for new photonics applications. Spatially confined excitation of unidirectional motions could make possible the local control of mechanical properties of the material and its structuration. The unprecedented flexibility of the reported photofluidization lithography with this material allows producing well-defined structures as lines, ellipsoids, rectangles, and circles at azopolymer surface with several tenth nanometers structural features

Spontaneous formation of optically induced surface relief gratings

A model based on Fick's law of diffusion as a phenomenological description of the molecular motion, and on the coupled mode theory, is developped to describe single-beam surface relief grating formation in azopolymers thin films. It allows to explain the mechanism of spontaneous patterning, and self-organization. It allows also to compute the surface relief profile and its evolution in time with good agreement with experiments

Cognitive ability process at the molecular level

In the standard SRG formation in azo-dye containing photoactive polymers, the photoactive molecules are excited by a coherent illumination pattern. The highly reactive molecules move in a non-uniform way, inducing a mass transport from the bright regions to the neighbouring dark regions. The maximum heights of the light induced SRG correspond to light intensity minima. We show that a well-defined surface relief grating is induced in an azo-polymer film by the combination of one low power coherent laser beam with another high power incoherent and unpolarised beam. The information brought by the coherent signal beam has been transmitted to peripheral incoherent regions by the molecular self-assembling process: i.e., the organised molecules communicate non-local information about photo-induced structural organisation to the non organised neighbouring ones. They communicate by exchanging light through surface relief variations. In this way, we see that a totally incoherent beam can provide the movement which is necessary to induce a well-defined SRG. We find in this way one of the simplest systems allowing to figure out the minimal requirements to organise disordered materials into well organised structures. We verify experimentally that random motion plus information exchange lead to self-organisation. Our experiment shows that complex behaviour can be experimented using simple systems: weak coherent light can serve as a seed to create information into a polymer film in such a way that molecules powered by incoherent light will build and transmit well defined complex structures

Cooperative interaction in azopolymers upon irradiation

We present two optical experiments which permits to evaluate individual and collective behaviours of molecules leading to a well-organized pattern in a randomly activated molecular assembly; in a first experiment a white light and a laser beam are sent together; in a second experiment a low-power coherent beam carr 3rd International Symposium on Molecular Materials (MOLMAT

Surface relief grating formation on nano-objects

We exploit the photoinduced migration effect in azopolymer thin films to induce surface relief patterning of nano-objects. Manipulation and precise control of the molecular order is achieved at the nanoscale. Interaction between a laser beam from an argon laser and the azopolymer nano-objects induces structures on the surface. The self-patterning process is observed to depend on the laser beam polarization

Second harmonic generation and photochromic grating in polyurethane films containing diazo isoxazole chromophore

The chromophoric intermediate: 2,2′-({4-[(E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer film was at 418 nm. The illumination of the film with crossed beams of the 488 nm Ar+ laser yielded surface relief grating of regular structure. Measurement of the frequency doubling signal with 1064 nm laser indicated the polymer as interesting material for photooptical applications. The measured nonlinear optical coefficient, d33, reached 90.2 pm/V

Mouvement photomoléculaire sur des nano-objets en azopolymère: Vers de nouvelles applications en photonique

Date du colloque&nbsp;: 08/2010</p