Application of the Limit Cycle Model to Star Formation Histories in Spiral Galaxies: Variation among Morphological Types

We propose a limit-cycle scenario of star formation history for any morphological type of spiral galaxies. It is known observationally that the early-type spiral sample has a wider range of the present star formation rate (SFR) than the late-type sample. This tendency is understood in the framework of the limit-cycle model of the interstellar medium (ISM), in which the SFR cyclically changes in accordance with the temporal variation of the mass fraction of the three ISM components. When the limit-cycle model of the ISM is applied, the amplitude of variation of the SFR is expected to change with the supernova (SN) rate. Observational evidence indicates that the early-type spiral galaxies show smaller rates of present SN than late-type ones. Combining this evidence with the limit-cycle model of the ISM, we predict that the early-type spiral galaxies show larger amplitudes in their SFR variation than the late-types. Indeed, this prediction is consistent with the observed wider range of the SFR in the early-type sample than in the late-type sample. Thus, in the framework of the limit-cycle model of the ISM, we are able to interpret the difference in the amplitude of SFR variation among the morphological classes of spiral galaxies.Comment: 12 pages LaTeX, to appear in A

Elliptical Galaxy Dynamics

A review of elliptical galaxy dynamics, with a focus on nonintegrable models. Topics covered include torus construction; modelling axisymmetric galaxies; triaxiality; collisionless relaxation; and collective instabilities.Comment: 97 Latex pages, 14 Postscript figures, uses aastex. To appear in Publications of the Astronomical Society of the Pacific, February 199

Chain transfer kinetics of acid/base switchable n-aryl- n-pyridyl dithiocarbamate RAFT agents in methyl acrylate, n-vinylcarbazole and vinyl acetate polymerization

This is an accepted manuscript of an article published by American Chemistry Society in Macromolecules on 14/05/2012, available online: https://doi.org/10.1021/ma300616g ©American Chemical Society. The accepted version of the publication may differ from the final published version.The structures of the "Z" and "R" substituents of a RAFT agent (Z-C(S)S-R) determine a RAFT agent's ability to control radical polymerization. In this paper we report new acid/base switchable N-aryl-N-pyridyl dithiocarbamates (R = -CH 2CN, Z = -N(Py)(Ar)) which vary in substituent at the 4-position of the aryl ring and the use of these to control molecular weight and dispersity. In their protonated form, the new RAFT agents are more effective in controlling polymerization of the more activated monomer, methyl acrylate (MA), whereas in their neutral form they provide more effective control of the polymerization of less activated monomers, N-vinyl carbazole (NVC) and vinyl acetate (VAc). For each polymerization, the apparent chain transfer coefficient (C trapp) shows a good correlation with Hammett parameters. Dithiocarbamates with more electron-withdrawing aryl ring substituents have the higher C trapp. This demonstrates the influence of polar effects on C trapp and supports the hypothesis that the activity of these RAFT agents is determined by the availability of the lone pair of the dithiocarbamate nitrogen.The authors gratefully acknowledge the Capability Development Fund of CSIRO Materials Science and Engineering for financial support.Published versio