Development of Internet of Things (IoT) Based Monitoring of Hazardous Exhaust Compounds in Air - A Review

Presence of pollutants in Air is the most prominent problem globally confronted now a day. The extreme use of fueled vehicles and rapid urbanization has deteriorated the air quality. This deteriorated air contains hazardous compounds like Mono-oxides & Di-oxides of carbon, Sulphur, Nitrogen, Atmospheric Particulate Matter. Exposure to such hazardous compounds in the air for a long time can cause damage to the human health. Traditional air monitoring systems consists of monitoring stations. As far as traditional air quality monitoring methods are concerned, they are highly expensive and requires a regular maintenance. Due to these limitations, these stations are deployed in small numbers and also it provides indicative values of the sensed data. This monitored data has low resolution and precision. This paper proposes framework for the development of smart and portable system using Internet of Things (IoT) for monitoring of hazardous exhaust compounds in the air using real time. This framework consists of different types of sensors and a controller that are used for monitoring and assessment of the air quality. Also it is used to check the presence of hazardous compounds emitted by different industries and share this data through IOT. The outcome of the proposed research work can be utilized by industries as well as by other agencies to carry out an audit of hazardous exhaust components present in air, so as to take necessary precautions and to save human

Development of Internet of Things (IoT) Based Monitoring of Hazardous Exhaust Compounds in Air - A Review

Presence of pollutants in Air is the most prominent problem globally confronted now a day. The extreme use of fueled vehicles and rapid urbanization has deteriorated the air quality. This deteriorated air contains hazardous compounds like Mono-oxides & Di-oxides of carbon, Sulphur, Nitrogen, Atmospheric Particulate Matter. Exposure to such hazardous compounds in the air for a long time can cause damage to the human health. Traditional air monitoring systems consists of monitoring stations. As far as traditional air quality monitoring methods are concerned, they are highly expensive and requires a regular maintenance. Due to these limitations, these stations are deployed in small numbers and also it provides indicative values of the sensed data. This monitored data has low resolution and precision. This paper proposes framework for the development of smart and portable system using Internet of Things (IoT) for monitoring of hazardous exhaust compounds in the air using real time. This framework consists of different types of sensors and a controller that are used for monitoring and assessment of the air quality. Also it is used to check the presence of hazardous compounds emitted by different industries and share this data through IOT. The outcome of the proposed research work can be utilized by industries as well as by other agencies to carry out an audit of hazardous exhaust components present in air, so as to take necessary precautions and to save human

Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting

Highly efficient and low-cost electrocatalysts are essential for water spitting via electrolysis in an economically viable fashion. However, the best catalytic performance is found with noble metal-based electrocatalysts, which presents a formidable obstacle for the commercial success of electrolytic water splitting-based H2 production due to their relatively high cost and scarcity. Therefore, the development of alternative inexpensive earth-abundant electrode materials with excellent electrocatalytic properties is of great urgency. In general, efficient electrocatalysts must possess several key characteristics such as low overpotential, good electrocatalytic activity, high stability, and low production costs. Direct synthesis of nanostructured catalysts on a conducting substrate may potentially improve the performance of the resultant electrocatalysts because of their high catalytic surface areas and the synergistic effect between the electrocatalyst and the conductive substrate. In this regard, three dimensional (3D) nickel foams have been advantageously utilized as electrode substrates as they offer a large active surface area and a highly conductive continuous porous 3D network. In this review, we discuss the most recent developments in nanostructured materials directly synthesized on 3D nickel foam as potential electrode candidates for electrochemical water electrolysis, namely, the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). We also provide perspectives and outlooks for catalysts grown directly on 3D conducting substrates for future sustainable energy technologies. © The Royal Society of Chemistry 2017192

Supported copper oxide as a highly active/selective catalyst for the epoxidation of styrene by TBHP to styrene oxide

Liquid phase epoxidation of styrene by anhydrous and aqueous TBHP to styrene oxide has been studied under reflux, using different supported CuO (viz. CuO/Si-MCM-41, CuO/Al2O3, CuO/Ga2O3 and CuO/In2O3) as easily separable and reusable heterogeneous catalysts. The CuO/Ga2O3 catalyst showed the best performance in the epoxidation by aqueous TBHP. The CuO supported on In2O3 or Si-MCM-41 also showed very good performance in the epoxidation but only by anhydrous TBHP. However, the CuO/SiO2 catalyst, however, showed very good performance in the epoxidation by both the anhydrous and aqueous TBHP. Influence of the reaction conditions (temperature, time and TBHP/styrene ratio) on the epoxidation by aqueous TBHP over the best catalyst (CuO/Ga2O3) has been investigated

Dyshidrosiform pemphigoid with Parkinsonism in a nonagenarian Maharashtrian female

Dyshidrosiform pemphigoid is a rare variant of bullous pemphigoid localized to the hands and feet whose characteristic subepidermal blisters develop as a result of binding of the IgG autoantibodies to intracellular plaque and extracellular face of the hemidesmosome recognizing a 230-kDa plakin molecule (BP230, BPAg1or BPAg1e) and a 180-kDa transmembrane protein. Neurodegenerative processes (viz., stroke, dementia, Parkinsonism, epilepsy, etc) uncover BPAg1-n, an alternatively spliced form of BPAg1-e that stabilizes the cytoskeleton of sensory neurons, generating autoantibodies that may subsequently lead to BP by cross-reacting with BPAg1-e. We present a patient with Parkinsonism who later developed blisters, erosions and crusts localized to the palms and soles, confirmed histopathologically as bullous pemphigoid. To the best of our knowledge, ours is the first case report from India wherein Parkinsonism-generated autoantibodies led to the development of dyshidrosiform pemphigoid due to their cross-reactivity with BPAg1-e

Familial myomatosis cutis et uteri, segmental type 2

Reed′s syndrome or familial myomatosis cutis et uteri, an autosomal dominant inherited condition with incomplete penetrance, is characterized by multiple cutaneous and uterine leiomyomas. [1] Uterine leiomyomas usually commence earlier compared to that in the general population and cutaneous leiomyomas may precede, follow or occur concurrently. Few patients may have associated renal cell carcinoma. Herein we report a case of a 50-year-old female with multiple, painful cutaneous leiomyomas and who had undergone hysterectomy owing to large uterine fibroids. Her 18-year-old daughter also has uterine fibroids

Clinicoepidemiological study of skin manifestations in patients of chronic renal failure on hemodialysis

Background: Chronic renal failure (CRF) is associated with a variety of cutaneous manifestations as a result of underlying etiology as well as the various treatment modalities. Aim: To evaluate the prevalence of various dermatoses in patients with CRF on hemodialysis and to study the effect of hemodialysis on the intensity of pruritus. Materials and Methods: A total of 35 patients of CRF on hemodialysis having at least one cutaneous manifestation were included in the study. Results: Twenty-four (68.71%) cases in our study belonged to the age group of 50-69 years, out of which 16 cases were in the sixth decade. Xerosis and pruritus occurred in 80% and 65.71% of cases, respectively. Other common findings included pallor (68.57%), dyspigmentation (34.29%), cutaneous infections (34.39%), acquired perforating dermatosis (17.4%), and nail changes (60%). Hemodialysis failed to improve pruritus in 17 (73.9%) of our patients. Twenty-six patients (74.28%) suffered from hypertension, 13 of them also were known cases of type II diabetes mellitus. Five patients suffered exclusively from type II diabetes mellitus. Conclusions: In our small study, xerosis was the commonest finding and pruritus, the commonest symptom. The intensity of pruritus was largely unaffected by hemodialysis