Geochemical Studies of Rare Earth Elements (REE) in Ion Adsorption Clays (IAC) in Gua Musang, Kelantan

Rare earth element (REE) become the ‘critical metals’ for green technology development that have been rapidly expanded worldwide in these days. REE is mainly originated from granitic rocks. REE in ion adsorption clay (IAC) is the product from weathering of granite. IAC are believed to store high concentration of heavy rare earth element (HREE) and light rare earth element (LREE). Gua Musang is selected for this study because it is located on the three longitudinal belts that composed of acid volcanic igneous rocks from Main Range, Senting and Boundary Range Granites. In this study, the characteristics of ion adsorption clays and REE distribution in Gua Musang have been studied by mineralogy and geochemical analyses. Rocks and soil samples were collected closed to the granite bodies and its surrounding to represent its weathering products. Polarised optical microscopy was used for petrography and mineralogy studies. From fieldwork observation, Gua Musang lithologies composed of carbonate facies, argillaceous facies and pyroclastic facies. X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD) and Inductive Coupled Plasma Microspectrometry (ICP-MS) were used accordingly to characterise the composition of major and trace elements in IAC samples. REE value in Pulai are the highest concentration as iron nodule have been found in the sampling area. Sample from Boundary Range granite also reported store high concentration of REEs in this study

Landslide investigation using Electrical Resistivity Imaging (ERI) method at Kg. Chuchoh Puteri, Kuala Krai, Kelantan, Malaysia

The possible landslide in Kg. Chuchoh Puteri, Kuala Krai, Kelantan were investigated using the electrical resistivity imaging (ERI) technique. The survey for the collecting of data was conducted along six lines. Each survey line was 200 meters long, with 5 meters between electrodes. ABEM Terrameter LS 1 is used to record all the data and RES2DINV software is used to process it. While conducting the geophysical survey, the relationship between resistivity and conductivity is reciprocal. A pole-dipole array configuration was utilised in survey Lines 1, 2, 4 and 5 and in survey Lines 3 and 6, a Schlumberger array configuration. Survey Lines 2, 3, and 6 are primarily indicated as having a high probability of experiencing a landslide using the pseudosection 2-D profile. The findings reveal varying resistivity at a depth of study between 40 and 80 meters for a survey line length of 200 meters. In general, the resistivity survey's seven pseudosections showed two distinct types of soils: dry residual soil (1–1500 Ωm) and weathered volcanic rocks (>1500 Ωm). Residual soils with varying saturation levels, hard soil and weathered volcanic rock, have dominated the soil profile. These profiles can generally be divided into two (2) zones: thin/thick layers of loose to dense residual soils (10–100 Ωm; Zone A) and thin/thick layers of dense and hard material (> 1000 Ωm)

Rare earth distribution in Batu Melintang Granitic Rocks, Jeli, Kelantan

Rare Earth Element (REE) is a group of elements that consisting of 17 metallic elements that that occur together in the periodic table, 15 lanthanides (La), Scandium (Sc) and Yttrium (Y). REE can be divided into two groups based on atomic weight which are the light REEs are lanthanum through gadolinium (atomic numbers 57 through 64); the heavy REEs comprise terbium through lutetium (atomic numbers 65 through 71). This paper investigates the distribution of Heavy REE and Light REE in granite rock in Batu Melintang, Jeli, Kelantan. This study employed Induced Coupled Plasma Mass Spectrometry (ICP-MS) to determine the distribution of rare earth elements. According to the findings, the research region has been found to contain 16 REE elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er Tm, Yb, Lu), with LREE distribution being greater than HREE in the granite rocks of Batu Melintang. LREE with concentration ranging from as low as 2285.53 ppb to as high as 35888.32 ppb with Ce and La being the most abundant LREE in the samples. While for HREE, the concentration ranged from 4479.72 ppb to 11,457.67 ppb, and abundance of Y, Yb, and Sc was found to be the highest in the HREE group

Geochemical Studies of Rare Earth Elements (REE) in Ion Adsorption Clays (IAC) in Gua Musang, Kelantan

Rare earth element (REE) become the ‘critical metals’ for green technology development that have been rapidly expanded worldwide in these days. REE is mainly originated from granitic rocks. REE in ion adsorption clay (IAC) is the product from weathering of granite. IAC are believed to store high concentration of heavy rare earth element (HREE) and light rare earth element (LREE). Gua Musang is selected for this study because it is located on the three longitudinal belts that composed of acid volcanic igneous rocks from Main Range, Senting and Boundary Range Granites. In this study, the characteristics of ion adsorption clays and REE distribution in Gua Musang have been studied by mineralogy and geochemical analyses. Rocks and soil samples were collected closed to the granite bodies and its surrounding to represent its weathering products. Polarised optical microscopy was used for petrography and mineralogy studies. From fieldwork observation, Gua Musang lithologies composed of carbonate facies, argillaceous facies and pyroclastic facies. X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD) and Inductive Coupled Plasma Microspectrometry (ICP-MS) were used accordingly to characterise the composition of major and trace elements in IAC samples. REE value in Pulai are the highest concentration as iron nodule have been found in the sampling area. Sample from Boundary Range granite also reported store high concentration of REEs in this study

The controls on the composition of biodegraded oils in the deep subsurface – Part 4. Destruction and production of high molecular weight non-hydrocarbon species and destruction of aromatic hydrocarbons during progressive in-reservoir biodegradation

This study extends the analysis of previously well studied biodegraded crude oil case history sample sets. The analytical window is extended into the high molecular weight, aromatic hydrocarbon and non-hydrocarbon fraction of crude oils, using a 12 T ultra-high resolution mass spectrometer (FTICR-MS). Biodegradation is pervasive across compound groups and extent of degradation appears dependent on compound abundance and hence availability. Oil constituents with molecular weights up to m/z 600 (carbon number 44) are affected by in-reservoir biodegradation. Apart from special, specific compound groups possibly related to the active reservoir biomass, all hydrocarbon and single heteroatom-containing compound classes are depleted by biodegradation. Production of various highly alkylated species indicate that transformation of crude oil components often involves derivatization and preservation rather than just complete destruction of high molecular weight compounds. Whereas one case study shows good correlation between depletion of S1 species and a strong increase in SO2 species, a nitrogen enriched oil suite shows an analogous trend in the transformation of N1 species to the corresponding NO2 species. Increase in O2 species are seen in both sample sets indicating partial oxidation is a major overall process in in-situ reservoir biodegradation. These variations are important geochemically but also impact transport, interfacial and corrosion properties of oils. Nitrogen isotope systematics indicate that nitrogen-containing compounds might act as nitrogen nutrient sources or mainly as carbon sources for the microorganisms causing in-situ reservoir biodegradation depending level of biodegradation. Distributions of some heterocyclic species add a very biodegradation resistant parameter set, to the petroleum geochemists arsenal

Rare earth distribution in Batu Melintang Granitic Rocks, Jeli, Kelantan

Rare Earth Element (REE) is a group of elements that consisting of 17 metallic elements that that occur together in the periodic table, 15 lanthanides (La), Scandium (Sc) and Yttrium (Y). REE can be divided into two groups based on atomic weight which are the light REEs are lanthanum through gadolinium (atomic numbers 57 through 64); the heavy REEs comprise terbium through lutetium (atomic numbers 65 through 71). This paper investigates the distribution of Heavy REE and Light REE in granite rock in Batu Melintang, Jeli, Kelantan. This study employed Induced Coupled Plasma Mass Spectrometry (ICP-MS) to determine the distribution of rare earth elements. According to the findings, the research region has been found to contain 16 REE elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er Tm, Yb, Lu), with LREE distribution being greater than HREE in the granite rocks of Batu Melintang. LREE with concentration ranging from as low as 2285.53 ppb to as high as 35888.32 ppb with Ce and La being the most abundant LREE in the samples. While for HREE, the concentration ranged from 4479.72 ppb to 11,457.67 ppb, and abundance of Y, Yb, and Sc was found to be the highest in the HREE group

Assessment of metal pollution using enrichment factor (EF) and pollution load index (PLI) in sediments of selected Terengganu rivers, Malaysia

Anthropogenic activities that happen in Terengganu River were contributed to sediment pollution at that area. The sediment pollution occurred when sediment are additional influenced with chemical adsorption between the metals, grain size, and organic matter. Thus, this study was conducted to assess the metal pollution using Enrichment Factor (EF) and Pollution Load Index (PLI) and compared with the previous study. A total of 15 sediment samples were collected from 5 different rives and metal concentration were analyzed using flame Atomic Absorption Spectrometer (ASS). The metal concentration ranged as followed: Cr (0.48-12.80 mg/kg), Cu (0.38-15.20 mg/kg), Mg (202.00-2769.00mg/kg), K (63.36-1730.00 mg/kg), Mn (4.27-33.70 mg/kg), Zn (2.05-31.30 mg/kg) and Cl (141.00-584.00 mg/kg) respectively. Enrichment Factor (EF) and Pollution Load Index (PLI) were used as a pollution indicator to access the sediment pollution in selected Terengganu Rivers. The mean Enrichment Factor (EF) value indicated in decrease order Cl (34.70) > Zn (23.44) > Cu (10.37) > Cr (1.95) > K (1.58) > Mg (1.16)> Mn (0.87). Meanwhile, Pollution Load Index (PLI) value showed below than 1 in all sampling stations. When compared with previous study, Mg and Cl metals need to take further action due to dramatically increased within seven years. The output from this study will be useful for environmental management at Terengganu Rivers