322 research outputs found
The development and general morphology of the telencephalon of actinopterygian fishes: synopsis, documentation and commentary
The Actinopterygii or ray-finned fishes comprise, in addition to the large superorder of teleosts, four other superorders, namely the cladistians, the chondrosteans, the ginglymodes, and the halecomorphs, each with a limited number of species. The telencephalon of actinopterygian fishes differs from that in all other vertebrates in that it consists of a pair of solid lobes. Lateral ventricles surrounded by nervous tissue are entirely lacking. At the end of the nineteenth century, the theory was advanced that the unusual configuration of the forebrain in actinopterygians results from an outward bending or eversion of its lateral walls. This theory was accepted by some authors, rejected or neglected by others, and modified by some other authors. The present paper is based on the data derived from the literature, complemented by new observations on a large collection of histological material comprising specimens of all five actinopterygian superorders. The paper consists of three parts. In the first, a survey of the development of the telencephalon in actinopterygian fishes is presented. The data collected show clearly that an outward bending or eversion of the pallial parts of the solid hemispheres is the principal morphogenetic event in all five actinopterygian superorders. In all of these superorders, except for the cladistians, eversion is coupled with a marked thickening of the pallial walls. In the second part, some aspects of the general morphology of the telencephalon in mature actinopterygians are highlighted. It is pointed out that (1) the degree of eversion varies considerably among the various actinopterygian groups; (2) eversion leads to the transformation of the telencephalic roof plate into a wide membrane or tela choroidea, which is bilaterally attached to the lateral or ventrolateral aspect of the solid hemispheres; (3) the lines of attachment or taeniae of the tela choroidea form the most important landmarks in the telencephalon of actinopterygians, indicating the sites where the greatly enlarged ventricular surface of the hemispheres ends and its reduced meningeal surface begins; (4) the meningeal surface of the telencephalon shows in most actinopterygians bilaterally a longitudinally oriented sulcus externus, the depth of which is generally positively correlated with the degree of eversion; (5) a distinct lateral olfactory tract, occupying a constant topological position close to the taenia, is present in all actinopterygians studied; and (6) this tract is not homologous to the tract of the same name in the evaginated and inverted forebrains of other groups of vertebrates. In the third and final section, the concept that the structural organization of the pallium in actinopterygians can be fully explained by a simple eversion of its walls, and the various theories, according to which the eversion is complicated by extensive shifts of its constituent cell groups, are discussed and evaluated. It is concluded that there are no reasons to doubt that the pallium of actinopterygian fishes is the product of a simple and complete eversion
Two gold surfaces and a cluster with remarkable reactivity for co oxidation, a density functional theory
. Two gold surfaces and a cluster with remarkable reactivity for CO oxidation, a density functional theory study. Topics in Catalysis, 54(5-7), 415-423. DOI: 10.1007/s11244-011-9672-3 DOI: 10.1007/s11244-011-9672-3 Document status and date: Published: 01/01/2011 Document Version: Publisher's PDF, also known as Version of Record (includes final page, issue and volume numbers) Please check the document version of this publication: • A submitted manuscript is the version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal. Abstract We calculate the energetics of CO oxidation on extended surfaces of particular structures chosen to maximize their reactivity towards either O 2 dissociation, after which CO ? O to CO 2 is a facile reaction, or to CO 2 from molecular O 2 and CO. We identified two configurations of Au atoms for which the energetics of these reactions are feasible. A site consisting of four Au atoms in a square geometry appears well suited for dissociating oxygen. A Au 38 cluster exposing this site provides the most favourable energetics for the CO oxidation
Magnetism of PdNi alloys near the critical concentration for ferromagnetism
We report results of a muon spin rotation and relaxation (SR) study of
dilute PdNi alloys, with emphasis on Ni concentrations 0.0243
and 0.025. These are close to the critical value for the onset
of ferromagnetic long-range order (LRO), which is a candidate for a quantum
critical point. The 2.43 and 2.5 at.% Ni alloys exhibit similar SR
properties. Both samples are fully magnetic, with average muon local fields
2.0 and 3.8 mT and Curie temperatures
1.0 and 2.03 K for 2.43 and 2.5 at.% Ni, respectively, at . The
temperature dependence of suggests ordering of
Ni spin clusters rather than isolated spins. Just above a two-phase
region is found with separate volume fractions of quasistatic short-range order
(SRO) and paramagnetism. The SRO fraction decreases to zero with increasing
temperature a few kelvin above . This mixture of SRO and paramagnetism is
consistent with the notion of an inhomogeneous alloy with Ni clustering. The
measured values of extrapolate to = 0.0236 0.0027.
The dynamic muon spin relaxation in the vicinity of differs for the two
samples: a relaxation-rate maximum at is observed for = 0.0243,
reminiscent of critical slowing down, whereas for 0.025 no dynamic
relaxation is observed within the SR time window. The data suggest a
mean-field-like transition in this alloy.Comment: 15 pages, 15 figures, to be published in Phys. Rev.
Magnetism in the 2D Limit and Interface Superconductivity in Metal-Insulator La(2-x)Sr(x)CuO(4) Superlattices
We show, by means of low-energy muon spin rotation measurements, that
few-unit-cells thick La(2)CuO(4) layers synthesized digitally by molecular beam
epitaxy synthesis are antiferromagnetically ordered. Below a thickness of about
5 CuO(2) layers the long-range ordered state breaks down, and a magnetic state
appears with enhanced quantum fluctuations and a reduced spin stiffness. This
magnetic state can exist in close proximity (few Angstrom) to high-temperature
superconducting layers, without transmitting supercurrents.Comment: 4 pages, 3 figure
Effects of Uniaxial Stress on Antiferromagnetic Moment in the Heavy Electron Compound URu_2Si_2
We have performed the elastic neutron scattering experiments under uniaxial
stress \sigma along the tetragonal [100], [110] and [001] directions for
URu2Si2. For \sigma // [100] and [110], the antiferromagnetic moment \mu_o is
strongly enhanced from 0.02 \mu_B (\sigma=0) to 0.22 \mu_B (\sigma=2.5 kbar) at
1.5 K. The rate of increase d\mu_o/d\sigma is roughly estimated to be ~ 0.1
\mu_B/kbar, which is much larger than that for the hydrostatic pressure (~
0.025 \mu_B/kbar). Above 2.5 kbar, \mu_o shows a tendency to saturate similar
to the behavior in the hydrostatic pressure. For \sigma // [001], on the other
hand, \mu_o shows only a slight increase to 0.028 \mu_B (\sigma = 4.6 kbar)
with a rate of ~ 0.002 \mu_B/kbar. The observed anisotropy suggests that the
competition between the hidden order and the antiferromagnetic state in URu2Si2
is strongly coupled with the tetragonal four-fold symmetry and the c/a ratio,
or both.Comment: 3 pages, 3 eps figures, Proceedings of Int. Conf. on Strongly
Correlated Electrons with Orbital Degrees of Freedom (Sendai, Japan,
September 11-14, 2001
Disorder, inhomogeneity and spin dynamics in f-electron non-Fermi liquid systems
Muon spin rotation and relaxation (SR) experiments have yielded evidence
that structural disorder is an important factor in many f-electron-based
non-Fermi-liquid (NFL) systems. Disorder-driven mechanisms for NFL behaviour
are suggested by the observed broad and strongly temperature-dependent SR
(and NMR) linewidths in several NFL compounds and alloys. Local disorder-driven
theories (Kondo disorder, Griffiths-McCoy singularity) are, however, not
capable of describing the time-field scaling seen in muon spin relaxation
experiments, which suggest cooperative and critical spin fluctuations rather
than a distribution of local fluctuation rates. A strong empirical correlation
is established between electronic disorder and slow spin fluctuations in NFL
materialsComment: 24 pages, 15 figures, submitted to J. Phys.: Condens. Matte
Spin glass behavior in URh_2Ge_2
URh_2Ge_2 occupies an extraordinary position among the heavy-electron
122-compounds, by exhibiting a previously unidentified form of magnetic
correlations at low temperatures, instead of the usual antiferromagnetism. Here
we present new results of ac and dc susceptibilities, specific heat and neutron
diffraction on single-crystalline as-grown URh_2Ge_2. These data clearly
indicate that crystallographic disorder on a local scale produces spin glass
behavior in the sample. We therefore conclude that URh_2Ge_2 is a 3D
Ising-like, random-bond, heavy-fermion spin glass.Comment: 10 pages, RevTeX, with 4 postscript figures, accepted by Physical
Review Letters Nov 15, 199
Evolution of Heterogeneous Antiferromagnetic State in URu2Si2: Study of Hydrostatic-Pressure, Uniaxial-Stress and Rh-Dope Effects
We have investigated the nature of the competition between hidden order and
antiferromagnetic (AF) order in URu_2Si_2 by performing the neutron scattering
experiments under hydrostatic-pressure P, uniaxial-stress sigma, and
Rh-substitution conditions. Hidden order observed at ambient pressure in pure
URu_2Si_2 is found to be replaced by the AF order by applying P, sigma along
the tetragonal basal plane, and by doping Rh. We discuss these experimental
results on the basis of the crystalline strain calculations, and suggest that
this phase transition is generated by the 0.1% increase of the tetragonal c/a
ratio. We have also found that the magnetic excitation observed in the hidden
order phase vanishes in the AF phase. We show that this variation can be
qualitatively explained by assuming the hidden order parameter to be
quadrupole.Comment: 4 pages, 4 figures, proceedings of workshop on Novel Pressure-Induced
Phenomena In Condensed Matter Systems, 2006 Fukuok
Effect of Pressure on Tiny Antiferromagnetic Moment in the Heavy-Electron Compound URu_2Si_2
We have performed elastic neutron-scattering experiments on the
heavy-electron compound URu_2Si_2 for pressure P up to 2.8 GPa. We have found
that the antiferrmagnetic (100) Bragg reflection below T_m ~ 17.5 K is strongly
enhanced by applying pressure. For P < 1.1 GPa, the staggered moment mu_o at
1.4 K increases linearly from ~ 0.017(3) mu_B to ~ 0.25(2) mu_B, while T_m
increases slightly at a rate ~ 1 K/GPa, roughly following the transition
temperature T_o determined from macroscopic anomalies. We have also observed a
sharp phase transition at P_c ~ 1.5 GPa, above which a 3D-Ising type of
antiferromagnetic phase (mu_o ~ 0.4 mu_B) appears with a slightly reduced
lattice constant.Comment: RevTeX, 4 pages, 4 eps figures, accepted for publication in Phys.
Rev. Let
Quantification of lateral repulsion between coadsorbed CO and N on Rh(100) using temperature-programmed desorption, low-energy electron diffraction, and Monte Carlo simulations
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