4 research outputs found
Mesoporous TiO<sub>2</sub> Microbead Electrodes for Cobalt-Mediator-Based Dye-Sensitized Solar Cells
Light scattering, porosity, surface
area, and morphology of TiO<sub>2</sub> working electrode can affect
the power conversion efficiency
of dye -sensitized solar cells dramatically. Here mesoporous TiO<sub>2</sub> microbeads were tested as working electrode in dye-sensitized
solar cells based on cobalt tris-bipyridine electrolyte. Power conversion
efficiencies up to 6.4% were obtained with D35 dye adsorbed onto the
light-scattering microbeads. Electron transport, studied using small
light perturbation methods, was found to be significantly faster in
the microbead films than in standard mesoporous TiO<sub>2</sub> films.
This was attributed to the favorable assembly of nanocrystals in the
microbeads, which can increase the electron diffusion coefficient
in the conduction band. Electron lifetimes were similar in both types
of film. While solar cell performance of microbead films was comparable
to that of standard mesoporous films in acetonitrile-based electrolytes,
a significant improvement was found when the more viscous 3-methoxypropionitrile
was used as solvent for electrolyte
Self-Assembled Monolayer of Wavelength-Scale Core–Shell Particles for Low-Loss Plasmonic and Broadband Light Trapping in Solar Cells
Scattering particles constitute a
key light trapping solution for thin film photovoltaics where either
the particles are embedded in the light absorbing layer or a thick
layer of them is used as a reflector. Here we introduce a monolayer
of wavelength-scale core–shell silica@Ag particles as a novel
light trapping strategy for thin film photovoltaics. These particles
show hybrid photonic–plasmonic resonance modes that scatter
light strongly and with small parasitic absorption losses in Ag (<1.5%).
In addition, their scattering efficiency does not vary significantly
with the refractive index of the surrounding medium. A monolayer of
these particles is applied as the top-scattering layers in a dye-sensitized
solar cells and it improves the short-circuit current density of a
cell with 7 μm-thick dye-sensitized layer by 38%. Optical measurements
of the scattering properties of these particles confirm that the strong
scattering and low-parasitic absorption losses constitute the main
reason for this efficient light trapping
Enhanced Light Harvesting with a Reflective Luminescent Down-Shifting Layer for Dye-Sensitized Solar Cells
For
a dye-sensitized solar cell with a near-infrared squaraine (SQ1) sensitizer,
the photovoltaic performance was enhanced remarkably with a reflective
luminescent down-shifting (R-LDS) layer to increase the light-harvesting
efficiency at the wavelength region 400–550 nm where the SQ1
dye has weak absorption. Relative enhancements greater than 200% in
IPCE near 500 nm and 40–54% in <i>J</i><sub>SC</sub> were achieved with red phosphor CaAlSiN<sub>3</sub>:Eu<sup>2+</sup> as the LDS material, attaining 5.0 and 4.8% overall efficiencies
of power conversion for the R-LDS layer coated on the counter electrode
(front illumination) and working electrode (back illumination), respectively
Ag Doping of Organometal Lead Halide Perovskites: Morphology Modification and p‑Type Character
We report a simple
synthetic approach to grow uniform CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> perovskite (PSK) layers free of pinholes
via varied portions of silver iodide (AgI) added to the precursor
solution. XRD/EDS elemental mapping experiments demonstrated nearly
uniform Ag distribution inside the perovskite film. When the 1% AgI-assisted
perovskite films were fabricated into a p-i-n planar device, the photovoltaic
performance was enhanced by ∼30% (PCE increased from 9.5% to
12.0%) relative to the standard cell without added AgI. Measurement
of electronic properties using a hall setup indicated that perovskite
films show p-type character after Ag doping, whereas the film is n-type
without Ag. Transients of photoluminescence of perovskite films with
and without AgI additive deposited on glass, p-type (PEDOT:PSS), and
n-type (TiO<sub>2</sub>) contact layers were recorded with a time-correlated
single-photon counting (TCSPC) technique. The TCSPC results indicate
that addition of AgI inside perovskite in contact with PEDOT:PSS accelerated
the hole-extraction motion whereas that in contact with TiO<sub>2</sub> led to a decelerated electron extraction, in agreement with the
trend observed from the photovoltaic results. The silver cationic
dopant inside the perovskite films had hence an effect of controlling
the morphology to improve photovoltaic performance for devices with
p-i-n configuration