Synthesis and properties of Co-doped titanate nanotubes and their optical sensitization with methylene blue

Here we report on a novel chemical route to synthesize homogenous cobalt doped titanate nanotubes (CoTNT), using an amorphous Co-doped precursor. The influence of the synthesis temperature, autoclave dwell time and metal doping on the structural and microstructural as well as on the optical properties of the synthesized titanate nanotubes is studied and discussed. The optical band gaps of the CoTNT samples are red shifted in comparison with the values determined for the undoped samples, such red shifts bringing the absorption edge of the CoTNT samples into the visible region. CoTNT materials also demonstrate particular high adsorption ability for methylene blue, the amount of the adsorbed dye being higher than the one predictable for a monolayer formation. This suggests the possibility of intercalation of the dye molecule between the TiO6 layers of the TNT structure. It is also shown that the methylene blue sensitized Co-doped nanostructures are highly stable under UV radiation and present a strong and broad absorption in the visible region.Comment: 31 pages, 3 tables, 7 figure

On quasi-Jacobi and Jacobi-quasi bialgebroids

We study quasi-Jacobi and Jacobi-quasi bialgebroids and their relationships with twisted Jacobi and quasi Jacobi manifolds. We show that we can construct quasi-Lie bialgebroids from quasi-Jacobi bialgebroids, and conversely, and also that the structures induced on their base manifolds are related via a quasi Poissonization

Temperature dependence of the coercive field in single-domain particle systems

The magnetic properties of Cu97Co3 and Cu90Co10 granular alloys were measured over a wide temperature range (2 to 300K). The measurements show an unusual temperature dependence of the coercive field. A generalized model is proposed and explains well the experimental behavior over a wide temperature range. The coexistence of blocked and unblocked particles for a given temperature rises difficulties that are solved here by introducing a temperature dependent blocking temperature. An empirical factor gamma arise from the model and is directly related to the particle interactions. The proposed generalized model describes well the experimental results and can be applied to other single-domain particle system.Comment: 7 pages, 8 figures, revised version, accepted to Physical Review B on 29/04/200

Mass freezing in growing neutrino quintessence

Growing neutrino quintessence solves the coincidence problem for dark energy by a growing cosmological value of the neutrino mass which emerges from a cosmon-neutrino interaction stronger than gravity. The cosmon-mediated attraction between neutrinos induces the formation of large scale neutrino lumps in a recent cosmological epoch. We argue that the non-linearities in the cosmon field equations stop the further increase of the neutrino mass within sufficiently dense and large lumps. As a result, we find the neutrino induced gravitational potential to be substantially reduced when compared to linear extrapolations. We furthermore demonstrate that inside a lump the possible time variation of fundamental constants is much smaller than their cosmological evolution. This feature may reconcile current geophysical bounds with claimed cosmological variations of the fine structure constant.Comment: 15 pages, 12 figures. Version published in PR