Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries

High-energy rechargeable Li metal batteries are hindered by dendrite growth due to the use of a liquid electrolyte. Solid polymer electrolytes, as promising candidates to solve the above issue, are expected to own high Li ion conductivity without sacrificing mechanical strength, which is still a big challenge to realize. In this study, a bifunctional solid polymer electrolyte exactly having these two merits is proposed with an interpenetrating network of poly­(ether–acrylate) (ipn-PEA) and realized via photopolymerization of ion-conductive poly­(ethylene oxide) and branched acrylate. The ipn-PEA electrolyte with facile processing capability integrates high mechanical strength (ca. 12 GPa) with high room-temperature ionic conductance (0.22 mS cm^–1), and significantly promotes uniform Li plating/stripping. Li metal full cells assembled with ipn-PEA electrolyte and cathodes within 4.5 V vs Li⁺/Li operate effectively at a rate of 5 C and cycle stably at a rate of 1 C at room temperature. Because of its fabrication simplicity and compelling characteristics, the bifunctional ipn-PEA electrolyte reshapes the feasibility of room-temperature solid-state Li metal batteries

Lithium-Ion Batteries: Charged by Triboelectric Nanogenerators with Pulsed Output Based on the Enhanced Cycling Stability

The triboelectric nanogenerator (TENG) has been used to store its generated energy into lithium-ion batteries (LIBs); however, the influences of its pulse current and high voltage on LIB polarization and dynamic behaviors have not been investigated yet. In this paper, it is found that LIBs based on the phase transition reaction of the lithium storage mechanism [LiFePO₄ (LFP) and Li₄Ti₅O₁₂ (LTO) electrodes] are more suitable for charging by TENGs. Thus, the enhanced cycling capacity, Coulombic efficiency (nearly 100% for LTO electrode), and energy storage efficiency (85.3% for the LFP–LTO electrode) are successfully achieved. Moreover, the pulse current has a positive effect on the increase of the Li-ion extraction, reducing the charge-transfer resistance (<i>R</i>_ct) for all studied electrodes as well (LFP, LiNi_0.6Co_0.2Mn_0.2O₂, LTO, and graphite). The excellent cyclability, high Coulombic, and energy storage efficiencies demonstrated the availability of storing pulsed energy generated by TENGs. This research has provided a promising analysis to obtain an enhanced charging methodology, which provides significant guidance for the scientific research of the LIBs