14,998 research outputs found
Test of quantum chemistry in vibrationally-hot hydrogen molecules
Precision measurements are performed on highly excited vibrational quantum
states of molecular hydrogen. The rovibrational levels of H
(), lying only cm below the first dissociation
limit, were populated by photodissociation of HS and their level energies
were accurately determined by two-photon Doppler-free spectroscopy. A
comparison between the experimental results on level energies with the
best \textit{ab initio} calculations shows good agreement, where the present
experimental accuracy of cm is more precise than
theory, hence providing a gateway to further test theoretical advances in this
benchmark quantum system.Comment: 5 pages, 4 figures, and 2 table
High-speed measurement of rotational anisotropy nonlinear optical harmonic generation using position sensitive detection
We present a method of performing high-speed rotational anisotropy nonlinear
optical harmonic generation experiments at rotational frequencies of several
hertz by projecting the harmonic light reflected at different angles from a
sample onto a stationary position sensitive detector. The high rotational speed
of the technique, to times larger than existing methods, permits
precise measurements of the crystallographic and electronic symmetries of
samples by averaging over low frequency laser power, beam pointing, and pulse
width fluctuations. We demonstrate the sensitivity of our technique by
resolving the bulk four-fold rotational symmetry of GaAs about its [001] axis
using second harmonic generation
High-precision laser spectroscopy of the CO A - X (2,0), (3,0) and (4,0) bands
High-precision two-photon Doppler-free frequency measurements have been
performed on the CO A - X fourth-positive system (2,0),
(3,0), and (4,0) bands. Absolute frequencies of forty-three transitions, for
rotational quantum numbers up to , have been determined at an accuracy
of cm, using advanced techniques of two-color 2+1'
resonance-enhanced multi-photon ionization, Sagnac interferometry,
frequency-chirp analysis on the laser pulses, and correction for AC-Stark
shifts. The accurate transition frequencies of the CO A - X
system are of relevance for comparison with astronomical data in the search for
possible drifts of fundamental constants in the early universe. The present
accuracies in laboratory wavelengths of may be considered exact for the purpose of such comparisons.Comment: 13 pages, 6 figures, The Journal of Chemical Physics (2015) accepte
Berry phases in superconducting transitions
I generalize the concept of Berry's geometrical phase for quasicyclic
Hamiltonians to the case in which the ground state evolves adiabatically to an
excited state after one cycle, but returns to the ground state after an integer
number of cycles. This allows to extend the charge Berry phase gamma_c related
to the macroscopic polarization, to many-body systems with fractional number of
particles per site. Under certain conditions, gamma_c and the spin Berry phase
gamma_s jump in pi at the boundary of superconducting phases. In the extended
Hubbard chain with on-site attraction U and nearest-neighbor interaction V at
quarter filling, the transitions detected agree very well with exact results in
two limits solved by the Bethe ansatz, and with previous numerical studies. In
chains with spin SU(2) symmetry, gamma_s jumps when a spin gap opens.Comment: 5 pages, 3 figures, accepted in Europhys. Let
The CO A-X System for Constraining Cosmological Drift of the Proton-Electron Mass Ratio
The band system of carbon monoxide,
which has been detected in six highly redshifted galaxies (), is
identified as a novel probe method to search for possible variations of the
proton-electron mass ratio () on cosmological time scales. Laboratory
wavelengths of the spectral lines of the A-X (,0) bands for have
been determined at an accuracy of
through VUV Fourier-transform absorption spectroscopy, providing a
comprehensive and accurate zero-redshift data set. For the (0,0) and (1,0)
bands, two-photon Doppler-free laser spectroscopy has been applied at the accuracy level, verifying the absorption data. Sensitivity
coefficients for a varying have been calculated for the CO A-X
bands, so that an operational method results to search for -variation.Comment: 7 pages (main article), 3 figures, includes supplementary materia
Compression of Atomic Phase Space Using an Asymmetric One-Way Barrier
We show how to construct asymmetric optical barriers for atoms. These
barriers can be used to compress phase space of a sample by creating a confined
region in space where atoms can accumulate with heating at the single photon
recoil level. We illustrate our method with a simple two-level model and then
show how it can be applied to more realistic multi-level atoms
Vanishing viscosity limits for the degenerate lake equations with Navier boundary conditions
The paper is concerned with the vanishing viscosity limit of the
two-dimensional degenerate viscous lake equations when the Navier slip
conditions are prescribed on the impermeable boundary of a simply connected
bounded regular domain. When the initial vorticity is in the Lebesgue space
with , we show the degenerate viscous lake equations
possess a unique global solution and the solution converges to a corresponding
weak solution of the inviscid lake equations. In the special case when the
vorticity is in , an explicit convergence rate is obtained
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