Synthesis of symmetrical terphenyl derivatives by PdCl₂-catalyzed Suzuki–Miyaura reaction of dibromobenzene using 3-(diphenylphosphino)propanoic acid as a ligand

<p>A simple and efficient catalytic system for PdCl₂ catalyzing the Suzuki–Miyaura reaction of dibromobenzene and arylboronic acid has been developed by using 3-(diphenylphosphino)propanoic acid as a ligand in dimethylsulfoxide at 100 °C. Using this method, a series of symmetrical terphenyl derivatives were obtained with remarkably good yields, up to 93%.</p

Additional file 3: Figure S2. of Analysis of the ways and methods of signaling pathways in regulating cell cycle of NIH3T3 at transcriptional level

Signal transduction of the signaling pathway that the reported genes involved (DOC 4343 kb

Additional file 4: Figure S3. of Analysis of the ways and methods of signaling pathways in regulating cell cycle of NIH3T3 at transcriptional level

The interaction network between signaling pathway and cell cycle network. (DOC 9794 kb

Additional file 1: Table S1. of Analysis of the ways and methods of signaling pathways in regulating cell cycle of NIH3T3 at transcriptional level

Expression profiles of cell cycle-associated genes. (XLSX 163 kb

Additional file 2: Figure S1. of Analysis of the ways and methods of signaling pathways in regulating cell cycle of NIH3T3 at transcriptional level

Physiological activity that the reported genes involved. (DOC 580 kb