2 research outputs found
Nano- and Submicrometer-Sized Spherical Particle Fabrication Using a Submicroscopic Droplet Formed Using Selective Laser Heating
Detailed
characterization of products by pulsed laser melting in
liquid was performed for TiO<sub>2</sub> particles obtained at different
laser fluences. The size, crystal structure, and inner structure of
obtained spherical particles depended on the irradiating laser fluence.
Single crystalline submicrometer spherical TiO<sub>2</sub> particles
of 200 nm were obtained using nanosecond pulsed laser irradiation
at 100 mJ cm<sup>–2</sup> pulse<sup>–1</sup> onto raw
particles dispersed in ethanol using cross-sectional high-resolution
transmission electron microscopy observation. At higher laser fluence
(e.g., 225 mJ cm<sup>–2</sup> pulse<sup>–1</sup>), large
submicrometer spheres with strain and twin structures 500 nm in diameter
and nanometer spheres of 70 nm were simultaneously observed. The formation
of such bimodal size distribution of obtained particles was explained
based on the phase transition fluence curves deduced by Mie theory
and the optical absorption increase induced by the formation of nonstoichiometric
TiO<sub>2</sub> particles. Thus, with the appropriate laser fluence,
this laser process can produce single crystalline submicrometer spherical
particles and nanometer spheres via cooling of droplets formed by
a selective laser heating by optical absorption