Universal Length Dependence of Rod-to-Seed Exciton Localization Efficiency in Type I and Quasi-Type II CdSe@CdS Nanorods

A critical step involved in many applications of one-dimensional seeded CdSe@CdS nanorods, such as luminescent solar concentrators, optical gains, and photocatalysis, is the localization of excitons from the light-harvesting CdS nanorod antenna into the light-emitting CdSe quantum dot seed. We report that the rod-to-seed exciton localization efficiency decreases with the rod length but is independent of band alignment between the CdSe seed and CdS rod. This universal dependence can be well modeled by the competition between exciton one-dimensional diffusion to the CdSe seed and trapping on the CdS rod. This finding provides a rational approach for optimizing these materials for their various device applications

One Dimensional Photonic Crystals Using Ultrahigh Refractive Index Chalcogenide Hybrid Inorganic/Organic Polymers

We report on the fabrication of wholly polymeric one-dimensional (1-D) photonic crystals (i.e., Bragg reflectors, Bragg mirrors) via solution processing for use in the near (NIR) and the short wave (SWIR) infrared spectrum (1–2 μm) with very high reflectance (<i>R</i> ∼ 90–97%). Facile fabrication of these highly reflective films was enabled by direct access to solution processable, ultrahigh refractive index polymers, termed, Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs). The high refractive index (<i>n</i>) of CHIPs materials (<i>n</i> = 1.75–2.10) allowed for the production of narrow band IR Bragg reflectors with high refractive index contrast (Δ<i>n</i> ∼ 0.5) when fabricated with low <i>n</i> polymers, such as cellulose acetate (<i>n</i> = 1.47). This is the highest refractive index contrast (Δ<i>n</i> ∼ 0.5) demonstrated for an all-polymeric Bragg mirror which directly enabled high reflectivity from films with 22 layers or less. Facile access to modular, thin, highly reflective films from inexpensive CHIPs materials offers a new route to IR Bragg reflectors and other reflective coatings with potential applications for IR photonics, commercial sensing, and LIDAR applications