8,239 research outputs found
Standardless Analysis of Biological Tissue Sections
The X-ray microanalysis of thin biological samples which are usually supported on a thin organic film or are self-supporting specimens, has required the use of standards which contain the elements of interest. Spectra from the standards are used to calculate the factors for converting X-ray data recorded on the specimen into elemental concentrations. A method is discussed here, in which these factors are evaluated from formulae. The most important physical process to be evaluated is that of characteristic X-ray production in the specimen. The bremsstrahlung production must also be evaluated if the Hall or continuum normalisation (CN) method of quantitation is to be used.
This paper discusses briefly methods of calculating values for the X-ray production cross-sections for both characteristic and bremsstrahlung radiation. The way in which these are incorporated into standardless quantitation methods for biological samples is described. Calculations of some cross-section data are presented for typical analytical conditions
A General Framework for Computing Optimal Correlated Equilibria in Compact Games
We analyze the problem of computing a correlated equilibrium that optimizes
some objective (e.g., social welfare). Papadimitriou and Roughgarden [2008]
gave a sufficient condition for the tractability of this problem; however, this
condition only applies to a subset of existing representations. We propose a
different algorithmic approach for the optimal CE problem that applies to all
compact representations, and give a sufficient condition that generalizes that
of Papadimitriou and Roughgarden. In particular, we reduce the optimal CE
problem to the deviation-adjusted social welfare problem, a combinatorial
optimization problem closely related to the optimal social welfare problem.
This framework allows us to identify new classes of games for which the optimal
CE problem is tractable; we show that graphical polymatrix games on tree graphs
are one example. We also study the problem of computing the optimal coarse
correlated equilibrium, a solution concept closely related to CE. Using a
similar approach we derive a sufficient condition for this problem, and use it
to prove that the problem is tractable for singleton congestion games.Comment: 14 pages. Short version to appear in WINE 201
Duality Invariant Magnetohydrodynamics And Dyons
The theory of magnetohydrodynamics is extended to the cases of a plasma of
separate magnetic and electric charges, as well as to a plasma of dyons
respectively. In both these cases the system possesses electric-magnetic
duality symmetry. In the former case we find that because of the existence of
two independent generalized Ohm's law equations, the limit of infinite electric
and magnetic conductivity results in the vanishing of both electric and
magnetic fields, as well as the corresponding currents. In the dyonic case, we
find that the resulting duality-invariant system of equations are equivalent to
those of ordinary MHD, after suitable field redefinitions.Comment: 11 pages, late
Amplitude dependent frequency, desynchronization, and stabilization in noisy metapopulation dynamics
The enigmatic stability of population oscillations within ecological systems
is analyzed. The underlying mechanism is presented in the framework of two
interacting species free to migrate between two spatial patches. It is shown
that that the combined effects of migration and noise cannot account for the
stabilization. The missing ingredient is the dependence of the oscillations'
frequency upon their amplitude; with that, noise-induced differences between
patches are amplified due to the frequency gradient. Migration among
desynchronized regions then stabilizes a "soft" limit cycle in the vicinity of
the homogenous manifold. A simple model of diffusively coupled oscillators
allows the derivation of quantitative results, like the functional dependence
of the desynchronization upon diffusion strength and frequency differences. The
oscillations' amplitude is shown to be (almost) noise independent. The results
are compared with a numerical integration of the marginally stable
Lotka-Volterra equations. An unstable system is extinction-prone for small
noise, but stabilizes at larger noise intensity
Global ocean cooling of 2.3°C during the Last Glacial Maximum
Quantitative constraints on past mean ocean temperature (MOT) critically inform our historical understanding of Earth's energy balance. A recently developed MOT proxy based on paleoatmospheric Xe, Kr, and N2 ratios in ice core air bubbles is a promising tool rooted in the temperature dependences of gas solubilities. However, these inert gases are systematically undersaturated in the modern ocean interior, and it remains unclear how air-sea disequilibrium may have changed in the past. Here, we carry out 30 tracer-enabled model simulations under varying circulation, sea ice cover, and wind stress regimes to evaluate air-sea disequilibrium in the Last Glacial Maximum (LGM) ocean. We find that undersaturation of all three gases was likely reduced, primarily due to strengthened high-latitude winds, biasing reconstructed MOT by −0.38 ± 0.37°C (1σ). Accounting for air-sea disequilibrium, paleoatmospheric inert gases indicate that LGM MOT was 2.27 ± 0.46°C (1σ) colder than the pre-industrial era
Models of the SL9 Impacts II. Radiative-hydrodynamic Modeling of the Plume Splashback
We model the plume "splashback" phase of the SL9 collisions with Jupiter
using the ZEUS-3D hydrodynamic code. We modified the Zeus code to include gray
radiative transport, and we present validation tests. We couple the infalling
mass and momentum fluxes of SL9 plume material (from paper I) to a jovian
atmospheric model. A strong and complex shock structure results. The modeled
shock temperatures agree well with observations, and the structure and
evolution of the modeled shocks account for the appearance of high excitation
molecular line emission after the peak of the continuum light curve. The
splashback region cools by radial expansion as well as by radiation. The
morphology of our synthetic continuum light curves agree with observations over
a broad wavelength range (0.9 to 12 microns). A feature of our ballistic plume
is a shell of mass at the highest velocities, which we term the "vanguard".
Portions of the vanguard ejected on shallow trajectories produce a lateral
shock front, whose initial expansion accounts for the "third precursors" seen
in the 2-micron light curves of the larger impacts, and for hot methane
emission at early times. Continued propagation of this lateral shock
approximately reproduces the radii, propagation speed, and centroid positions
of the large rings observed at 3-4 microns by McGregor et al. The portion of
the vanguard ejected closer to the vertical falls back with high z-component
velocities just after maximum light, producing CO emission and the "flare" seen
at 0.9 microns. The model also produces secondary maxima ("bounces") whose
amplitudes and periods are in agreement with observations.Comment: 13 pages, 9 figures (figs 3 and 4 in color), accepted for Ap.J.
latex, version including full figures at:
http://oobleck.tn.cornell.edu/jh/ast/papers/slplume2-20.ps.g
Spin-polarization-induced structural selectivity in Pd and Pt () compounds
Spin-polarization is known to lead to important {\it magnetic} and {\it
optical} effects in open-shell atoms and elemental solids, but has rarely been
implicated in controlling {\it structural} selectivity in compounds and alloys.
Here we show that spin-polarized electronic structure calculations are crucial
for predicting the correct crystal structures for Pd and Pt
compounds. Spin-polarization leads to (i) stabilization of the structure
over the structure in PtCr, PdCr, and PdMn, (ii) to the
stabilization of the structure over the structure in PdCo
and to (iii) ordering (rather than phase-separation) in PtCo and PdCr.
The results are analyzed in terms of first-principles local spin density
calculations.Comment: 4 pages, REVTEX, 3 eps figures, to appear in PR
Critical behavior of repulsive linear -mers on triangular lattices
Monte Carlo (MC) simulations and finite-size scaling analysis have been
carried out to study the critical behavior in a submonolayer two-dimensional
gas of repulsive linear -mers on a triangular lattice at coverage
. A low-temperature ordered phase, characterized by a repetition of
alternating files of adsorbed -mers separated by adjacent empty sites,
is separated from the disordered state by a order-disorder phase transition
occurring at a finite critical temperature, . The MC technique was
combined with the recently reported Free Energy Minimization Criterion Approach
(FEMCA), [F. Rom\'a et al., Phys. Rev. B, 68, 205407, (2003)], to predict the
dependence of the critical temperature of the order-disorder transformation.
The dependence on of the transition temperature, , observed in MC
is in qualitative agreement with FEMCA. In addition, an accurate determination
of the critical exponents has been obtained for adsorbate sizes ranging between
and . For , the results reveal that the system does not belong
to the universality class of the two-dimensional Potts model with (,
monomers). Based on symmetry concepts, we suggested that the behavior observed
for and 3 could be generalized to include larger particle sizes ().Comment: 17 pages, 13 figure
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