Design of gas turbine axial compressors for fuel flexibility

Current gas turbine technology for power generation is generally optimised for natural gas. On the basis of current instabilities in natural gas price and supply, the use of alternative fuels, such as syngas, has recently gained high interest. Due to the different thermodynamic properties of syngas compared to natural gas the behaviour of existing gas turbine components may significantly change. From practical and economic points of view, it is generally considered that in order to meet the new fuel properties, the main effort should be put on the adaptation of conventional gas turbines in integrated gasification combined cycle (IGCC) plants rather than producing a new generation of gas turbine designs from scratch. In addition to the requirement of new combustion technologies, main critical issues are represented by the reduction of compressor surge margin and turbine blade overheating. Solutions might include thermodynamic cycle as well as turbine geometry modifications. The latter would be preferred in terms of power plant performance. The main aim of this thesis is to explore suitable solutions to be applied to gas turbine compressors in order to accommodate syngas combustion. Among others, the use of variable stator vanes (VSVs) and blade radial stacking line modifications are considered. These are investigated on reference geometries available in the public domain. A baseline compressor geometry representative of a conventional heavy-duty gas turbine fueled with natural gas is generated and modified according to the understating gained during this study. The re-designed machine is a result of the application of stator vanes re-staggering in the front stages and blade sweep in the rear stages in order to cope with compressor air supply control and critical flow separation regions respectively. The obtained results show that efficient and stable operation during power modulation can be achieved, while reducing the need of other modifications to the combined cycle plant. It was therefore concluded that the proposed option can be considered a viable option to satisfy some important technical and economic constraints imposed by the integration of an existing gas turbine within an IGCC plant

Protein clustering in chemically stressed HeLa cells studied by infrared nanospectroscopy

Photo-Thermal Induced Resonance (PTIR) nanospectroscopy, tuned towards amide-I absorption, was used to study the distribution of proteic material in 34 different HeLa cells, of which 18 were chemically stressed by oxidative stress with Na3AsO3. The cell nucleus was found to provide a weaker amide-I signal than the surrounding cytoplasm, while the strongest PTIR signal comes from the perinuclear region. AFM topography shows that the cells exposed to oxidative stress undergo a volume reduction with respect to the control cells, through an accumulation of the proteic material around and above the nucleus. This is confirmed by the PTIR maps of the cytoplasm, where the pixels providing a high amide-I signal were identified with a space resolution of ∼300 × 300 nm. By analyzing their distribution with two different statistical procedures we found that the probability to find protein clusters smaller than 0.6 μm in the cytoplasm of stressed HeLa cells is higher by 35% than in the control cells. These results indicate that it is possible to study proteic clustering within single cells by label-free optical nanospectroscopy

Electrolytic Hydrogen Production From Renewable Source, Storage and Reconversion in Fuel Cells: The System of the “Mediterranea” University of Reggio Calabria

AbstractNowadays a redesign of cities, amid the others from an energetic point of view, is taking place. It increasingly addresses the smart city model, an organic system in which infrastructures, services and technology are organized in order to achieve friendly and livable cities, combining in a single urban model environment protection, energy efficiency and economic sustainability.In smart cities buildings are nZEB and equipped with domotics applications, energy grids are smart, transports are electric, lighting is high-efficiency, hydrogen is used for energy storage, ecc. As concerns this latter, in the last periods hydrogen has increasingly shown to be particularly fit as an energetic carrier, being not pollutant, versatile, allowing production at all scales and, compared to electric battery, not requiring time consuming recharging. Anyway, due to the present relevant starting funds of its technology, its quick, effective penetration into the market still requires the necessary economic breakthroughs.Within this frame, in the paper a system aimed at hydrogen production through electrolysis from renewable source (provided by both PV and wind generators), its storage and reconversion in fuel cells is presented. The system is installed at the Mediterranea University of Reggio Calabria. Particularly, in the paper the global process taking place in the system is described, evaluating the hourly hydrogen stored amount, the power autonomy provided and the global efficiency of the process

Optical study of the vibrational and dielectric properties of BiMnO3

BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also ferroelectric (FE) due to a non-centro-symmetric C2 structure, until diffraction data indicated that its space group is the centro-symmetric C2/c. Here we present infrared phonon spectra of BMO, taken on a mosaic of single crystals, which are consistent with C2/c at any T > 10 K, as well as room-temperature Raman data which strongly support this conclusion. We also find that the infrared intensity of several phonons increases steadily for decreasing T, causing the relative permittivity of BMO to vary from 18.5 at 300 K to 45 at 10 K. At variance with FE materials of displacive type, no appreciable softening has been found in the infrared phonons. Both their frequencies and intensities, moreover, appear insensitive to the FM transition at Tc

Infrared study of the charge-ordered multiferroic LuFe(2)O(4)

The reflectivity of a large LuFe(2)O(4) single crystal has been measured with the radiation field either perpendicular or parallel to the c axis of its rhombohedral structure, from 10 to 500K, and from 7 to 16000 cm-1. The transition between the two-dimensional and the three-dimensional charge order at T_(CO) = 320 K is found to change dramatically the phonon spectrum in both polarizations. The number of the observed modes above and below T_(CO), according to a factor-group analysis, is in good agreement with a transition from the rhombohedral space group R{bar 3}m to the monoclinic C2/m. In the sub-THz region a peak becomes evident at low temperature, whose origin is discussed in relation with previous experiments.Comment: Physical Review B in pres

Effect of Mn substitution by Ga on the optical properties of a metallic manganite

In a metallic manganite like La(2/3)Sr(1/3)MnO(3), the substitution of Mn(+3) by Ga(+3) dilutes the ferromagnetic order and locally cancels the Jahn-Teller distortion, without heavily affecting the crystal structure. One can thus follow the changes in the charge dynamics induced by Ga, until the ferro-metallic manganite is turned into an insulator. Here this phenomenon is studied in detail through the infrared reflectivity of five samples of La(2/3)Sr(1/3)Mn(1-x)Ga(x)O(3), with x increasing from 0 to 0.30 and for 50 < T < 320 K. A simple model which links the measured optical parameters to the magnetization M(x, T) well describes the behavior of the plasma frequency, the scattering rate, and the mid-infrared absorption along the metal-to-insulator transition.Comment: 8 pages including 7 figure

Optical Properties of (SrMnO3)n/(LaMnO3)2n superlattices: an insulator-to-metal transition observed in the absence of disorder

We measure the optical conductivity of (SrMnO3)n/(LaMnO3)2n superlattices (SL) for n=1,3,5, and 8 and 10 < T < 400 K. Data show a T-dependent insulator to metal transition (IMT) for n \leq 3, driven by the softening of a polaronic mid-infrared band. At n = 5 that softening is incomplete, while at the largest-period n=8 compound the MIR band is independent of T and the SL remains insulating. One can thus first observe the IMT in a manganite system in the absence of the disorder due to chemical doping. Unsuccessful reconstruction of the SL optical properties from those of the original bulk materials suggests that (SrMnO3)n/(LaMnO3)2n heterostructures give rise to a novel electronic state.Comment: Published Online in Nano Letters, November 8, 2010; http://pubs.acs.org/doi/abs/10.1021/nl1022628; 5 pages, 3 figure

Effect of Al doping on the optical phonon spectrum in Mg(1-x)Al(x)B(2)

Raman and infrared absorption spectra of Mg(1-x)Al(x)B(2) have been collected for 0<x<0.5 in the spectral range of optical phonons. The x-dependence of the peak frequency, the width and the intensity of the observed Raman lines has been carefully analized. A peculiar x-dependence of the optical modes is pointed out for two different Al doping ranges. In particular the onset of the high-doping structural phase previously observed in diffraction measurements is marked by the appearence of new spectral components at high frequencies. A connection between the whole of our results and the observed suppression of superconductivity in the high doping region is established